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Volume 23
Main Index

Issue 1


Conversion of (.pi.-allyl)nickel complexes to (.pi.-arene)nickel complexes
S. T. Lin, T. J. Groshens, and K. J. Klabunde
pp 1 - 1; DOI:
10.1021/ic00169a001
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Electrochemical studies of a series of dirhodium(II) complexes with acetate and acetamidate bridging ligands
T. P. Zhu, M. Q. Ahsan, T. Malinski, K. M. Kadish, and J. L. Bear
pp 2 - 3; DOI:
10.1021/ic00169a002
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Electrochemistry in liquid sulfur dioxide. 5. Oxidation of bipyridine and phenanthroline complexes of osmium, ruthenium, and iron
John G. Gaudiello, Paul G. Bradley, Kenneth A. Norton, William H. Woodruff, and Allen J. Bard
pp 3 - 10; DOI:
10.1021/ic00169a003
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Dehydrohalogenation of adducts of dichloro(pentafluorophenyl)borane with mesidine and p-anisidine: a reinvestigation
Joseph G. Morse and W. Kent Glanville
pp 11 - 13; DOI:
10.1021/ic00169a004
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Some aspects of the chemistry of [two] bipentaborane isomers (1,2'-(B5H8)2, 2,2'-(B5H8)2) and their derivatives
Joseph A. Heppert, Matthew A. Kulzick, and Donald F. Gaines
pp 14 - 18; DOI:
10.1021/ic00169a005
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Complexes of aluminum(III) with hydroxy carboxylic acids
Ramunas J. Motekaitis and Arthur E. Martell
pp 18 - 23; DOI:
10.1021/ic00169a006
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Conformational preferences in Mo2L6 complexes
Kerwin D. Dobbs, Michelle M. Francl, and Warren J. Hehre
pp 24 - 26; DOI:
10.1021/ic00169a007
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Structure and bonding in thiazyl fluorides
Constantin Zirz and Reinhart Ahlrichs
pp 26 - 31; DOI:
10.1021/ic00169a008
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Metal tetrathiolenes. 8. Molecular structures of two isostructural two-electron systems: (Ph3P)2(CO)XIr(C10Cl4S4) (X-Cl,H). The first member of a novel series of metal tetrathiolene complexes
Boon K. Teo and P. A. Snyder-Robinson
pp 32 - 39; DOI:
10.1021/ic00169a009
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Synthesis and crystal and molecular structure of cyclo-tetrakis[bis(.mu.-N-methylpiperidine-4-thiolato)nickel(II)]
W. Gaete, J. Ros, X. Solans, M. Font-Altaba, and J. L. Brianso
pp 39 - 43; DOI:
10.1021/ic00169a010
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Reaction of hydrogen sulfide with phosphine complexes of rhodium(I) and iridium(I). Crystal and molecular structures of [RhCl(H)(.mu.-SH)(PPh3)2]2.2CH2Cl2 and IrCl(H)(SH)CO(PPh3)2
Ann M. Mueting, Paul Boyle, and Louis H. Pignolet
pp 44 - 48; DOI:
10.1021/ic00169a011
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Outer-sphere charge-transfer photochemistry of ruthenium(III) complexes: flash photolysis of Ru(NH3)5py3+/halide ion pairs
D. A. Sexton, J. C. Curtis, H. Cohen, and P. C. Ford
pp 49 - 52; DOI:
10.1021/ic00169a012
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Intrazeolite rhodium carbonyl and rhodium carbonyl phosphine complexes
Brian E. Hanson, Mark E. Davis, Dennis Taylor, and Edward Rode
pp 52 - 56; DOI:
10.1021/ic00169a013
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Molecular orbital analysis of the bonding capabilities of carbon disulfide and carbon dioxide toward transition metal fragments
Carlo Mealli, Roald Hoffmann, and Armel Stockis
pp 56 - 65; DOI:
10.1021/ic00169a014
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Ruthenium complexes of 1,3-bis(2-pyridylimino)isoindolines as alcohol oxidation catalysts
Robert R. Gagne and David N. Marks
pp 65 - 74; DOI:
10.1021/ic00169a015
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Synthesis and crystal structure of [(Ph3P)2(CO)2(S2N2)RuCl]+AlCl4-. Preparation of novel S2N2 complexes
H. W. Roesky, J. Anhaus, and W. S. Sheldrick
pp 75 - 79; DOI:
10.1021/ic00169a016
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Dealkylation of N-methyl-5,10,15,20-tetraphenylporphine by palladium(II) in acetonitrile, dimethyl sulfoxide, and dimethylformamide
Jon D. Doi, Catherine Compito-Magliozzo, and David K. Lavallee
pp 79 - 84; DOI:
10.1021/ic00169a017
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Effect of pH and acetate on the rate of hydrolysis of the chromium-carbon bond in (.alpha.-hydroxyalkyl)chromium(III) complexes
Haim Cohen and Dan Meyerstein
pp 84 - 87; DOI:
10.1021/ic00169a018
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Ligation of phosphorus ligands to silver(I). 1. Coordination of one to four P(NR2)3 ligands and the structure of a nonlinear two-coordinate complex
S. M. Socol, R. A. Jacobson, and J. G. Verkade
pp 88 - 94; DOI:
10.1021/ic00169a019
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Preparation and characterization of binuclear (1,4,7-triazacyclononane)molybdenum(III) complexes. Crystal structures of [MoIII2(.mu.-OH)2Cl2(C6H15N3)2]I2 and [MoIII2(.mu.-OH)2(.mu.-O2CCH3)(C6H15N3)2]I3.H2O
Karl Wieghardt, Manfred Hahn, Wolfgang Swiridoff, and Johannes Weiss
pp 94 - 99; DOI:
10.1021/ic00169a020
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A linear .mu.-oxo-diosmium(IV) molecule in which two bis(diphenylphosphino)methane ligands bridge an entire MOM unit: Os2(.mu.-O)(.mu.-Ph2PCH2PPh2)2Cl6
Akhil R. Chakravarty, F. Albert Cotton, and Willi Schwotzer
pp 99 - 103; DOI:
10.1021/ic00169a021
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Kinetics and mechanism of iron(II), cobalt(II), and nickel(II) mono complex formation with acetohydroxamic acid
Lawrence A. Dominey and Kenneth Kustin
pp 103 - 108; DOI:
10.1021/ic00169a022
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The hydrogen oxide bridging ligand (H3O2-). 2. Effect of the hydrogen ion concentration
Avi Bino and Dan Gibson
pp 109 - 115; DOI:
10.1021/ic00169a023
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Interactions between metal chelate electrolytes of 1,10-phenanthroline and nitrobenzene in water: crystal and molecular structure of the nitrobenzene solvate of tris(1,10-phenanthroline)iron(II) iodide dihydrate
Terufumi Fujiwara, Etsuro Iwamoto, and Yuroku Yamamoto
pp 115 - 117; DOI:
10.1021/ic00169a024
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Determination of reaction entropies for the single steps of two-electron-transfer processes with small E1.degree. - E2.degree. differences: application to Au9(PPh3)83+ and ((bpy)2ClRu)2pyz2+
J. E. J. Schmitz and J. G. M. Van der Linden
pp 117 - 119; DOI:
10.1021/ic00169a025
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Effect of crystal quality on the spin-transition behavior in a cobalt(II) complex
E. W. Mueller, H. Spiering, and P. Guetlich
pp 119 - 120; DOI:
10.1021/ic00169a026
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Issue 2


Steric control of metal-thiolate coordination: synthesis and structure of monomeric cobalt(II) and copper(I) thiolate complexes
Stephen A. Koch, Ronald Fikar, Michelle Millar, and Timothy O'Sullivan
pp 121 - 122; DOI:
10.1021/ic00170a001
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Neutron diffraction analysis of [H3Pt2(Ph2PCH2CH2PPh2)2]+[BPh4]-: an unusual example of an unsymmetrical [P2Pt(.mu.-H)2PtP2H] core
Michael Y. Chiang, Robert Bau, Giovanni Minghetti, Anna Laura Bandini, Guido Banditelli, and Thomas F. Koetzle
pp 122 - 124; DOI:
10.1021/ic00170a002
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Characterization of a Fischer-Tropsch catalyst prepared by decarbonylation of dodecacarbonyltetracobalt on alumina
Gregory F. Meyers and Michael B. Hall
pp 124 - 131; DOI:
10.1021/ic00170a003
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Carbon-13 NMR spectra of monosubstituted tungsten carbonyl complexes. NMR trans influence in octahedral tungsten (0) compounds
Wolfgang Buchner and Wolfdieter A. Schenk
pp 132 - 137; DOI:
10.1021/ic00170a004
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Formation of palladium(II) and palladium(I) carbonyl halo complexes
Daniela Belli Dell'Amico, Fausto Calderazzo, and Nicola Zandona
pp 137 - 140; DOI:
10.1021/ic00170a005
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Preparation and spectral and electrochemical characterization of dirhodium(II) complexes with bridging 1,8-naphthyridine ligands: 2,7-bis(2-pyridyl)-1,8-naphthyridine, 5,6-dihydrodipyrido[2,3-b:3'2'-j][1,10]phenanthroline, 2-(2-pyridyl)-1,8-naphthyridine and 1,8-naphthyridine. X-ray crystal structure of tris(.mu.-acetato)(2,7-bis(2-pyridyl)-1,8-naphthyridine)dirhodium(II) Hexafluorophosphate
Wayne R. Tikkanen, E. Binamira-Soriaga, William C. Kaska, and Peter C. Ford
pp 141 - 146; DOI:
10.1021/ic00170a006
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Intermediates in the formation of gold clusters. Preparation and x-ray analysis of [Au7(PPh3)7]+ and synthesis and characterization of [Au8(PPh3)6I]PF6
J. W. A. Van der Velden, P. T. Beurskens, J. J. Bour, W. P. Bosman, J. H. Noordik, M. Kolenbrander, and J. A. K. M. Buskes
pp 146 - 151; DOI:
10.1021/ic00170a007
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Synthesis, structure, and magnetic properties of fluoride-bridged copper(II) dimers. Crystal and molecular structures of bis(.mu.-fluoro)bis[tris(3,4,5-trimethylpyrazole-N2)copper(II)] bis(tetrafluoroborate) and bis(.mu.-fluoro)bis[(5-methylpyrazole-N2)bis(3,5-dimethylpyrazole-N2)copper(II)] bis(tetrafluoroborate)
Frederik J. Rietmeijer, Rudolf A. G. De Graaff, and Jan Reedijk
pp 151 - 156; DOI:
10.1021/ic00170a008
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Synthesis and crystal structure of dibromotetrakis(dimethyl sulfoxide) ruthenium(II). Structural implications for oxygen oxidation catalysis
Joel D. Oliver and Dennis P. Riley
pp 156 - 158; DOI:
10.1021/ic00170a009
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Synthesis and structural characterization of the dirhenium polyhydride complex [Re2(.mu.-H)3H2(PPh3)4(CN-tert-Bu)2]PF6
Joe D. Allison, F. A. Cotton, Gregory L. Powell, and Richard A. Walton
pp 159 - 164; DOI:
10.1021/ic00170a010
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Niobium aluminum chloride (NbAlCl8): a molecular dinuclear complex in the solid, melt, and vapor phases. Synthesis, crystal structure, and Raman spectra
Bernt Krebs, Holger Janssen, Niels J. Bjerrum, Rolf W. Berg, and G. N. Papatheodorou
pp 164 - 171; DOI:
10.1021/ic00170a011
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Crystal structure and polarized electronic spectra of a (.mu.-superoxo)dicobalt(III) complex: [((NH3)5Co)2O2](NO3)2Cl3.2H2O
Vincent M. Miskowski, Bernard D. Santarsiero, William P. Schaefer, Gary E. Ansok, and Harry B. Gray
pp 172 - 176; DOI:
10.1021/ic00170a012
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Carbon dioxide activation by alkali metals. 2. Infrared spectra of M+CO2- and M22+CO22- in argon and nitrogen matrixes
Zakya H. Kafafi, Robert H. Hauge, W. Edward Billups, and John L. Margrave
pp 177 - 183; DOI:
10.1021/ic00170a013
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Hypersensitivity in the absorption spectra of erbium(III) complexes in aqueous solutions
Scott A. Davis and F. S. Richardson
pp 184 - 189; DOI:
10.1021/ic00170a014
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Synthesis, structure and magnetic properties of a binuclear, pentacoordinate copper(II) complex
Thomas N. Sorrell, Donald L. Jameson, and Charles J. O'Connor
pp 190 - 195; DOI:
10.1021/ic00170a015
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Wavelength-dependent photochemical reaction of (.mu.-tetraphenylporphinato)bis[dicarbonylrhodium(I)]. Locking of metal ion into ligand
Sadaaki Yamamoto, Mikio Hoshino, Katsutoshi Yasufuku, and Masashi Imamura
pp 195 - 198; DOI:
10.1021/ic00170a016
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Trans .fwdarw. cis isomerization of stilbene photocatalyzed by copper(I) complexes. The first example of copper(I) photocatalysis efficient under visible-light irradiation
Shigeyoshi Sakaki, Isao Okitaka, and Katsutoshi Ohkubo
pp 198 - 203; DOI:
10.1021/ic00170a017
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Reaction of nickel electrode surfaces with anionic metal-cyanide complexes: formation of precipitated surfaces
Sujit Sinha, Brian D. Humphrey, and Andrew B. Bocarsly
pp 203 - 212; DOI:
10.1021/ic00170a018
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Characterization and photochemistry of surface-confined mononuclear and trinuclear phosphine/carbonyl complexes of ruthenium(0)
David K. Liu, Mark S. Wrighton, Dale R. McKay, and Gary E. Maciel
pp 212 - 220; DOI:
10.1021/ic00170a019
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Electron transfer. 66. Mediation by ligands bearing a remote isonicotinoyl group
U. B. Goli and E. S. Gould
pp 221 - 227; DOI:
10.1021/ic00170a020
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New oxotechnetium(V) complexes of N,N'-ethylenebis(acetylacetone imine), N,N'-ethylenebis(salicylideneamine), and o-phenylenebis(salicylideneamine). X-ray structures of the complexes of N,N'-ethylenebis(acetylacetone imine) and N,N'-ethylenebis(salicylideneamine)
Silvia Jurisson, Leonard F. Lindoy, Keith P. Dancey, Mary McPartlin, Peter A. Tasker, Daljit K. Uppal, and Edward Deutsch
pp 227 - 231; DOI:
10.1021/ic00170a021
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Kinetics of the primary interaction of pentacyanonitrosylferrate(2-) (nitroprusside) with aliphatic thiols
Michael D. Johnson and Ralph G. Wilkins
pp 231 - 235; DOI:
10.1021/ic00170a022
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Kinetics of dissociation and isomerization of cis-Ni([14]aneN4)(H2O)22+ in aqueous perchloric acid solutions
E. J. Billo
pp 236 - 238; DOI:
10.1021/ic00170a023
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1,2-Bis(F-alkyl)cyclo-1,2-diazo-3-sulfanes, 1,2-bis(F-alkyl)cyclo-1,2-diaza-3,4,5-trisulfanes, and 1,2-bis(F-alkyl)cyclo-1,2-diaza-3,4,5,6-tetrasulfanes
Ramesh C. Kumar and Jean'ne M. Shreeve
pp 238 - 241; DOI:
10.1021/ic00170a024
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.eta.5-Bonding between main-group elements and cyclopentadiene rings: an X.alpha.-scattered-wave study
M. Lattman and A. H. Cowley
pp 241 - 247; DOI:
10.1021/ic00170a025
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Electronic structure of metal carbonyl clusters. 2. An INDO investigation of tetra-, penta-, and hexanuclear nickel complexes
Piercarlo Fantucci, Gianfranco Pacchioni, and Venanzio Valenti
pp 247 - 253; DOI:
10.1021/ic00170a026
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Molecular structure of (.mu.-oxo)bis[oxobis(8-quinolinolato)vanadium(V)]
Shinkichi Yamada, Chuji Katayama, Jiro Tanaka, and Motoharu Tanaka
pp 253 - 255; DOI:
10.1021/ic00170a027
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Entropic driving-force effects upon preexponential factors for intramolecular electron transfer: implications for the assessment of nonadiabaticity
Joseph T. Hupp and Michael J. Weaver
pp 256 - 258; DOI:
10.1021/ic00170a028
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Unexpected formation of cis- and trans-Ph2PCH:CHPPh2 by reaction of lithiobis(diphenylphosphino)methane and dichloromethane. Carbon-13 NMR studies of the products
Sibbele Hietkamp and Othmar Stelzer
pp 258 - 260; DOI:
10.1021/ic00170a029
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Issue 3


Reduction of cis-dioxo (tetraphenylporphinato) molybdenum(VI); one- or two-electron-transfer pathway
H. Ledon, F. Varescon, T. Malinski, and K. M. Kadish
pp 261 - 263; DOI:
10.1021/ic00171a001
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Studies on the kinetics and mechanism of oxygen exchange between solvent water and pentachlorooxomolybdate(2-)
Chang Su Kim and R. Kent Murmann
pp 263 - 268; DOI:
10.1021/ic00171a002
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Chlorotellurate(IV) equilibria in aqueous hydrochloric acid
John Milne and Mani Mahadevan
pp 268 - 271; DOI:
10.1021/ic00171a003
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Metallotetraphenylporphyrin-catalyzed oxidation of 2,6-di-tert-butylphenol
Xian Yuan Wang, Ramunas J. Motekaitis, and Arthur E. Martell
pp 271 - 275; DOI:
10.1021/ic00171a004
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Formation and stabilities of cobalt(II) chelates of N-benzyl triamine Schiff bases and their dioxygen complexes
Ramunas J. Motekaitis, Arthur E. Martell, and David A. Nelson
pp 275 - 283; DOI:
10.1021/ic00171a005
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Unusual structural, chemical, and magnetic properties of mononuclear iron(III) complexes of the potentially binucleating ligand meso-.alpha.,.alpha.,.alpha.,.alpha.-tetrakis(o-nicotinamidophenyl)porphyrin
Maxwell J. Gunter, George M. McLaughlin, Kevin J. Berry, Keith S. Murray, Mark Irving, and Paul E. Clark
pp 283 - 300; DOI:
10.1021/ic00171a006
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Photophysical characterization of the decatungstoeuropate(9-) anion
Roberto Ballardini, Quinto Giuliano Mulazzani, Margherita Venturi, Fabrizio Bolletta, and Vincenzo Balzani
pp 300 - 305; DOI:
10.1021/ic00171a007
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Relativistic calculation of the electronic structure and related properties of hexachloroiridate(2-)
Annick Goursot, Henry Chermette, and Claude Daul
pp 305 - 314; DOI:
10.1021/ic00171a008
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Synthesis, molecular structure, and solution properties of a phenolate-bridged (tetraarylporphinato)iron(III) dimer
Harold M. Goff, Eric T. Shimomura, Young Ja Lee, and W. Robert Scheidt
pp 315 - 321; DOI:
10.1021/ic00171a009
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Carbon-13 and deuterium NMR spectroscopy of high-spin manganese(III) porphyrin halide and pyridine complexes
Harold M. Goff and Andrew P. Hansen
pp 321 - 326; DOI:
10.1021/ic00171a010
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A nickel complex containing an extremely long nickel-phosphorus bond. Syntheses and x-ray structures of [Ni(CN)2[P(CH2OH)Ph2]3](C6H6)0.5 and trans-[Ni(CN)2[P(CH2-OH)Ph2]2]
H. Hope, M. M. Olmstead, P. P. Power, and M. Viggiano
pp 326 - 330; DOI:
10.1021/ic00171a011
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Preparation, spectra, and crystal structures of two rhodium(III) complexes with short intramolecular hydrogen bonds
Sutatip Siriparisarnpipat and E. O. Schlemper
pp 330 - 334; DOI:
10.1021/ic00171a012
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Structure and magnetic behavior of iron(III) dithiocarbamate complexes exhibiting S = |1/2.rtbbrac. .dblarw. S = |5/2.rtbbrac. thermal equilibrium. Study of the tris(N-methyl-N-n-butyldithiocarbamato)iron homolog
A. Terzis, S. Filippakis, D. Mentzafos, mV. Petrouleas, and Angelos Malliaris
pp 334 - 337; DOI:
10.1021/ic00171a013
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Complexes of tetracyanobiimidazole. 1. Dimeric and tetrameric species.
P. G. Rasmussen, O. H. Bailey, and J. C. Bayon
pp 338 - 343; DOI:
10.1021/ic00171a014
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Complexes of tetracyanobiimidazole. 2. Monomeric species
P. G. Rasmussen, O. H. Bailey, J. C. Bayon, and W. M. Butler
pp 343 - 349; DOI:
10.1021/ic00171a015
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Poly(pyrazolyl)borate derivatives of chlorotrimethyltantalum(V). Synthesis, crystal structure, and stereochemically nonrigid behavior of seven-coordinate molecules
Daniel L. Reger, Cornelius A. Swift, and Lukasz Lebioda
pp 349 - 354; DOI:
10.1021/ic00171a016
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Solvento complexes of tungsten, rhenium, osmium, and iridium and the x-ray crystal structure of [IrH2(Me2CO)2(PPh3)2]BF4
Robert H. Crabtree, Gregory G. Hlatky, Charles A. Parnell, Brigitte E. Segmueller, and Richard J. Uriarte
pp 354 - 358; DOI:
10.1021/ic00171a017
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Crystal and molecular structure of sodium aqua(1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetato)europate(III) tetrahydrate Na+(EuDOTA.H2O)-.4H2O, and its relevance to NMR studies of the conformational behavior of the lanthanide complexes formed by the macrocyclic ligand DOTA
Marie Rose Spirlet, Jean Rebizant, Jean F. Desreux, and Marie France Loncin
pp 359 - 363; DOI:
10.1021/ic00171a018
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Aryldiazenido, aryldiazene, and arylhydrazido complexes. X-ray structure of [(.eta.5-C5H5)Re(CO)2(NHNMeC6H4Me-p)][BF4] and proton NMR study of stereoisomerism of the organohydrazido(1-) ligand in complexes of this type
Carlos F. Barrientos-Penna, Charles F. Campana, Frederick W. B. Einstein, Terry Jones, Derek Sutton, and Alan S. Tracey
pp 363 - 368; DOI:
10.1021/ic00171a019
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Metal-vapor synthesis and electrochemistry of bis(bipyridyl)nickel(0)
Bruce J. Henne and Duane E. Bartak
pp 369 - 373; DOI:
10.1021/ic00171a020
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Synthesis of some alkyl phosphite complexes of platinum and their structural and spectral characterization
Jose M. Solar, Robin D. Rogers, and W. Roy Mason
pp 373 - 377; DOI:
10.1021/ic00171a021
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Synthesis and spectroscopic and electrochemical properties of a new ruthenium complex: the tris(1,4,5,8-tetraazaphenanthrene)ruthenium(II) dication
A. Kirsch-De Mesmaeker, R. Nasielski-Hinkens, D. Maetens, D. Pauwels, and J. Nasielski
pp 377 - 379; DOI:
10.1021/ic00171a022
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Mixed isocyanide-halide complexes of osmium(II) and osmium(III)
Stephen M. Tetrick and Richard A. Walton
pp 379 - 382; DOI:
10.1021/ic00171a023
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One-electron, visible-light photooxidation of porphyrins in alkyl chloride solutions
Zbigniew Gasyna, William R. Browett, and Martin J. Stillman
pp 382 - 384; DOI:
10.1021/ic00171a024
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Issue 4


Induced electron transfer in ammineruthenium catechol and quinone complexes
R. B. Salmonsen, A. Abelleira, M. J. Clarke, and S. D. Pell
pp 385 - 387; DOI:
10.1021/ic00172a001
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Osmium(V): synthesis, characterization, and spectral examination of hexahalo complexes
Roy H. Magnuson
pp 387 - 392; DOI:
10.1021/ic00172a002
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Crystal structures of the tetraphenylphosphonium salts of hexachloroosmate(V) and hexachloroosmate(IV), [(C6H5)4P]OsCl6 and [(C6H5)4P]2OsCl6
Eunice E. Kim, Klaas Eriks, and Roy Magnuson
pp 393 - 397; DOI:
10.1021/ic00172a003
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Structural studies on polynuclear osmium carbonyl hydrides. 25. Synthesis, characterization, and reversible photochemical/thermal interconversion of .eta.1- and .eta.2-bridged (aryldiazo)triosmium clusters. Crystal structure of (.mu.-H)Os3(CO)10(.mu.-.eta.2-N:NPh)
Deborah E. Samkoff, John R. Shapley, Melvyn Rowen Churchill, and Harvey J. Wasserman
pp 397 - 402; DOI:
10.1021/ic00172a004
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Addition of activated acetylenes to coordinated polysulfide ligands. 2. Synthesis of the Fe2[S2C2(COOCH3)2]42- dithiolene complex by the addition of CH3OOCC.tplbond.CCOOCH3 to the (Fe2S12)2- anion. The crystal and molecular structure of (Ph4P)2Fe2[S2C2(COOCH3)2]4
M. G. Kanatzidis and D. Coucouvanis
pp 403 - 409; DOI:
10.1021/ic00172a005
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Crystal and molecular structure of a dinuclear chromium(III) complex with a linear oxygen bridge
Massimo Di Vaira and Fabrizio Mani
pp 409 - 412; DOI:
10.1021/ic00172a006
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Structural studies of tin(II) and lead(II) dimethylamides: x-ray crystal structure of [Sn(NMe2)2]2 and isolation of its lead analog
Marilyn M. Olmstead and Philip P. Power
pp 413 - 415; DOI:
10.1021/ic00172a007
PDF
Gas-phase structure of dimeric tetrafluorosulfur chloroimide, (ClNSF4)2
Heinz Oberhammer, Alfred Waterfeld, and Ruediger Mews
pp 415 - 418; DOI:
10.1021/ic00172a008
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Synthesis and stereochemistry of metal(II) thiolates of the types [M(SR)4]2-, [M2(SR)6]2-, and [M4(SR)10]2- (M = Fe(II), Co(II))
Karl S. Hagen and R. H. Holm
pp 418 - 427; DOI:
10.1021/ic00172a009
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Reactions of LM(CO)3 complexes (M = Cr, Mo, W; L = 1,4,7-triazacyclononane) with bromine, iodine, and nitric acid. Syntheses of air-stable hydridocarbonyl and hydridonitrosyl complexes. Crystal structure of [LMo(CO)3Br](ClO4).H2O
Phalguni Chaudhuri, Karl Weighardt, Yi Hung Tsai, and Carl Krueger
pp 427 - 432; DOI:
10.1021/ic00172a010
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Bis(pentamethylcyclopentadienyl)ytterbium(II) as a Lewis acid and electron-transfer ligand. Preparation and crystal structures of [Yb(Me5C5)2(.mu.-CO)xMn(CO)5-x]y (x, y = 2; x = 3, y = .infin.)
James M. Boncella and Richard A. Andersen
pp 432 - 437; DOI:
10.1021/ic00172a011
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Reactions of coordinated molecules. 39. Crystal and molecular structure of a rhena .beta.-keto iminato complex of boron
P. Galen Lenhert, C. M. Lukehart, and K. Srinivasan
pp 438 - 440; DOI:
10.1021/ic00172a012
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Oxidative displacement and addition reactions of F-tert-butyl hypochlorite with metal chlorides and oxidative additions to several elements
JoAnn M. Canich, Gary L. Gard, and Jean'ne M. Shreeve
pp 441 - 444; DOI:
10.1021/ic00172a013
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cis Effect of the phosphorus ligand, L, in six-coordinate Ru(CO)3(L)(SiCl3)2 compounds. Importance of the steric factor
Karen L. Chalk and Roland K. Pomeroy
pp 444 - 449; DOI:
10.1021/ic00172a014
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A multinuclear NMR investigation of stannous chloride promoted ligand exchange of platinum phosphole complexes
Mark S. Holt, J. Jeffrey MacDougall, Francois Mathey, and John H. Nelson
pp 449 - 453; DOI:
10.1021/ic00172a015
PDF
Excited-state spectra and lifetimes for oxomethoxomolybdenum(V) tetraphenylporphine: a comparison of d1 and d9 metalloporphyrin photophysics
Nick Serpone, Henry Ledon, and Thomas L. Netzel
pp 454 - 457; DOI:
10.1021/ic00172a016
PDF
Method for determination of phosphate anion-cation association constants from phosphorus-31 chemical shifts
Paul Haake and Richard V. Prigodich
pp 457 - 462; DOI:
10.1021/ic00172a017
PDF
Low-frequency IR and Raman spectra of tricarbonylcyclopentadienylmanganese and tricarbonylcyclopentadienylrhenium. Study of dynamic disorder
K. Chhor and G. Lucazeau
pp 462 - 468; DOI:
10.1021/ic00172a018
PDF
Dimerization of aquadioxovanadium(V) ion in concentrated perchloric and sulfuric acid media
C. Madic, G. M. Begun, R. L. Hahn, J. P. Launay, and W. E. Thiessen
pp 469 - 476; DOI:
10.1021/ic00172a019
PDF
Redox chemistry of bis(2,9-dimethyl-4,7-bis(sulfonatophenyl)-1,10-phenanthrolinato)copper(II/I). Reactions with nickel oxime imine complexes
Anne E. Allan, A. Graham Lappin, and Mauro C. M. Laranjeira
pp 477 - 482; DOI:
10.1021/ic00172a020
PDF
Copper(II) and nickel(II) complexes of the tetra-N-methylated macrocycle dibenzocyclam: synthesis, crystal structure and kinetics of formation and substitution
Dirk Detlev Klaehn, Helmut Paulus, Ruediger Grewe, and Horst Elias
pp 483 - 490; DOI:
10.1021/ic00172a021
PDF
Crystal structure and magnetic and EPR properties of bis(.mu.-azido)tetrakis(4-tert-butylpyridine)dicopper(II) perchlorate: a new copper(II) dinuclear complex with a large stabilization of the ground triplet state
Sonia Sikorav, Itka Bkouche-Waksman, and Olivier Kahn
pp 490 - 495; DOI:
10.1021/ic00172a022
PDF
Crystal structure and spectroscopic studies of [MoO2(L-Cys-OMe)2]
Iain Buchanan, Martin Minelli, Michael T. Ashby, Trevor J. King, John H. Enemark, and C. David Garner
pp 495 - 500; DOI:
10.1021/ic00172a023
PDF
Reinterpretation of five recent crystal structures of heteropoly and isopoly complexes: divanadodecamolybdophosphate, trivanadoenneamolybdophosphate, ".gamma.-dodecatungstophosphate", the dodecamolybdate-dodecamolybdomolybdate blue complex, and dihydrogen decavanadate
Howard T. Evans and Michael T. Pope
pp 501 - 504; DOI:
10.1021/ic00172a024
PDF
Chemical and electrochemical reduction of pentacarbonyl(4-cyanopyridine) complexes of chromium(0), molybdenum(0) and tungsten(0)
Wolfgang Kaim
pp 504 - 506; DOI:
10.1021/ic00172a025
PDF
Mixed-ligand (1,2-diimine)(ethylene-1,2-dithiolate) complexes of nickel, palladium, and platinum
Arnd Vogler, Horst Kunkely, Joachim Hlavatsch, and Andreas Merz
pp 506 - 509; DOI:
10.1021/ic00172a026
PDF
Alcohol formation from O-alkyl aldoximes by reaction with ruthenium(II) complexes
Maureen J. Kendrick Geno and John H. Dawson
pp 509 - 510; DOI:
10.1021/ic00172a027
PDF

Issue 5


Metal complexes of the neutral borane adduct (B2H4.2P(CH3)3)
Steven A. Snow, Mamoru Shimoi, Calvin D. Ostler, Brian K. Thompson, Goji Kodama, and Robert W. Parry
pp 511 - 512; DOI:
10.1021/ic00173a001
PDF
Photochemical conversion of H2Os3(CO)10(P-donor) to H2Os3(CO)9(P-donor) in solution and on high surface area silica
James G. Bentsen and Mark S. Wrighton
pp 512 - 515; DOI:
10.1021/ic00173a002
PDF
The .sigma.- and .pi.-acidity of arsenic pentafluorooxotellurate (As(OTeF5)3)
Steven H. Strauss and Kent D. Abney
pp 515 - 516; DOI:
10.1021/ic00173a003
PDF
Redox behavior of Fe4S4 clusters surrounded by hydrophobic groups, [Fe4S4(SC6H4R-p)4]2- (R = n-C4H9, n-C8H17, and n-C12H25), in aqueous micellar solutions
Koji Tanaka, Toshio Tanaka, and Isao Kawafune
pp 516 - 518; DOI:
10.1021/ic00173a004
PDF
Synthesis of CF3NBr2 and CF3NBrCl. Novel metal fluoride promoted conversion of nitrogen-chlorine bonds to nitrogen-bromine bonds
Yuan Y. Zheng, Qui Chi Mir, Brian A. O'Brian, and Darryl D. DesMarteau
pp 518 - 519; DOI:
10.1021/ic00173a005
PDF
Copper(I)-dioxygen reactivity. 2. Reaction of a three-coordinate copper(I) complex with dioxygen, with evidence for a binuclear oxo-copper(II) species: structural characterization of a parallel-planar dihydroxo-bridged dimer
Kenneth D. Karlin, Yilma Gultneh, Jon C. Hayes, and Jon Zubieta
pp 519 - 521; DOI:
10.1021/ic00173a006
PDF
Observation of distinct cadmium-113 NMR signals for complexes of nitrogen-donor chelate ligands in solution at ambient temperature
Michael F. Summers and Luigi G. Marzilli
pp 521 - 523; DOI:
10.1021/ic00173a007
PDF
Mechanism of heterolytic iron-iron bond cleavage in (.mu.-dimethylarsenido)(tetracarbonyliron)dicarbonylnitrosyliron(Fe-Fe)
Ronald A. Jackson, Ratana Kanluen, and Anthony Poe
pp 523 - 527; DOI:
10.1021/ic00173a008
PDF
Mechanism of the photochemical disproportionation reaction of decacarbonyldimanganese (Mn2(CO)10) with nitrogen donor ligands
Albert E. Stiegman and David R. Tyler
pp 527 - 529; DOI:
10.1021/ic00173a009
PDF
Seven-coordinate halo and dithiocarbamate trimethylphosphine derivatives of molybdenum(II) and tungsten(II)
Ernesto Carmona, Karl Doppert, Jose M. Marin, Manuel L. Poveda, Luis Sanchez, and Roberto Sanchez-Delgado
pp 530 - 534; DOI:
10.1021/ic00173a010
PDF
[VO(O2)2Cl]2--[V(O2)3Cl]2- pair in peroxyvanadium(V) chemistry: synthesis of the first chloroperoxyvanadate(V) compounds and evidence for diperoxyvanadate(V)-triperoxyvanadate(V) interconversion
Mihir K. Chaudhuri and Soumitra K. Ghosh
pp 534 - 537; DOI:
10.1021/ic00173a011
PDF
Coordination modes of polydentate ligands. 1. Template synthesis of complexes of nickel(2+), copper(2+), and cobalt(2+) with pentadentate and hexadentate ligands: structure of a highly distorted six-coordinate cobalt(2+) complex
Edward Konefal, Stephen J. Loeb, Douglas W. Stephan, and Christopher J. Willis
pp 538 - 545; DOI:
10.1021/ic00173a012
PDF
Steric effects in electron-transfer reactions. 1. Trends in homogeneous rate constants for reactions between members of structurally related redox series
Carl A. Koval, Robin L. A. Pravata, and Cindy M. Reidsema
pp 545 - 553; DOI:
10.1021/ic00173a013
PDF
Gas-phase reactions of cobalt(1+) and rhodium(1+) with toluene, cycloheptatriene, and norbornadiene
D. B. Jacobson, G. D. Byrd, and B. S. Freiser
pp 553 - 557; DOI:
10.1021/ic00173a014
PDF
Phase diagram of the sodium chloride-aluminum chloride system near equimolar composition, with determination of the cryoscopic constant, the enthalpy of melting, and oxide contaminations
Rolf W. Berg, Hans Aage Hjuler, and Niels J. Bjerrum
pp 557 - 565; DOI:
10.1021/ic00173a015
PDF
Preparation of well-defined surfaces at atmospheric pressure: studies by electrochemistry and LEED of platinum(100) pretreated with iodine
Andrzej Wieckowski, Stephen D. Rosasco, Bruce C. Schardt, John L. Stickney, and Arthur T. Hubbard
pp 565 - 569; DOI:
10.1021/ic00173a016
PDF
A two-level approach to deconvoluting absorbance data involving multiple species. Applications to copper systems
Cynthia E. Atkins, Stephen E. Park, Judith A. Blaszak, and David R. McMillin
pp 569 - 572; DOI:
10.1021/ic00173a017
PDF
Theoretical study of the electrical behavior of one-dimensional metallophthalocyanines and related metallomacrocyclic compounds
Enric Canadell and Santiago Alvarez
pp 573 - 579; DOI:
10.1021/ic00173a018
PDF
Spin-state differences and spin crossover in five-coordinate Lewis base adducts of cobalt(II) Schiff base complexes. Structure of the high-spin (N,N'-o-phenylenebis(salicylaldiminato))cobalt(II)-2-methylimidazole adduct
Brendan J. Kennedy, Gary D. Fallon, Bryan M. K. C. Gatehouse, and Keith S. Murray
pp 580 - 588; DOI:
10.1021/ic00173a019
PDF
Magnetic properties of some spin-crossover, high-spin, and low-spin cobalt(II) complexes with Schiff bases derived from 3-formylsalicylic acid
Jacqueline Zarembowitch and Olivier Kahn
pp 589 - 593; DOI:
10.1021/ic00173a020
PDF
NMR studies of thermochromic transitions in copper(II) and nickel(II) complexes with N,N-diethylethylenediamine
Russell J. Pylkki, Roger D. Willett, and Harold W. Dodgen
pp 594 - 597; DOI:
10.1021/ic00173a021
PDF
Vibrational investigations of polyoxometalates. 3. Isomerism in molybdenum(VI) and tungsten(VI) compounds related to the Keggin structure
Rene Thouvenot, Michel Fournier, Raymonde Franck, and Claude Rocchiccioli-Deltcheff
pp 598 - 605; DOI:
10.1021/ic00173a022
PDF
Crystal and molecular structure of bis[2-(aminocarbonyl)anilinium] dimethyltetrachlorostannate(IV) dihydrate at 138 K: a hydrogen-bonded network lattice
F. A. K. Nasser, M. B. Hossain, D. Van der Helm, and J. J. Zuckerman
pp 606 - 609; DOI:
10.1021/ic00173a023
PDF
Synthesis and structural characterization of a new ruthenium-gold cluster complex: Ru3(.mu.-AuPPh3)(.mu.-Cl)(CO)10
Guy Lavigne, Foune Papageorgiou, and Jean Jacques Bonnet
pp 609 - 613; DOI:
10.1021/ic00173a024
PDF
The molybdenum-molybdenum triple bond. 13. Preparations and characterization of bis(.beta.-diketonato)tetraalkoxydimolybdenum and -ditungsten compounds
M. H. Chisholm, K. Folting, J. C. Huffman, and A. L. Ratermann
pp 613 - 618; DOI:
10.1021/ic00173a025
PDF
Preparation and molecular structure of the nickel(II) perchlorate complex of a hexadentate macrobicyclic ligand, 1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6]eicosane
Myunghyun Paik Suh, Whanchul Shin, Du Sup Kim, and Sang Soo Kim
pp 618 - 620; DOI:
10.1021/ic00173a026
PDF
A centrosymmetric hydrogen-bonded cyclic (H2O.Br-)2 system. Crystal structure of 1-methyl-1,3,5,7-tetraazaadamantan-1-ium bromide hydrate
Thomas C. W. Mak
pp 620 - 622; DOI:
10.1021/ic00173a027
PDF
Nucleophilicity of thiolato sulfur when coordinated to ruthenium(II). Kinetics of the alkylation of (8-mercaptoquinolinato)bis(2,2'-bipyridine)ruthenium(II) by iodomethane
Michael J. Root and Edward Deutsch
pp 622 - 624; DOI:
10.1021/ic00173a028
PDF
.gamma.-Ray-induced linkage isomerization of tetrahedral thiocyanato complexes of iron(II)
Ho Hsiang Wei and Lie Zen Ho
pp 624 - 627; DOI:
10.1021/ic00173a029
PDF
An ab initio study of the heptahydrodiborate (B2H7-) anion
Anne Marie Sapse and Louis Osorio
pp 627 - 628; DOI:
10.1021/ic00173a030
PDF
High-pressure synthesis and magnetic properties of MMnSb (M = Ti, V, Cr) with nickel-indium (Ni2In) type structures
Y. Noda, M. Shimada, and M. Koizumi
pp 628 - 630; DOI:
10.1021/ic00173a031
PDF
Photochemistry in liquid krypton: generation and thermal stability of Fe(CO)(N2)(NO)2 and Fe(N2)2(NO)2
Gerard E. Gadd, Martyn Poliakoff, and James J. Turner
pp 630 - 631; DOI:
10.1021/ic00173a032
PDF
Reactivity of a bridging sulfhydryl ligand, S-alkylation of [Mo(NC6H4CH3)(S2P(OC2H5)2)]2(.mu.-S)(.mu.-SH)(.mu.-O2CCF3), and structure of [Mo(NC6H4CH3)(S2P(OC2H5)2)]2(.mu.-S)(.mu.-SCH3)(.mu.-O2CCF3)
Mark E. Noble, Kirsten Folting, J. C. Huffman, and R. A. D. Wentworth
pp 631 - 634; DOI:
10.1021/ic00173a033
PDF

Issue 6


Thermochemistry of fluoroxy compounds: a linear correlation between oxygen-fluorine bond energies and fluorine-19 chemical shifts
E. Ghibaudi and A. J. Colussi
pp 635 - 636; DOI:
10.1021/ic00174a001
PDF
Kinetics and mechanism of the oxidation of europium(II) ions and of the reduction of europium(III) ions by 2-hydroxy-2-propyl radicals
S. Muralidharan and James H. Espenson
pp 636 - 639; DOI:
10.1021/ic00174a002
PDF
Kinetics of coordinated-base-catalyzed and free-base-catalyzed configurational conversions of a tetraamine macrocyclic ligand complex of copper(II)
Chung Shin Lee and Chung Sun Chung
pp 639 - 644; DOI:
10.1021/ic00174a003
PDF
Some reactions of sulfonyl hypohalites with sulfur tetrafluoride
Brian A. O'Brien and Darryl D. DesMarteau
pp 644 - 648; DOI:
10.1021/ic00174a004
PDF
Carborane reductive-elimination reaction from a six-coordinate hydridocarboranyliridium(III) complex: kinetic and mechanistic study
M. Basato, F. Morandini, B. Longato, and S. Bresadola
pp 649 - 653; DOI:
10.1021/ic00174a005
PDF
Novel fluorosulfate derivatives of germanium(IV) and tin(IV)
S. P. Mallela, K. C. Lee, and F. Aubke
pp 653 - 659; DOI:
10.1021/ic00174a006
PDF
Steric course of base hydrolysis of cis- and trans-[Co(en)2(N3)X]n+ and cis- and trans-[Co(en)2(NCS)X]n+ (X = Br-, Cl-, OS(CH3)2, OCHN(CH3)2, N3-, O2CH-)
W. G. Jackson and C. M. Begbie
pp 659 - 667; DOI:
10.1021/ic00174a007
PDF
Base hydrolysis of [(NH3)5CoX]n+. Capture of sulfur and nitrogen of the thiocyanate ion
W. G. Jackson and C. N. Hookey
pp 668 - 673; DOI:
10.1021/ic00174a008
PDF
Electrochemical characterization of a rhodium(II) dimer with N-phenylacetamido bridging ligands
J. L. Bear, T. P. Zhu, T. Malinski, A. M. Dennis, and K. M. Kadish
pp 674 - 678; DOI:
10.1021/ic00174a009
PDF
Electron-transfer and ligand-addition reactions of (TPP)CrClO4 and (TPP)Cr(NO) in nonaqueous media
S. L. Kelly and K. M. Kadish
pp 679 - 687; DOI:
10.1021/ic00174a010
PDF
Cyclic voltammetric wave symmetry and peak current calculations as confirmation of the reversible, sequential transfer of two electrons at very similar potentials in bis(1,3,5-triketonato)dicopper(II) complexes and their diamine Schiff bases. Comparison between mono- and binuclear complexes and a study of the effect of sodium(1+) and lithium(1+) on the electron-transfer process
R. L. Lintvedt, G. Ranger, and E. A. Schoenfelner
pp 688 - 695; DOI:
10.1021/ic00174a011
PDF
Parametrization of static magnetic susceptibility of a "linear" tetranuclear chromium(III) complex by isotropic Heisenberg-Dirac-Van Vleck Hamiltonians and correlation with structural data
Ture Damhus and Erik Pedersen
pp 695 - 699; DOI:
10.1021/ic00174a012
PDF
Polarized electronic absorption spectra of dichlorotetrakis(.mu.-pivalato)dirhenium(III)
Don S. Martin, Hai Wei Huang, and Robert A. Newman
pp 699 - 701; DOI:
10.1021/ic00174a013
PDF
Helium(He I and He II) photoelectron spectra of nickel(II), palladium(II) and platinum(II) diethyldithiocarbamate complexes
G. Granozzi, A. Vittadini, L. Sindellari, and D. Ajo
pp 702 - 706; DOI:
10.1021/ic00174a014
PDF
Infrared emission spectra of alkali chloroaluminates and related melts
Jan Hvistendahl, Peter Klaeboe, Erling Rytter, and Harald A. Oeye
pp 706 - 715; DOI:
10.1021/ic00174a015
PDF
Lewis-base properties of ortho chlorines in copper(II) 2,4,6-trichlorophenolates, 4-bromo-2,6-dichlorophenolates, and 2,6-dichlorophenolates as studied by chlorine-35 nuclear quadrupole resonance spectroscopy
Gary Wulfsberg, Jim Yanisch, Ron Meyer, John Bowers, and Maria Essig
pp 715 - 719; DOI:
10.1021/ic00174a016
PDF
S-Alkyl (diorganothiophosphinoyl)dithioformate, N-phenyl(diorganophosphino)thioformamide, and N-phenyl(diorganothiophosphinoyl)thioformamide complexes of platinum. Preparation and proton, phosphorus-31, and platinum-195 NMR studies
Stuart W. Carr, Ray Colton, and Dainis Dakternieks
pp 720 - 726; DOI:
10.1021/ic00174a017
PDF
Reexamination of the reactions of Ph2P(CH2)nPPh2 (n = 1-4) with RuCl2(PPh3)3
Chu W. Jung, Philip E. Garrou, Paul R. Hoffman, and Kenneth G. Caulton
pp 726 - 729; DOI:
10.1021/ic00174a018
PDF
Oxo-bridged mixed-oxidation-state complexes of molybdenum: preparation, properties, and x-ray structure of [Mo2O(S2CNEt2)6]BF4 and related compounds
John A. Broomhead, Meta Sterns, and Charles G. Young
pp 729 - 737; DOI:
10.1021/ic00174a019
PDF
Preparation and crystal structure of lanthanum molybdenum silicon oxide (La3MO4SiO14), an unusual cluster compound of molybdenum
P. W. Betteridge, A. K. Cheetham, J. A. K. Howard, G. Jakubicki, and W. H. McCarroll
pp 737 - 740; DOI:
10.1021/ic00174a020
PDF
Trinuclear Fe-M-S complexes containing a linear FeMFe array and a bridging S2MS2 unit. Electronic structures and crystal and molecular structures of the [(C6H5)4P]2[Cl2FeS2MS2FeCl2] (M = Mo, W) complexes
D. Coucouvanis, E. D. Simhon, P. Stremple, M. Ryan, D. Swenson, N. C. Baenziger, A. Simopoulos, V. Papaefthymiou, A. Kostikas, and V. Petrouleas
pp 741 - 749; DOI:
10.1021/ic00174a021
PDF
Theoretical and experimental studies of the electronic structure of the Mo3(.mu.3-O)(.mu.3-OR)(.mu.-OR)3(OR)6 type of triangular metal atom cluster compound
Malcolm H. Chisholm, F. Albert Cotton, Anne Fang, and Edward M. Kober
pp 749 - 754; DOI:
10.1021/ic00174a022
PDF
The molybdenum-molybdenum triple bond. 14. Preparation and characterization of mixed alkoxy-thiolate compounds of formula Mo2(OR)2(SAr)4 (M.tplbond.M)
Malcolm H. Chisholm, James F. Corning, and John C. Huffman
pp 754 - 757; DOI:
10.1021/ic00174a023
PDF
Electronic absorption and magnetic circular dichroism spectra of some planar platinum(II), palladium(II), and nickel(II) complexes with phosphorus-donor ligands
Jose M. Solar, M. Aydin Ozkan, Huseyin Isci, and W. Roy Mason
pp 758 - 764; DOI:
10.1021/ic00174a024
PDF
Preparation, structure, and properties of central-carbon-bonded diethyl malonato complexes of palladium(II) with bis-(.mu.-chloro) and .mu.-oxalato bridges
Toshio Kawato, Tetsuo Uechi, Hiroyuki Koyama, Hajime Kanatomi, and Yumako Kawanami
pp 764 - 769; DOI:
10.1021/ic00174a025
PDF
Homopolyatomic anions of the post transition elements. Synthesis and structure of potassium-crypt salts of the tetraantimonide(2-) and heptaantimonide(3-) anions, Sb42- and Sb73-
Susan C. Critchlow and John D. Corbett
pp 770 - 774; DOI:
10.1021/ic00174a026
PDF
Rate-determining t2g-t2g electron transfer: reaction of (3-formylpentane-2,4-dionato)bis(pentane-2,4-dionato)ruthenium(III) with titanium(III) and formation of (pentane-2,4-dionato)titanium(III)
Barbara H. Berrie and Joseph E. Earley
pp 774 - 778; DOI:
10.1021/ic00174a027
PDF
Metal-assisted, facile syntheses of chelating triphosphine ligands on platinum
Robert D. Waid and Devon W. Meek
pp 778 - 782; DOI:
10.1021/ic00174a028
PDF
Crystal and molecular structure of bis(.mu.-bromo)bis(N,N,N',N'-tetraethylethylenediamine)dicopper(I) and the kinetics of its oxidation by dioxygen in nitrobenzene
Melvyn Rowen Churchill, Geoffrey Davies, Mohamed A. El-Sayed, Jay A. Fournier, John P. Hutchinson, and Jon A. Zubieta
pp 783 - 787; DOI:
10.1021/ic00174a029
PDF
Preparation of activated cobalt and its use for the preparation of octacarbonyldicobalt
G. L. Rochfort and R. D. Rieke
pp 787 - 789; DOI:
10.1021/ic00174a030
PDF
The exchange of cyclopalladated ligands in chloro-bridged palladium(II) complexes
A. D. Ryabov and A. K. Yatsimirskii
pp 789 - 790; DOI:
10.1021/ic00174a031
PDF

Issue 7


Copper(2+) in 5-coordination: a case of a second-order Jahn-Teller effect. 2. Pentachlorocuprate(3-) and other CuIIL5 complexes: trigonal bipyramid or square pyramid?
D. Reinen and C. Friebel
pp 791 - 798; DOI:
10.1021/ic00175a001
PDF
Electronic structure of the nitroxyl complex bis(di-tert-butyl nitroxide)cobalt(II) bromide
Cristiano Benelli, Dante Gatteschi, and Claudia Zanchini
pp 798 - 800; DOI:
10.1021/ic00175a002
PDF
Interaction of dioxygen with binuclear nitride-bridged iron porphyrins
David F. Bocian, Eric W. Findsen, Joseph A. Hofmann, G. Alan Schick, Daniel R. English, David N. Hendrickson, and Kenneth S. Suslick
pp 800 - 807; DOI:
10.1021/ic00175a003
PDF
Stepwise incorporation of copper(II) into a double-ring octaaza macrocycle and consecutive oxidation to the trivalent state
Luigi Fabbrizzi, Fabrizio Forlini, Angelo Perotti, and Barbara Seghi
pp 807 - 813; DOI:
10.1021/ic00175a004
PDF
Adduct formation and electrochemistry of a unipositive nickel(II) macrocycle, [Ni(cyclops)]+
A. W. Addison, B. Watts, and M. Wicholas
pp 813 - 816; DOI:
10.1021/ic00175a005
PDF
Electrochemistry of nickel(II) porphyrins and chlorins
D. Chang, T. Malinski, A. Ulman, and K. M. Kadish
pp 817 - 824; DOI:
10.1021/ic00175a006
PDF
Electron transfer. 67. Reductions of hydroxylamine derivatives by vitamin B12s (cob(I)alamin)
P. N. Balasubramanian and E. S. Gould
pp 824 - 828; DOI:
10.1021/ic00175a007
PDF
Electrochemical studies of graphite oxidation in sodium carbonate melt
Gary B. Dunks
pp 828 - 837; DOI:
10.1021/ic00175a008
PDF
Electron exchange between bis(1,10-phenanthroline)copper(1+) adsorbed on graphite and bis(1,10-phenanthroline)copper(2+) in solution
Chi Woo Lee and Fred C. Anson
pp 837 - 844; DOI:
10.1021/ic00175a009
PDF
Solution equilibria and redox properties of Schiff base complexes of oxomolybdenum(V) in dimethylformamide solution
Julie R. Bradbury, Graeme R. Hanson, Alan M. Bond, and Anthony G. Wedd
pp 844 - 850; DOI:
10.1021/ic00175a010
PDF
Effects of substituted polar groups on ionic association of bis(.beta.-diketonato)(ethylenediamine)cobalt(III) perchlorate complexes in nitrobenzene
Kazuaki Ito, Hiroyuki Isono, Etsuro Iwamoto, and Yuroku Yamamoto
pp 850 - 853; DOI:
10.1021/ic00175a011
PDF
Decomposition of aqueous hexacyanoruthenate(III) ions
Frances M. Crean and Kenneth Schug
pp 853 - 857; DOI:
10.1021/ic00175a012
PDF
Spectroscopic and electrochemical properties of the dimer tetrakis(2,2'-bipyridine)(.mu.-2,3-bis(2-pyridyl)pyrazine)diruthenium(II) and its monomeric analog
Carlos H. Braunstein, A. David Baker, Thomas C. Strekas, and Harry D. Gafney
pp 857 - 864; DOI:
10.1021/ic00175a013
PDF
Resonance Raman spectra and structure of flavins bound to tetraammineruthenium(II)
Michael J. Benecky, Michael G. Dowling, Michael J. Clarke, and Thomas G. Spiro
pp 865 - 869; DOI:
10.1021/ic00175a014
PDF
Infrared and Raman spectra of the hexaaquaruthenium ions: normal-coordinate analysis for Ru(H2O)62+ and Ru(H2O)63+
Paul Bernhard and Andreas Ludi
pp 870 - 872; DOI:
10.1021/ic00175a015
PDF
Low-temperature synthesis and properties of cobalt sulfide (Co9S8), nickel sulfide (Ni3S2), and iron sulfide (Fe7S8)
D. M. Pasquariello, R. Kershaw, J. D. Passaretti, K. Dwight, and A. Wold
pp 872 - 874; DOI:
10.1021/ic00175a016
PDF
Properties of osmium(II) photosensitizers in aqueous and sodium lauryl sulfate micellar media
Walter J. Dressick, Kevin W. Raney, J. N. Demas, and B. A. DeGraff
pp 875 - 880; DOI:
10.1021/ic00175a017
PDF
Optical spectra of exchange-coupled manganese(II) pairs in cesium magnesium trichloride and cesium magnesium tribromide
Paul J. McCarthy and Hans U. Guedel
pp 880 - 887; DOI:
10.1021/ic00175a018
PDF
Mercury-199 NMR study of the mercury cations (Hg2+, Hg22+, Hg32+, and Hg42+): the first example of mercury-mercury spin-spin coupling
Ronald J. Gillespie, Pierre Granger, Keith R. Morgan, and Gary J. Schrobilgen
pp 887 - 891; DOI:
10.1021/ic00175a019
PDF
The pKa and isomer determinations of cobalt(III) imidazole and histidine complexes by NMR and x-ray crystallography
N. R. Brodsky, N. M. Nguyen, N. S. Rowan, C. B. Storm, R. J. Butcher, and E. Sinn
pp 891 - 897; DOI:
10.1021/ic00175a020
PDF
Resolution of a structural disorder through apparently inconsistent x-ray diffraction and EXAFS data: structure of the new layered system manganese copper phosphorus sulfide (Mn1-xCu2x)PS3 (x = 0.13)
Y. Mathey, A. Michalowicz, P. Toffoli, and G. Vlaic
pp 897 - 902; DOI:
10.1021/ic00175a021
PDF
Synthesis and characterization of multiply substituted lacunar macrobicyclic complexes of nickel(II), a representative crystal structure, and preparation of corresponding free ligands
Bohdan Korybut-Daszkiewicz, Massaki Kojima, James H. Cameron, Norman Herron, Madhav Y. Chavan, Alan J. Jircitano, Bradley K. Coltrain, Daryle H. Busch, Gary L. Neer, and Nathaniel W. Alcock
pp 903 - 914; DOI:
10.1021/ic00175a022
PDF
Crystal structure of tetrakis(.mu.-trifluoroacetato)bis(triphenylphosphine)cadmium(II)]: a dimer containing the tetrakis(.mu.-carboxylato)dimetal framework
Tim Allman, Ram C. Goel, N. K. Jha, and Andre L. Beauchamp
pp 914 - 918; DOI:
10.1021/ic00175a023
PDF
Carbon-13 NMR studies on diastereotopic rhodium(III) (.+-.)-2,3-butanediamine complexes and the structure of lel,lel,lel-[Rh((.+-.)-bn)3]Br3
Maria Fe Gargallo, Robert E. Tapscott, and Eileen N. Duesler
pp 918 - 922; DOI:
10.1021/ic00175a024
PDF
Reductive intramolecular hydrogen transfer in a d8 metal hydride promoted by carbon monoxide addition. An experimental study and its theoretical implications
Franco Cecconi, Carlo A. Ghilardi, Paolo Innocenti, Carlo Mealli, Stefano Midollini, and Annabella Orlandini
pp 922 - 929; DOI:
10.1021/ic00175a025
PDF
Crystal and molecular structure of [Cd10(SCH2CH2OH)16](ClO4)4.8H2O. Correlations with cadmium-113 NMR spectra of the solid and implications for cadmium-thiolate ligation in proteins
Serge Lacelle, William C. Stevens, Donald M. Kurtz, James W. Richardson, and Robert A. Jacobson
pp 930 - 935; DOI:
10.1021/ic00175a026
PDF
X-ray crystal structure of a late-transition-metal dialkylamide, [(CuNEt2)4]
Hakon Hope and Philip P. Power
pp 936 - 937; DOI:
10.1021/ic00175a027
PDF
Metal-metal-bonded complexes of the early transition metals. 8. Tertiary alkylphosphine adducts of W2(O2CCF3)4 (W::W)
D. J. Santure, J. C. Huffman, and A P. Sattelberger
pp 938 - 945; DOI:
10.1021/ic00175a028
PDF
A metal-metal-bonded dinuclear phosphine complex of niobium(IV) chloride, [NbCl2(PMe2Ph)2]2(.mu.-Cl)4
F. Albert Cotton and Wieslaw J. Roth
pp 945 - 947; DOI:
10.1021/ic00175a029
PDF
Synthesis, crystal and molecular structure, and spectroscopic properties of tris(2,2'-bipyridyl)iron(II) nitroprusside tetrahydrate, [Fe(bpy)3][Fe(CN)5NO].4H2O
M. E. Garcia Posse, M. A. Juri, P. J. Aymonino, O. E. Piro, H. A. Negri, and E. E. Castellano
pp 948 - 952; DOI:
10.1021/ic00175a030
PDF
Dehalogenation of binuclear arene-ruthenium complexes: a new route to homonuclear triruthenium and heteronuclear ruthenium-iron cluster complexes containing chelating phosphorus ligands. Crystal structure of Ru3(CO)10(Ph2PCH2PPh2)
Anthony W. Coleman, Denis F. Jones, Pierre H. Dixneuf, Colette Brisson, Jean Jacques Bonnet, and Guy Lavigne
pp 952 - 956; DOI:
10.1021/ic00175a031
PDF
Origin of the exceptional reactivity of vanadium pentacarbonyl nitrosyl
Qizhen Shi, Thomas G. Richmond, William C. Trogler, and Fred Basolo
pp 957 - 960; DOI:
10.1021/ic00175a032
PDF
Functionalized isocyanides as ligands. Synthesis of 2-(chloromethyl)- and 2-(iodomethyl)phenyl isocyanides and their transition-metal complexes
Rino A. Michelin, Giacomo Facchin, and Paolo Uguagliati
pp 961 - 969; DOI:
10.1021/ic00175a033
PDF
Molybdenum-95 NMR studies of cis-dinitrosylmolybdenum complexes containing the [Mo(NO)2]2+ unit
Martin Minelli, John L. Hubbard, and John H. Enemark
pp 970 - 973; DOI:
10.1021/ic00175a034
PDF
Enthalpy and entropy changes associated with the ternary complexes of xanthosine in solution
P. Rabindra Reddy, M. Harilatha Reddy, and K. Venugopal Reddy
pp 974 - 978; DOI:
10.1021/ic00175a035
PDF
Redetermination of the hexaaminecobalt(III/II) electron-self-exchange rate
Anders Hammershoi, Daniel Geselowitz, and Henry Taube
pp 979 - 982; DOI:
10.1021/ic00175a036
PDF
Relaxation processes of electronically excited states in polypyridine ruthenium complexes
William R. Cherry and Leslie J. Henderson
pp 983 - 986; DOI:
10.1021/ic00175a037
PDF
First and second ionic association constants of unsymmetrical metal chelate electrolytes from conductance measurements: (1,4,8,11-tetraazacyclotetradecane)nickel(II) tetraphenylborate, perchlorate, and iodide in nitrobenzene at 25.degree.C
Etsuro Iwawmoto, Katsumi Imai, and Yuroku Yamamoto
pp 986 - 988; DOI:
10.1021/ic00175a038
PDF
Preparation and characterization of rhodium(III) polyphosphate complexes
Irene Lin, Wilson B. Knight, Su Jen Ting, and Debra Dunaway-Mariano
pp 988 - 991; DOI:
10.1021/ic00175a039
PDF
Electrochemical studies of [bis(acetylacetone) ethylenediiminato]oxovanadium(IV), VO(acen), and its thioanalog, VS(acen)
R. Seangprasertkij and Thomas L. Riechel
pp 991 - 994; DOI:
10.1021/ic00175a040
PDF

Issue 8


Theoretical characterization of nitrogen fixation: Initial dinitrogen activation
A. K. Rappe
pp 995 - 996; DOI:
10.1021/ic00176a001
PDF
Preparation, structure, and magnetic properties of dimeric copper(II) tribromoacetate adducts. Influence of the substituent R on the magnetic behavior of the series of dimers [Cu(O2CR)2L]2 (R = H, CH3, CF3, CCl3, CBr3)
Leigh C. Porter and Robert J. Doedens
pp 997 - 999; DOI:
10.1021/ic00176a002
PDF
Solution and solid-state cadmium-113 NMR of Cd(.alpha.,.alpha.'-bpy)2X2 (X = Cl-,Br-, NCS-,NO3-,H2O) and crystal structures of the nitrate (monohydrate) and the isothiocyanate derivatives
P. F. Rodesiler, R. W. Turner, N. G. Charles, E. A. H. Griffith, and E. L. Amma
pp 999 - 1004; DOI:
10.1021/ic00176a003
PDF
Synthesis and structure of the imidazolate-bridged dicopper(II) ion in two binucleating macrocycles
Peter K. Coughlin, Andrea E. Martin, John C. Dewan, Eiichi Watanabe, John E. Bulkowski, Jean Marie Lehn, and Stephen J. Lippard
pp 1004 - 1009; DOI:
10.1021/ic00176a004
PDF
Synthetic, structural, and physical studies of titanium complexes of catechol and 3,5-di-tert-butylcatechol
Brandan A. Borgias, Stephen R. Cooper, Yun Bai Koh, and Kenneth N. Raymond
pp 1009 - 1016; DOI:
10.1021/ic00176a005
PDF
Structural studies on polynuclear osmium carbonyl hydrides. 28. Synthesis and structure of (.eta.5-C5H5)WOs3(CO)8(.mu.-O)(.mu.3-.eta.2-C2H2)(.mu.-H), a tetrahedral tungsten-triosmium cluster complex with a unique unsymmetrical (W, Os) edge-bridging oxo ligand
Melvyn Rowen Churchill, Clifford Bueno, Joon T. Park, and John R. Shapley
pp 1017 - 1021; DOI:
10.1021/ic00176a006
PDF
Reactions of metal-metal multiple bonds. 10. Reactions of Mo2(OR)6 (M.tplbond.M) and [Mo(OR)4]x compounds with molecular oxygen. Preparation and characterization of oxo alkoxides of molybdenum: MoO2(OR)2, MoO2(OR)2(bpy), MoO(OR)4, Mo3O(OR)10, Mo4O8(OR)4(py)4, and Mo6O10(OR)12
Malcolm H. Chisholm, Kirsten Folting, John C. Huffman, and Charles C. Kirkpatrick
pp 1021 - 1037; DOI:
10.1021/ic00176a007
PDF
Reactions of metal-metal multiple bonds. 11. A comparison of the reactivity of M2(OR)6 (M.tplbond.M) and M2(OR)4(R'COCHCOR')2 (M.tplbond.M) compounds (M = Mo, W) with the .pi.-acid ligands CO, RC.tplbond.CR and RNC
Malcolm H. Chisholm, James F. Corning, Kirsten Folting, John C. Huffman, Andrew L. Ratermann, Ian P. Rothwell, and William E. Streib
pp 1037 - 1042; DOI:
10.1021/ic00176a008
PDF
Oxy-methoxy compounds of hexavalent molybdenum
E. M. McCarron, R. H. Staley, and A. W. Sleight
pp 1043 - 1045; DOI:
10.1021/ic00176a009
PDF
Synthesis and physicochemical studies of some novel chromium(III) tetraalkoxyaluminates and allied derivatives
Ram C. Mehrotra and Jagvir Singh
pp 1046 - 1048; DOI:
10.1021/ic00176a010
PDF
Interpretation of kinetic data for the reaction of azide with aquapentaamminechromium(III) and the reverse (aquation) reaction
Silvia Castillo-Blum and A. Geoffrey Sykes
pp 1049 - 1052; DOI:
10.1021/ic00176a011
PDF
Mono- and bimetallic cationic dinitrosylmolybdenum complexes
Peter Legzdins and Jimmie C. Oxley
pp 1053 - 1059; DOI:
10.1021/ic00176a012
PDF
Hydrogen bonding in metalloporphyrin reactions. Reaction of (tetraphenylporphinato)iron(III) chloride and imidazole
G. A. Tondreau and D. A. Sweigart
pp 1060 - 1065; DOI:
10.1021/ic00176a013
PDF
Synthesis and properties of substituted (phthalocyaninato)-iron and -cobalt compounds and their pyridine adducts
Josef Metz, Otto Schneider, and Michael Hanack
pp 1065 - 1071; DOI:
10.1021/ic00176a014
PDF
Bonding in transition-metal tetrahydroborates: a multinuclear magnetic resonance study of (C5H5)2Sc(BH4) and Sc(BH4)3 and some comments on the isolobality of BH4-, halide, and .eta.5-C5H5- groups
Mary Mancini, Peter Bougeard, Robert C. Burns, Michael Mlekuz, Brian G. Sayer, J. Ian A. Thompson, and Michael J. McGlinchey
pp 1072 - 1078; DOI:
10.1021/ic00176a015
PDF
Nuclear magnetic resonance studies of stereochemical rearrangements in pentagonal-bipyramidal (.eta.5-cyclopentadienyl)tris(N,N-dimethyldithiocarbamato)titanium(IV), -zirconium(IV), and -hafnium(IV)
Robert C. Fay, John R. Weir, and Alan H. Bruder
pp 1079 - 1089; DOI:
10.1021/ic00176a016
PDF
Proton nuclear magnetic resonance study of N,N-dimethylformamide exchange on (N,N-dimethylformamide)(2,2',2''-tris(dimethylamino)triethylamine)manganese(II) and its cobalt(II) and copper(II) analogs
Stephen F. Lincoln, Andrea M. Hounslow, Dino L. Pisaniello, Bruce G. Doddridge, John H. Coates, Andre E. Merbach, and Donald Zbinden
pp 1090 - 1093; DOI:
10.1021/ic00176a017
PDF
Superconductivity, magnetic susceptibility, and magnetic resonance studies of the pseudobinary systems europium molybdenum sulfide-europium molybdenum selenide (Eu1.2Mo6S8-Eu1.2Mo6Se8) and lanthanum molybdenum selenide-europium molybdenum selenide (LaMo6Se8-EuMo6Se8)
J. M. Tarascon, M. R. Harrison, D. C. Johnson, and M. J. Sienko
pp 1094 - 1100; DOI:
10.1021/ic00176a018
PDF
Electron-transfer quenching of ruthenium(II) photosensitizers by mercury(II) chlorides. 1. Reactions in aqueous solution
B. L. Hauenstein, Krishnagopal Mandal, J. N. Demas, and B. A. DeGraff
pp 1101 - 1107; DOI:
10.1021/ic00176a019
PDF
Electron-transfer quenching of ruthenium(II) photosensitizers by mercury(II) chlorides. 2. Reactions in aqueous sodium lauryl sulfate micellar solutions
W. J. Dressick, B. L. Hauenstein, J. N. Demas, and B. A. DeGraff
pp 1107 - 1113; DOI:
10.1021/ic00176a020
PDF
Helium [He(I) and He(II)] photoelectron spectra and infrared intensity measurements of alkynylmercury(II) compounds: the search for d.pi.-p.pi. interactions
C. Cauletti, C. Furlani, M. N. Piancastelli, A. Sebald, and B. Wrackmeyer
pp 1113 - 1119; DOI:
10.1021/ic00176a021
PDF
Hydrolysis equilibria of tungsten(VI) in aqueous sodium chloride solutions to 300.degree.C
D. Wesolowski, S. E. Drummond, R. E. Mesmer, and H. Ohmoto
pp 1120 - 1132; DOI:
10.1021/ic00176a022
PDF
Kinetics of the reaction of the bis(.mu.-oxalato)bis(.mu.-diacetato)diaquadiruthenium(II,III) anion with hexaaquatitanium(3+)
Rathindra N. Bose, Paul A. Wagner, and Joseph E. Earley
pp 1132 - 1134; DOI:
10.1021/ic00176a023
PDF
Kinetics of the manganese(III)-sulfur(IV) reaction in aqueous perchloric acid solutions
P. A. Siskos, N. C. Peterson, and R. E. Huie
pp 1134 - 1137; DOI:
10.1021/ic00176a024
PDF
Photochemistry and photophysics of aqueous cyanopentaamminechromium(2+) and trans-dicyanotetraamminechromium(1+)
Edoardo Zinato, Arthur W. Adamson, James L. Reed, Jean Pierre Puaux, and Pietro Riccieri
pp 1138 - 1144; DOI:
10.1021/ic00176a025
PDF
Nature of the residual paramagnetic fraction in discontinuous and continuous high-spin(5T2) .dblharw. low-spin(1A1) transitions of iron(II) complexes
E. Konig, G. Ritter, and S. K. Kulshreshtha
pp 1144 - 1148; DOI:
10.1021/ic00176a026
PDF
Covalent bonding in cis-bis(2,2'-bipyridyl)dichloroiron(III) tetrachloroferrate(III)
B. N. Figgis, P. A. Reynolds, and R. Mason
pp 1149 - 1153; DOI:
10.1021/ic00176a027
PDF
Polarized electronic spectra of dirhodium(II) tetraacetate
Vincent M. Miskowski, William P. Schaefer, Behzad Sadeghu Sadeghi, Bernard D. Santarsiero, and Harry B. Gray
pp 1154 - 1162; DOI:
10.1021/ic00176a028
PDF
Hemiporphyrazine, a porphyrin-related macrocycle that induces rhombically compressed stereochemistries: structure and properties of bis(pyridine)(hemiporphyrazinato)nickel(II)
E. Agostinelli, D. Attanasio, I. Collamati, and V. Fares
pp 1162 - 1165; DOI:
10.1021/ic00176a029
PDF
Metal-nitroxyl interactions. 35. Conformational effects on spin-spin interaction in spin-labeled copper salicylaldimines
K. M. More, G. R. Eaton, and S. S. Eaton
pp 1165 - 1170; DOI:
10.1021/ic00176a030
PDF
Structure of the iron pentacarbonyl anion
Alfred B. Anderson and Dae Bok Kang
pp 1170 - 1172; DOI:
10.1021/ic00176a031
PDF
Self-exchange rate for the copper(II)/copper(I) couple complexed to TAAB, an N4 macrocycle
Elizabeth J. Pulliam and David R. McMillin
pp 1172 - 1175; DOI:
10.1021/ic00176a032
PDF
Correlations between core size and wavelength of the .alpha. band for nonhyper metalloporphyrins
J. A. Shelnutt and M. R. Ondrias
pp 1175 - 1177; DOI:
10.1021/ic00176a033
PDF
Resonance Raman spectra of the carbon-bridged iron porphyrin dimer, (.mu.-carbido)bis[(5,10,15,20-tetraphenylporphinato)iron]
Joseph A. Hofmann and David F. Bocian
pp 1177 - 1180; DOI:
10.1021/ic00176a034
PDF

Issue 9


Platinum(II)-catalyzed hydrolysis of pyrophosphate and triphosphate: phosphorus-31 NMR characterization of kinetic intermediates
Rathindra N. Bose, Richard D. Cornelius, and Ronald E. Viola
pp 1181 - 1182; DOI:
10.1021/ic00177a001
PDF
Observation of an intervalence charge-transfer band in a mixed-valence ruthenium dimer bridged by a nonconjugated nitrogen donor ligand
Maureen J. Kendrick Geno and John H. Dawson
pp 1182 - 1183; DOI:
10.1021/ic00177a002
PDF
Redox behavior of blue copper model complexes. Redox potentials and electron-transfer kinetics of some copper(II)-copper(I) complexes with nitrogen and thioether donors
K. D. Karlin and J. K. Yandell
pp 1184 - 1188; DOI:
10.1021/ic00177a003
PDF
New multidentate ligands. 22. N,N'-Dipyridoxylethylenediamine-N,N'-diacetic acid: a new chelating ligand for trivalent metal ions
Christina Hasserodt, Ramunas J. Motekaitis, and Arthur E. Martell
pp 1188 - 1192; DOI:
10.1021/ic00177a004
PDF
Copper(II) complexes of 3,8-dimethyl-4,7-diazadeca-3,7-dienediamide in solution
Meng Chay Lim and Brian J. McCool
pp 1192 - 1194; DOI:
10.1021/ic00177a005
PDF
Solution properties of bis(dipeptide)nickelate(III) complexes and kinetics of their decomposition in acid
Stephen A. Jacobs and Dale W. Margerum
pp 1195 - 1201; DOI:
10.1021/ic00177a006
PDF
Coordination tendencies of a series of tetraazacycloalkanes related to 1,4,7,10-tetraazadecane (trien): synthetic, thermodynamics, and structural aspects
Antonio Bianchi, Lucia Bologni, Paolo Dapporto, Mauro Micheloni, and Piero Paoletti
pp 1201 - 1205; DOI:
10.1021/ic00177a007
PDF
A convenient route for the synthesis of complex metal oxides employing solid-solution precursors
K. Vidyasagar, J. Gopalakrishnan, and C. N. R. Rao
pp 1206 - 1210; DOI:
10.1021/ic00177a008
PDF
Oxide salt reactions in matrix isolation: infrared spectra of the Tl+2SO32- and Tl+2S2O52- triple ions
Shelle J. David and Bruce S. Ault
pp 1211 - 1215; DOI:
10.1021/ic00177a009
PDF
EXAFS studies of amorphous molybdenum and tungsten trisulfides and triselenides
S. P. Cramer, K. S. Liang, A. J. Jacobson, C. H. Chang, and R. R. Chianelli
pp 1215 - 1221; DOI:
10.1021/ic00177a010
PDF
Electronic structures of transition-metal tetrachalcogenides (MSe4)nI (M = Nb, Ta)
Pascal Gressier, Myung Hwan Whangbo, Alain Meerschaut, and Jean Rouxel
pp 1221 - 1228; DOI:
10.1021/ic00177a011
PDF
Band structure of niobium tetratelluride (NbTe4)
Myung Hwan Whangbo and Pascal Gressier
pp 1228 - 1232; DOI:
10.1021/ic00177a012
PDF
Photophysical studies of uranyl complexes. 4. X-ray photoelectron and luminescence studies of hydrolyzed uranyl salts
Dale L. Perry, Leon Tsao, and Harry G. Brittain
pp 1232 - 1237; DOI:
10.1021/ic00177a013
PDF
Reaction dynamics and hydroxide ion quenching of rhodium(III) ligand field excited states: photoreactions of iodopentaamminerhodium(2+)
Mark E. Frink, Douglas Magde, Douglas Sexton, and Peter C. Ford
pp 1238 - 1240; DOI:
10.1021/ic00177a014
PDF
Nature of the continuous high-spin (5T2) .dblharw. low-spin (1A1) transition in the acetone solvate of dichlorobis[cis-1,2-bis(diphenylphosphino)ethylene]iron(II). Coupling with the order-disorder transition of acetone molecules
E. Koenig, G. Ritter, S. K. Kulshreshtha, J. Waigel, and L. Sacconi
pp 1241 - 1246; DOI:
10.1021/ic00177a015
PDF
Nuclear magnetic resonance studies of the solution chemistry of metal complexes. 20. Ligand-exchange kinetics of methylmercury(II)-thiol complexes
Dallas L. Rabenstein and R. Stephen Reid
pp 1246 - 1250; DOI:
10.1021/ic00177a016
PDF
New topological electron-counting theory
Boon K. Teo
pp 1251 - 1257; DOI:
10.1021/ic00177a017
PDF
Applications of topological electron-counting theory to polyhedral metal clusters
Boon K. Teo, G. Longoni, and F. R. K. Chung
pp 1257 - 1266; DOI:
10.1021/ic00177a018
PDF
Steric and electronic control of the Arbuzov reaction in transition metal halides: proton and phosphorus-31 NMR study of the reaction of [CpCo(LL)X]+ complexes (LL = N, P, As chelate ligands; X- = Cl-, Br-, I-, CN-) with P(OMe)3
Shayne J. Landon and Thomas B. Brill
pp 1266 - 1271; DOI:
10.1021/ic00177a019
PDF
Technetium electrochemistry. 2. Electrochemical and spectroelectrochemical studies of the bis(tertiary phosphine) (D) complexes trans-[TcIIID2X2]+ (X =chlorine or bromine)
Akio Ichimura, William R. Heineman, Jean Luc Vanderheyden, and Edward Deutsch
pp 1272 - 1278; DOI:
10.1021/ic00177a020
PDF
Matrix-isolation studies of alkali-metal and thallium perrhenates. IR spectrum of oxygen-18 enriched thallium perrhenate and dimerization of the MReO4 species
L. Bencivenni, H. M. Nagarathna, D. W. Wilhite, and K. A. Gingerich
pp 1279 - 1285; DOI:
10.1021/ic00177a021
PDF
Charge-transfer-induced IR absorptions in mixed-valence compounds
K. Y. Wong
pp 1285 - 1290; DOI:
10.1021/ic00177a022
PDF
Rhodium-rhodium bond protonation in [Rh2Cl2(.mu.-CO)(Ph2PCH2PPh2)2] and the structure of an unusual oxidative-addition product, [Rh2Cl3(.mu.-H)(.mu.-CO)(Ph2PCH2PPh2)2].cntdot.H2O
Bruce R. Sutherland and Martin Cowie
pp 1290 - 1297; DOI:
10.1021/ic00177a023
PDF
Stereoisomers of a tetraamine macrocyclic ligand complex of nickel(II)
Chung Shin Lee, Shei Yeh Wu, and Chung Sun Chung
pp 1298 - 1303; DOI:
10.1021/ic00177a024
PDF
Preparation and characterization of low-spin iron(II) porphyrin complexes with bis(phosphine) or bis(phosphite) axial ligands
Toshie Ohya, Hiromi Morohoshi, and Mitsuo Sato
pp 1303 - 1305; DOI:
10.1021/ic00177a025
PDF
Characterization of the charge density waves in niobium triselenide (NbSe3) by band electronic structure
Myung Hwan Whangbo and Pascal Gressier
pp 1305 - 1306; DOI:
10.1021/ic00177a026
PDF

Issue 10


Factors affecting metal-metal interactions in binuclear complexes. Synthesis and structure of the face-to-face complex trans-Rh(CO)Cl(.mu.-Ph2AsCH2PPh2)2-cis-PtCl2
Rosalvina R. Guimerans, Fred E. Wood, and Alan L. Balch
pp 1307 - 1308; DOI:
10.1021/ic00178a001
PDF
Ambient- and low-temperature crystal structure of vanadyl hydrogen phosphate (VO)2H4P2O9
C. C. Torardi and J. C. Calabrese
pp 1308 - 1310; DOI:
10.1021/ic00178a002
PDF
EPR and optical spectra of tetrachlorocuprate(2-) doped into single crystals of several zinc(II) host lattices
Robert J. Deeth, Michael A. Hitchman, Gerhard Lehmann, and Hubert Sachs
pp 1310 - 1320; DOI:
10.1021/ic00178a003
PDF
Metal-nitroxyl interactions. 36. Single-crystal EPR spectra of two copper porphyrins spin labeled with five-membered nitroxyl rings
Reddy Damoder, Kundalika M. More, Gareth R. Eaton, and Sandra S. Eaton
pp 1320 - 1326; DOI:
10.1021/ic00178a004
PDF
Metal-nitroxyl interactions. 37. Single-crystal EPR spectra of a spin-labeled copper complex containing an imine-urea linkage
Reddy Damoder, Kundalika M. More, Gareth R. Eaton, and Sandra S. Eaton
pp 1326 - 1330; DOI:
10.1021/ic00178a005
PDF
Proton transfer and nucleophilic displacement reactions of copper(II) N,N'-diglycylethylenediaminate
P. K. Mitchell and Gordon K. Pagenkopf
pp 1330 - 1334; DOI:
10.1021/ic00178a006
PDF
Thermodynamic study and stabilities of complex dicerium carbide molecules
J. E. Kingcade, D. L. Cocke, and K. A. Gingerich
pp 1334 - 1338; DOI:
10.1021/ic00178a007
PDF
Electron self-exchange by hexakis(cyclohexyl isocyanide)manganese(I/II): solvent, electrolyte, and temperature dependences
Roger Nielson and Scot Wherland
pp 1338 - 1344; DOI:
10.1021/ic00178a008
PDF
Electron-transfer kinetics of the reactions between copper(III,II) and nickel(III,II) deprotonated-peptide complexes
Grove D. Owens, David A. Phillips, John J. Czarnecki, John M. T. Raycheba, and Dale W. Margerum
pp 1345 - 1353; DOI:
10.1021/ic00178a009
PDF
Complexes of titanium tetrachloride of interest in Friedel-Crafts reactions
Liang K. Tan and Sydney Brownstein
pp 1353 - 1355; DOI:
10.1021/ic00178a010
PDF
A nuclear magnetic resonance study of the kinetics of ligand-exchange reactions in uranyl complexes. 4. Intramolecular-exchange reaction of methyl groups of acetylacetonate in UO2(acac)2L with L = Me2S:O, Me2N:COH, and Et2N:COH
Yasuhisa Ikeda, Hiroshi Tomiyasu, and Hiroshi Fukutomi
pp 1356 - 1360; DOI:
10.1021/ic00178a011
PDF
Photolysis of the tantalum cluster Ta6Br122+ in aqueous acidic solution
Arnd Vogler and Horst Kunkely
pp 1360 - 1363; DOI:
10.1021/ic00178a012
PDF
Synthesis of bimetallic iron-nickel carbonyl clusters: crystal structure of the iron-nickel carbonyl cluster [N(CH3)3CH2Ph][Fe3Ni(CO)8(.mu.-CO)4(.mu.3-H)]
Allesandro Ceriotti, Paolo Chini, Allesandro Fumagalli, Thomas F. Koetzle, Giuliano Longoni, and Fusao Takusagawa
pp 1363 - 1368; DOI:
10.1021/ic00178a013
PDF
Synthesis and stereochemistry of some alkyl[bis(trimethylsilyl)amino]boranes
Bei Li Li, Mary A. Goodman, and Robert H. Neilson
pp 1368 - 1371; DOI:
10.1021/ic00178a014
PDF
Oxidation and methylation reactions of P-H-substituted (silylamino)phosphines
H. Randy O'Neal and Robert H. Neilson
pp 1372 - 1377; DOI:
10.1021/ic00178a015
PDF
Structural chemistry of pentacoordinated silicon. Molecular structures of the pentafluorosilicate anion and the diphenyltrifluorosilicate anion
Dietmar Schomburg and Roland Krebs
pp 1378 - 1381; DOI:
10.1021/ic00178a016
PDF
Higher valent manganese chemistry. Synthetic, structural, and solution studies on [Mn(catecholate)3]n- (n = 2, 3) complexes
JudithAnn R. Hartman, Bruce M. Foxman, and Stephen R. Cooper
pp 1381 - 1387; DOI:
10.1021/ic00178a017
PDF
Synthesis and crystal structure of bis(.mu.-hydroxo)bis[oxo(1,4,7-triazacyclononane)vanadium(IV)] dibromide, a .mu.-hydroxo-bridged cation with antiferromagnetically coupled vanadium(IV) centers
Karl Wieghardt, Ursula Bossek, Klaus Volckmar, Wolfgang Swiridoff, and Johannes Weiss
pp 1387 - 1389; DOI:
10.1021/ic00178a018
PDF
Synthesis and characterization of edge-double-bridged Ru3(.mu.-H,.mu.-X)(CO)10 (X = Cl, Br, I) and face-triple-bridged Ru3(.mu.-H,.mu.3-I)(CO)9. Crystal and molecular structure of Ru3(.mu.-H,.mu.-Br)(CO)10, Ru3(.mu.-I)2(CO)10 and Ru3(.mu.-H,.mu.3-I)(CO)9
Carsten E. Kampe, Neil M. Boag, Carolyn B. Knobler, and Herbert D. Kaesz
pp 1390 - 1397; DOI:
10.1021/ic00178a019
PDF
Metal complexes of fluorophosphines. 13. Reaction of fac-tris(acetonitrile)molybdenum tricarbonyl (fac-(CH3CN)3Mo(CO)3) with (methylamino)bis(difluorophosphine). X-ray crystal structure analysis of a novel binuclear molybdenum fluorophosphine carbonyl complex with a bridging chlorine atom: (CO)2Mo[.mu.-CH3N(PF2)2]2(.mu.-PF2)(.mu.-Cl)Mo(CO)(PF2NHCH3)
R. B. King, M. Shimura, and George M. Brown
pp 1398 - 1404; DOI:
10.1021/ic00178a020
PDF
Synthesis, spectroscopic characterization, and magnetic properties of unusual 3,5-dialkyl-1,2,4-triazole compounds containing N-bridging isothiocyanato ligands. X-ray structure of trinuclear bis[(.mu.-thiocyanato-N)bis(.mu.-3,5-diethyl-1,2,4-triazole-N1,N2)bis(thiocyanato-N)(3,5-diethyl-1,2,4-triazole-N1)nickel(II)-N,N1,N1']nickel(II) dihydrate
Gerard A. Van Albada, Rudolf A. G. De Graaff, Jaap G. Haasnoot, and Jan Reedijk
pp 1404 - 1408; DOI:
10.1021/ic00178a021
PDF
Synthesis and characterization of copper(I), copper(II), zinc(II), cobalt(II), and iron(II) complexes of a chelating ligand derived from 2,6-diacetylpyridine and L-histidine. Oxygenation of the copper(I), cobalt(II), and iron(II) complexes. Crystal structure of the zinc(II) complex
Luigi Casella, Michael E. Silver, and James A. Ibers
pp 1409 - 1418; DOI:
10.1021/ic00178a022
PDF
Coordination behavior of 4-toluensulfonamide derivatives: thermal and spectroscopic properties of (N-tosylglycinato)(2,2'-bipyridine)copper(II) complexes. Crystal and molecular structure of (ethanol)(N-tosylglycinato)(2,2'-bipyridine)copper(II)
L. Antolini and L. Menabue
pp 1418 - 1422; DOI:
10.1021/ic00178a023
PDF
Single-crystal x-ray and spectroscopic studies on the complex aquo(tris[(3,5-dimethyl-1-pyrazolyl)methyl]amine)cobalt(II) perchlorate. A spectroscopic model of cobalt-substituted carbonic anhydrase
Cristiano Benelli, Ivano Bertini, Massimo Di Vaira, and Fabrizio Mani
pp 1422 - 1425; DOI:
10.1021/ic00178a024
PDF
X-ray structural characterization of [Cr(CNPh)6][CF3SO3], [Cr(CNPh)6][PF6]2, and [Cr(CNPh)6][SbCl6]3.CH2Cl2. Completion of a unique series of complexes in which the metal attains four different oxidation states while maintaining identical ligation
David A. Bohling and Kent R. Mann
pp 1426 - 1432; DOI:
10.1021/ic00178a025
PDF
Dinuclear aryloxide chemistry. 2. Synthesis and structure of 2,6-dimethylphenoxide complexes of dimolybdenum (Mo.tplbond.Mo)
Timothy W. Coffindaffer, Ian P. Rothwell, and John C. Huffmann
pp 1433 - 1436; DOI:
10.1021/ic00178a026
PDF
Complex formation of lanthanide polyaminopolycarboxylates
P. K. Tse, J. E. Powell, M. W. Potter, and H. R. Burkholder
pp 1437 - 1440; DOI:
10.1021/ic00178a027
PDF
Photosubstitution reactions of Ru(bpy)2XYn+ complexes
David V. Pinnick and Bill Durham
pp 1440 - 1445; DOI:
10.1021/ic00178a028
PDF
Magnetic, ESR, electrochemical, and potentiometric titration studies of the imidazolate-bridged dicopper(II) ion in a binucleating macrocycle
Peter K. Coughlin and Stephen J. Lippard
pp 1446 - 1451; DOI:
10.1021/ic00178a029
PDF
Electron-transfer and ligand-addition reactions of (TTP)Mn(NO) and (TTP)Co(NO) in a nonaqueous media
S. Kelly, D. Lancon, and K. M. Kadish
pp 1451 - 1458; DOI:
10.1021/ic00178a030
PDF
Moessbauer and Raman spectroscopic studies of substituted pyridinium bromoantimonate(III) compounds
Sheila W. Hedges and L. H. Bowen
pp 1458 - 1463; DOI:
10.1021/ic00178a031
PDF
Acid-base properties of .alpha.-ribazole and the thermodynamics of dimethylbenzimidazole association in alkylcobalamins
Kenneth L. Brown, Janette M. Hakimi, Debra M. Nuss, Yolanda D. Montejano, and Donald W. Jacobsen
pp 1463 - 1471; DOI:
10.1021/ic00178a032
PDF
Stereochemical aspects of the thermal substitution reactions of cobalt(III) complexes
L. G. Vanquickenborne and K. Pierloot
pp 1471 - 1478; DOI:
10.1021/ic00178a033
PDF
Reinterpretations, based on tungsten-183 NMR spectra, of several heteropolytungstates derived from the Wells-Dawson "2:18" structure. Preparation and structure proof for the first .gamma.-isomer of a 2:18 complex
Rafael Acerete, Charles F. Hammer, and Louis C. W. Baker
pp 1478 - 1482; DOI:
10.1021/ic00178a034
PDF
Rearrangement of closo-3,3-(PPh3)2-3-H-1-(R)-3,1,2-IrC2B9H10 to closo-2,2-(PPh3)2-2-H-8-(R)-2,1,8-IrC2B9H10. Synthesis and x-ray structure of closo-2,2-(PPh3)2-2-H-8-(C6H5)-2,1,8-IrC2B9H10
James A. Doi, Eugene A. Mizusawa, Carolyn B. Knobler, and M. Frederick Hawthorne
pp 1482 - 1484; DOI:
10.1021/ic00178a035
PDF
Synthesis and stereochemistry of dichlororhodium(III) complexes of ethylenediamine-N,N'-di-S-.alpha.-propionic acid
Mary Ellen Foss Sheridan, Moo Jin Jun, and Chui Fan Liu
pp 1485 - 1487; DOI:
10.1021/ic00178a036
PDF
N,N',N",N'''-Tetrabis(2-hydroxyethyl)cyclam a nitrogen-donor macrocycle with rapid metalation reactions
Claire M. Madeyski, Joseph P. Michael, and Robert D. Hancock
pp 1487 - 1489; DOI:
10.1021/ic00178a037
PDF
Reversible binding of dinitrogen and dihydrogen by (.eta.6-phenylmethylphenylphosphine)tris(methyldiphenylphosphine)molybdenum (Mo(.eta.6-PhPMePh)(PMePh2)3): use of [9-BBN]2 as a phosphine sponge reagent
Rudy Luck and Robert H. Morris
pp 1489 - 1491; DOI:
10.1021/ic00178a038
PDF
Determination of equilibrium constants for the tetrachloroaluminate ion dissociation in ambient-temperature ionic liquids
Zenon J. Karpinski and Robert A. Osteryoung
pp 1491 - 1494; DOI:
10.1021/ic00178a039
PDF

Issue 11


Synthesis and characterization of the first ansa-cyclotriphosphazene
Paul J. Harris and Kenneth B. Williams
pp 1495 - 1496; DOI:
10.1021/ic00179a001
PDF
Activation of oxygen and mediation of DNA degradation by manganese-bleomycin
Guy M. Ehrenfeld, Natesan Murugesan, and Sidney M. Hecht
pp 1496 - 1498; DOI:
10.1021/ic00179a002
PDF
Relation between the electronic structure and the condensation of metal clusters in M5X4 compounds
Vijay Kumar and Volker Heine
pp 1498 - 1500; DOI:
10.1021/ic00179a003
PDF
Rhodium-103 NMR spectrum of [(Rh2(mhp)4)2]: the first measurement of 1J(rhodium-103, rhodium-103) for a [Rh2]4+ core
C. D. Garner, M. Berry, and B. E. Mann
pp 1500 - 1501; DOI:
10.1021/ic00179a004
PDF
Synthesis and characterization of a technetium phosphite complex: hexakis(trimethyl phosphite)technetium(I) tetraphenylborate
Dennis W. Wester, David H. White, Fred W. Miller, and Richard T. Dean
pp 1501 - 1502; DOI:
10.1021/ic00179a005
PDF
Reactions of coordinated dinitrogen. 15. Isolation and characterization of a molybdenum-containing product in a hydrazine-forming reaction
T. Adrian George and Daniel B. Howell
pp 1502 - 1503; DOI:
10.1021/ic00179a006
PDF
Tetraphenyl derivatives of phosphorus, arsenic, and antimony: exchange reaction and reduction. Crystal and molecular structure of dioxane-sodium-diphenylarsenic complex ([(C4H8O2)NaAsPh2]n), an extended array containing substantially linear sodium-arsenic-sodium bonds
Antonio Belforte, Fausto Calderazzo, Antonino Morvillo, Giancarlo Pelizzi, and Dario Vitali
pp 1504 - 1508; DOI:
10.1021/ic00179a007
PDF
Coordination modes of polydentate ligands. 2. Template synthesis of four-, five-, and six-coordinate fluorinated Schiff-base complexes of nickel(2+): structure of an octahedral nickel(2+) complex containing two tridentate ligands
Stephen J. Loeb, Douglas W. Stephan, and Christopher J. Willis
pp 1509 - 1512; DOI:
10.1021/ic00179a008
PDF
A novel synthetic route to "iron trihydroxide, Fe(OH)3": characterization and magnetic properties
Steve C. F. Au-Yeung, Georges Denes, J. E. Greedan, Donald R. Eaton, and Thomas Birchall
pp 1513 - 1517; DOI:
10.1021/ic00179a009
PDF
Kinetics and mechanism of the reaction of (.mu.-peroxo)bis[(bis(salicyaldehyde)ethylenediiminato)cobalt(III)] with cyanide and thiocyanate ions
Steve C. F. Au-Yeung and Donald R. Eaton
pp 1517 - 1520; DOI:
10.1021/ic00179a010
PDF
The structures of atom clusters. Nido, arachno, hypho and planar aromatic molecules
Brian W. Clare and David L. Kepert
pp 1521 - 1525; DOI:
10.1021/ic00179a011
PDF
Electrochemical studies of sulfur-nitrogen compounds. 1. The trisulfur trinitride and tetrasulfur pentanitride anions and further investigations of tetrasulfur tetranitride
T. Chivers and M. Hojo
pp 1526 - 1530; DOI:
10.1021/ic00179a012
PDF
Formation and x-ray crystal structures of (Ph2PN)2[NS(O)NPPh2NPPh2NH2] and Et2NH2+ [(Ph2PN)2(NSO2)]- from the aerial hydrolysis of (Ph2PN)2(NSNR2) (R = Me, Et)
T. Chivers, M. N. S. Rao, and J. F. Richardson
pp 1531 - 1535; DOI:
10.1021/ic00179a013
PDF
Photoelectron spectra and molecular properties. 107. The isomers of trifluoromethyl isocyanide and trifluoroacetonitrile: photoelectron spectra, thermal rearrangement, and effects of fluorine substitution on parent molecules C2H3N
H. Bock, R. Dammel, and D. Lentz
pp 1535 - 1540; DOI:
10.1021/ic00179a014
PDF
Cyano-bridged ruthenium(II)/platinum(II) complexes: synthesis, photophysical properties, and excited-state redox behavior
Carlo Alberto Bignozzi and Franco Scandola
pp 1540 - 1545; DOI:
10.1021/ic00179a015
PDF
Electronic excited states of arylphosphine complexes of copper(I) halides
Dennis J. Fife, William M. Moore, and Karen W. Morse
pp 1545 - 1549; DOI:
10.1021/ic00179a016
PDF
Electron spin resonance spectra of low-symmetry rare-earth complexes: tetraphenylarsonium pentakis(nitrato)ytterbate(III)
W. Urland and R. Kremer
pp 1550 - 1553; DOI:
10.1021/ic00179a017
PDF
Investigation of complex equilibria in solution by EPR spectroscopy
Harald Gampp
pp 1553 - 1557; DOI:
10.1021/ic00179a018
PDF
Equilibrium constants of chromium(III) and chromium(II) inner-hand outer-sphere complexes with chloride, bromide and iodide ions
Piotr K. Wrona
pp 1558 - 1562; DOI:
10.1021/ic00179a019
PDF
Bidentate linkage isomerization and phosphate hydrolysis in (triphosphato)tetraamminecobalt(III)
Joseph Reibenspies and Richard D. Cornelius
pp 1563 - 1565; DOI:
10.1021/ic00179a020
PDF
Magnetic circular dichroism spectra for the intense UV bands of the tetrachloro- and tetrabromoplatinate(II) ions
Huseyin Isci and W. Roy Mason
pp 1565 - 1569; DOI:
10.1021/ic00179a021
PDF
Structures and energies of lithium amide dimers and trimers: an ab initio study
Ann Marie Sapse, Elmar Kaufmann, Paul v. R. Schleyer, and Rolf Gleiter
pp 1569 - 1574; DOI:
10.1021/ic00179a022
PDF
Investigation of zinc-67 coordination effects on the nitrogen-15 NMR spectra of coordinated ligands
Brad P. Bammel and R. F. Evilia
pp 1574 - 1576; DOI:
10.1021/ic00179a023
PDF
Are the pre-lanthanides similar to the lanthanide ions in aqueous methanol?
Herbert B. Silber and Tomasz Mioduski
pp 1577 - 1583; DOI:
10.1021/ic00179a024
PDF
Electrooxidation of dirhodium(II) tetracarboxylate-nitrogenous base adducts
Lawrence A. Bottomley and Timothy A. Hallberg
pp 1584 - 1587; DOI:
10.1021/ic00179a025
PDF
Anion binding in macrobicyclic metal cryptate complexes: copper(II)-BISTREN
Ramunas J. Motekaitis, Arthur E. Martell, Bernard Dietrich, and Jean Marie Lehn
pp 1588 - 1591; DOI:
10.1021/ic00179a026
PDF
Quantitative estimates of steric effects. Intramolecular strain-energy effects on the stability and dissociation rate constants of polythia ether macrocycle complexes of copper(II)
George R. Brubaker and David W. Johnson
pp 1591 - 1595; DOI:
10.1021/ic00179a027
PDF
Reactions of metal-metal multiple bonds. 12. Reactions of organic halides (chloride, bromide, iodide) with hexaalkoxydimolybdenum and -ditungsten (M.tplbond.M) compounds. Preparation and characterization of hexaneopentoxydibromo(pyridine)dimolybdenum (M:M)
Malcolm H. Chisholm, John C. Huffman, Andrew L. Ratermann, and Crystal Smith
pp 1596 - 1599; DOI:
10.1021/ic00179a028
PDF
Decacarbonylnitrosyltriosmate(3 Os-Os)(1-): structural analysis and fluxional properties
Brian F. G. Johnson, Jack Lewis, Julian M. Mace, Paul R. Raithby, Robert E. Stevens, and Wayne L. Gladfelter
pp 1600 - 1603; DOI:
10.1021/ic00179a029
PDF
Preparative, structural, and spectroscopic studies of tetrakis(carboxylato)ditungsten(II) compounds with tungsten-tungsten quadruple bonds
F. Albert Cotton and Wenning Wang
pp 1604 - 1610; DOI:
10.1021/ic00179a030
PDF
Formation of isomeric dimolybdenum(II) compounds using the potentially ambidentate ligands [R2PC(S)NR']- (R/R' = Ph/Ph, Ph/Me) and [Me2NC(S)NPh]-
H. P. M. M. Ambrosius, F. A. Cotton, L. R. Falvello, H. T. J. M. Hintzen, T. J. Melton, W. Schwotzer, M. Tomas, and J. G. M. Van der Linden
pp 1611 - 1616; DOI:
10.1021/ic00179a031
PDF
Isolation and characterization of [Zn2(O2CCH3)3][Mo3O2(O2CCH3)6(OCH3)3].2H2O, an anionic trimolybdenum(IV) cluster compound containing an unusual cation
Amira Birnbaum, F. Albert Cotton, Zvi Dori, and Moshe Kapon
pp 1617 - 1619; DOI:
10.1021/ic00179a032
PDF
Anisotropic exchange in transition-metal dinuclear complexes. 2. Crystal and molecular structure and EPR spectra of a dinuclear copper oxamidato complex
A. Bencini, M. Di Vaira, A. C. Fabretti, D. Gatteschi, and C. Zanchini
pp 1620 - 1623; DOI:
10.1021/ic00179a033
PDF
Binuclear Schiff base complexes of m-xylylenebis[2-(1,3-propanediylbis(2-pyridinecarbaldimine))] and m-xylylenebis[2-(1,3-propanediylbis(2-pyrrolecarbaldimine))]
Bryan C. Whitmore and Richard Eisenberg
pp 1624 - 1629; DOI:
10.1021/ic00179a034
PDF
The four-electron oxidation of a novel .alpha.-oxo dimer, [((p-Et2N)TPP)Fe]2O
D. Chang, P. Cocolios, Y. T. Wu, and K. M. Kadish
pp 1629 - 1633; DOI:
10.1021/ic00179a035
PDF
.sigma. Vs. .pi. bonding in organoactinides and possibilities of cocoordination to actinides
Kazuyuki Tatsumi and Roald Hoffmann
pp 1633 - 1634; DOI:
10.1021/ic00179a036
PDF

Issue 12


Nature of .gamma.-alumina-supported molybdenum subcarbonyls from cross polarization-magic angle spinning carbon-13 NMR spectroscopy
Brian E. Hanson, George W. Wagner, Robert J. Davis, and Edwin Motell
pp 1635 - 1636; DOI:
10.1021/ic00180a001
PDF
Iridium-nitrogen bond cleavage in the photolysis of carbonylnitrosylbis(triphenylphosphine)iridium
Mitsuru Kubota, Michael K. Chan, and L. Keith Woo
pp 1636 - 1638; DOI:
10.1021/ic00180a002
PDF
Reactions of uranium(V), neptunium(V), and plutonium(V) with the carbonate radical ion
W. A. Mulac, S. Gordon, K. H. Schmidt, D. Wester, and J. C. Sullivan
pp 1639 - 1641; DOI:
10.1021/ic00180a003
PDF
Hypersensitivity in the 4f .fwdarw. 4f absorption spectra of neodymium(III) complexes in aqueous solution
Eileen M. Stephens, Karl Schoene, and F. S. Richardson
pp 1641 - 1648; DOI:
10.1021/ic00180a004
PDF
Europium(III) luminescence excitation spectroscopy. A species-specific method for the quantitation of lanthanide ion binding to chelating agents. Complexes of (1,2-ethanediyldioxy)diacetate
Michael Albin, Gregory K. Farber, and William DeW. Horrocks
pp 1648 - 1651; DOI:
10.1021/ic00180a005
PDF
Spectroscopic investigation of the multidentate coordination equilibrium among conformational isomers of tris(2,2', 2"-terpyridyl)europium(III) perchlorate in acetonitrile
Robert D. Chapman, Richard T. Loda, James P. Riehl, and Robert W. Schwartz
pp 1652 - 1657; DOI:
10.1021/ic00180a006
PDF
Intramolecular electron transfer at metal surfaces. 1. Relative energetics of some corresponding outer- and inner-sphere pathways involving halide and pseudohalide bridging ligands
Stephen W. Barr and Michael J. Weaver
pp 1657 - 1663; DOI:
10.1021/ic00180a007
PDF
Intramolecular electron transfer at metal surfaces. 2. Comparisons of ligand-bridged chromium(III) reduction kinetics at silver vs. mercury electrodes
Kendall L. Guyer and Michael J. Weaver
pp 1664 - 1670; DOI:
10.1021/ic00180a008
PDF
Electrochemical oxidation of spin-admixed S = 5/2, 3/2 iron(III) porphyrins: in situ characterization by deuterium NMR spectroscopy
Arden D. Boersma and Harold M. Goff
pp 1671 - 1676; DOI:
10.1021/ic00180a009
PDF
Ligand field spectrum and the electronic structure of the hexacyanochromate(3-) ion
L. G. Vanquickenborne, L. Haspeslagh, M. Hendrickx, and J. Verhulst
pp 1677 - 1684; DOI:
10.1021/ic00180a010
PDF
Solution equilibria of tertiary phosphine complexes of copper(I) halides
Dennis J. Fife, William M. Moore, and Karen W. Morse
pp 1684 - 1691; DOI:
10.1021/ic00180a011
PDF
Preparation and characterization of chromium(III) and cobalt(III) complexes of adenosine 5'-O-(1-thiodiphosphate)
Irene Lin, Amy Hsueh, and Debra Dunaway-Mariano
pp 1692 - 1697; DOI:
10.1021/ic00180a012
PDF
Flexibly bridged binuclear rhodium and iridium complexes of p-xylylenebis(3-(2,4-pentanedione))
Bryan C. Whitmore and Richard Eisenberg
pp 1697 - 1703; DOI:
10.1021/ic00180a013
PDF
Altruism revisited: gas electron diffraction study of tris(trifluoromethyl)phosphine oxide, OP(CF3)3, and ab initio molecular orbital calculations on X3CY and X3CY(O) systems (X = H, F; Y = PH2, SH, Cl)
Colin J. Marsden
pp 1703 - 1708; DOI:
10.1021/ic00180a014
PDF
Ruthenium(IV) in centrosymmetric RuX2N2O2 coordination: synthesis, structure, and redox properties of dihalobis(triazene 1-oxidato)ruthenium species
Samaresh Bhattacharya, Animesh Chakravorty, F. Albert Cotton, Rabindranath Mukherjee, and Willi Schwotzer
pp 1709 - 1713; DOI:
10.1021/ic00180a015
PDF
Tridentate 1-methyluracil in a tetranuclear Pt2,Ag2 complex. Crystal structure and solution behavior of bis(.mu.-1-methyluracilato)bis(cis-diammineplatinum(II))disilver tetranitrate-2-water (head-tail), cis-[(NH3)2Pt(C5H5N2O2)Ag]2(NO3)4.cntdot.2H2O
Ulf Thewalt, Dietmar Neugebauer, and Bernhard Lippert
pp 1713 - 1718; DOI:
10.1021/ic00180a016
PDF
Paramagnetic hydride complexes of niobium(IV) and tantalum(IV)
M. L. Luetkens, W. L. Elcesser, J. C. Huffman, and A. P. Sattelberger
pp 1718 - 1726; DOI:
10.1021/ic00180a017
PDF
Electrochemical studies of antimony(III) and antimony(V) in molten mixtures of aluminum chloride and butylpyridinium chloride
Dhia A. Habboush and Robert A. Osteryoung
pp 1726 - 1734; DOI:
10.1021/ic00180a018
PDF
Reaction of chloride ions in low-temperature molten salts and application to the study of complex ion stoichiometry
Marek Lipsztajn and Robert A. Osteryoung
pp 1735 - 1739; DOI:
10.1021/ic00180a019
PDF
Decamethylvanadocene chemistry: synthesis, structure, and reactions of vanadium(II) and vanadium(III) derivatives with carbon monoxide and isocyanides
Sandro Gambarotta, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 1739 - 1747; DOI:
10.1021/ic00180a020
PDF
Incorporation of redox couples into p-chlorosulfonated polystyrene coated electrodes by chemical binding
Charles D. Ellis and Thomas J. Meyer
pp 1748 - 1756; DOI:
10.1021/ic00180a021
PDF
Heteronuclear NMR studies of cobalamins. 2. Carbon-13 and phosphorus-31 NMR studies of [13C]cyanocobalamin
Kenneth L. Brown and Janette M. Hakimi
pp 1756 - 1764; DOI:
10.1021/ic00180a022
PDF
Influence of ligand structure on the mechanism of oxidation of dithioethers by copper(II). X-ray crystal structure of bis(2-hydroxy-1,5-dithiacyclooctane)copper(II) perchlorate
W. K. Musker, M. M. Olmstead, and R. M. Kessler
pp 1764 - 1768; DOI:
10.1021/ic00180a023
PDF
Pulsed-laser conductivity and emission study of some chromium(III) amine complex ions in acidic and alkaline aqueous media
William L. Waltz, Jochen Lilie, and Sang H. Lee
pp 1768 - 1775; DOI:
10.1021/ic00180a024
PDF
Boron analogs of amino acids. 3. Synthesis of (ethylcarbamoyl)borane adducts of trimethylamine, dimethylamine, methylamine, and ammonia
Bernard F. Spielvogel, Fahim U. Ahmed, Karen W. Morse, and Andrew T. McPhail
pp 1776 - 1777; DOI:
10.1021/ic00180a025
PDF
EPR studies of the formation of low-spin dimethoxo(tetraphenylporphinato)ferrate(III) in solution
Tomoko Otsuka, Toshie Ohya, and Mitsuo Sato
pp 1777 - 1779; DOI:
10.1021/ic00180a026
PDF
Further examples of binuclear phosphido-bridged complexes of rhodium(I). Evidence for bridge-cleavage reactions
Eric W. Burkhardt, William C. Mercer, and Gregory L. Geoffrey
pp 1779 - 1782; DOI:
10.1021/ic00180a027
PDF
Higher coordinate cyanide and isocyanide complexes. Part 21. Synthesis and structure of [(.eta.5-C5H5)Nb(CNCMe3)4Cl][NbOCl4(THF)].THF
Helen C. Aspinall, Michael M. Roberts, and Stephen J. Lippard
pp 1782 - 1784; DOI:
10.1021/ic00180a028
PDF
Structures of trans-bis[(phenylazo)acetaldoximato]platinum(II) and -palladium(II): a case of nonplanar tetracoordination in a bis complex of palladium(II)
Debkumar Bandyopadhyay, Pinaki Bandyopadhyay, Animesh Chakravorty, F. Albert Cotton, and Larry R. Falvello
pp 1785 - 1787; DOI:
10.1021/ic00180a029
PDF
Additions and Corrections - Synthesis, Crystal and Molecular Structure, and Spectroscopic Properties of Tris(2,2' -bipyridyl)iron(II) Nitroprusside Tetrahydrate [Fe(bpy)3][Fe(CN)5NO]-4H2O.
M. E. Garcia Posse, M. A. Juri, P. J. Aymonino, O. E. Piro, H. A. Negri, and E. E. Castellano
pp 1788 - 1788; DOI:
10.1021/ic00180a600
PDF
Additions and Corrections - Reversible Binding of Dinitrogen and Dihydrogen by Mo(η6-PhPMePh)(PMePh2)3. Use of [9-BBN]2 as a Phosphine Sponge Reagent.
Rudy Luck, and Robert H. Morris
pp 1788 - 1788; DOI:
10.1021/ic00180a601
PDF

Issue 13


In Memorium: Earl Muetterties

pp 1789 - 1789; DOI:
10.1021/ic181a600
PDF
Synthetic metals based on bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF): synthesis, structure (T = 298 and 125 K) and NMR of (BEDT-TTF)2X, X = ReO4- and BrO4-
Jack M. Williams, Mark A. Beno, Hau H. Wang, Peter E. Reed, Larry J. Azevedo, and James E. Schirber
pp 1790 - 1792; DOI:
10.1021/ic00181a001
PDF
Synthesis and characterization of carbonylpentacyanocobaltate(III)
R. Palmans, L. Viaene, and J. D'Olieslager
pp 1792 - 1793; DOI:
10.1021/ic00181a002
PDF
Oxidation of peroxotitanium(IV) by chlorine and cerium(IV) in acidic perchlorate solution
Richard C. Thompson
pp 1794 - 1798; DOI:
10.1021/ic00181a003
PDF
Action of strong acids on M2(O2CR)4 species
Joshua Telser and Russell S. Drago
pp 1798 - 1803; DOI:
10.1021/ic00181a004
PDF
Nickel(II) complexes of diamino diamides in aqueous solution
Si Han Liu and Chung Sun Chung
pp 1803 - 1806; DOI:
10.1021/ic00181a005
PDF
Reactions of coordinated molecules. 36. Crystal and molecular structure of a rhenaacetylacetonate anion as the benzamidinium salt
P. Galen Lenhert, C. M. Lukehart, Peter D. Sotiropoulos, and K. Srinivasan
pp 1807 - 1810; DOI:
10.1021/ic00181a006
PDF
Synthesis, structure, electrochemistry, and ligand activity of the dioxobis(.mu.-sulfido)bis(dithiocarbamato)dimolybdenum(V) complex
Nepal C. Howlader, Gilbert P. Haight, Trevor W. Hambley, Michael R. Snow, and Geoffrey A. Lawrence
pp 1811 - 1815; DOI:
10.1021/ic00181a007
PDF
Synthetic route to [Fe6S9(SR)2]4- clusters (R = alkyl). Their spectroscopic and magnetic properties and the solid-state structures of [Fe6S9(SCH2Ph)2]4- and [(Fe6S9(SMe)2)2Na2]6-
Henry Strasdeit, Bernt Krebs, and Gerald Henkel
pp 1816 - 1825; DOI:
10.1021/ic00181a008
PDF
Gas-phase electron-diffraction study of tetrafluorosulfidotungsten(VI)
David A. Rice, Kolbjoern Hagen, Lise Hedberg, Kenneth Hedberg, Garry M. Staunton, and John H. Holloway
pp 1826 - 1828; DOI:
10.1021/ic00181a009
PDF
Low-temperature neutron diffraction analysis of [Rh4(.eta.5-C5Me5)4H4][BF4]2
John S. Ricci, Thomas F. Koetzle, Robin J. Goodfellow, Pablo Espinet, and Peter M. Maitlis
pp 1828 - 1831; DOI:
10.1021/ic00181a010
PDF
Gas-phase ultraviolet photoelectron studies of octahedral tris(pyrazol-1-yl)borate complexes of some divalent transition metals
Giovanni Bruno, Gabriele Centineo, Enrico Ciliberto, Santo Di Bella, and Ignazio Fragala
pp 1832 - 1836; DOI:
10.1021/ic00181a011
PDF
Ligand steric effects on the photophysics of bis- and tris(2,2'-bipyridine) complexes of rhodium(III)
M. Nishizawa, T. M. Suzuki, S. Sprouse, R. J. Watts, and P. C. Ford
pp 1837 - 1841; DOI:
10.1021/ic00181a012
PDF
Charge-transfer spectra and photochemistry of the hexakis(isothiocyanato)ferrate(III) ion at cryogenic temperatures in diluent crystals
Ian M. Walker and Paul J. McCarthy
pp 1842 - 1845; DOI:
10.1021/ic00181a013
PDF
Redox and spectral properties of monooxo polypyridyl complexes of ruthenium and osmium in aqueous media
Kenneth J. Takeuchi, Mark S. Thompson, David W. Pipes, and Thomas J. Meyer
pp 1845 - 1851; DOI:
10.1021/ic00181a014
PDF
Influence of the metal centers on the pKa of the pyrrole hydrogen of imidazole complexes of (NH3)53+, M(III) = Co(III), Rh(III), Ir(III), Ru(III)
M. Fazlul Hoq and Rex E. Shepherd
pp 1851 - 1858; DOI:
10.1021/ic00181a015
PDF
Influence of oxygen insertion on the electrochemistry of chromium(III) dithiocarbamate complexes
A. M. Bond and G. G. Wallace
pp 1858 - 1865; DOI:
10.1021/ic00181a016
PDF
Kinetics and mechanism of some fast substitution reactions of a series of methyl-substituted dien complexes of palladium(II) in aqueous solution
E. L. J. Breet and R. Van Eldik
pp 1865 - 1869; DOI:
10.1021/ic00181a017
PDF
Cobalt(III) complex catalyzed hydrolysis of phosphorus esters
Richard A. Kenley, Ronald H. Fleming, Richard M. Laine, Doris S. Tse, and John S. Winterle
pp 1870 - 1876; DOI:
10.1021/ic00181a018
PDF
Gas-phase ion chemistry of zinc atoms and ions
John E. Bartmess and John G. Kester
pp 1877 - 1880; DOI:
10.1021/ic00181a019
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Vanadium(II) pair excitations in cesium magnesium vanadium chloride (CsMg1-xVxCl3)
Hans Riesen and Hans U. Guedel
pp 1880 - 1885; DOI:
10.1021/ic00181a020
PDF
An iron-57 and antimony-121 Moessbauer-effect study of several spinel antimonates
Fernande Grandjean, Gary J. Long, Geoffrey Longworth, and Brian J. Laundy
pp 1886 - 1895; DOI:
10.1021/ic00181a021
PDF
The discontinuous high-spin (5T2) .dblharw. low-spin (1A1) transition in solid bis(1,10-phenanthroline-2-carbaldehyde phenylhydrazone)iron(II) bis(tetrafluoroborate): hysteresis effects, concurrent crystallographic phase change, entropy of the transition, and effect of pressure
E. Koenig, G. Ritter, S. K. Kulshreshtha, J. Waigel, and H. A. Goodwin
pp 1896 - 1902; DOI:
10.1021/ic00181a022
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Moessbauer effect and x-ray diffraction at the high-spin (5T2) .dblharw. low-spin(1A1) transition in bis(thiocyanato)bis(4,7-dimethyl-1,10-phenanthroline)iron(II)-.alpha.-picoline: thermal hysteresis, associated crystallographic phase change, time dependence of 5T2 .fwdarw. 1A1 transition, particle size effects and related phenomena
E. Koenig, G. Ritter, S. K. Kulshreshtha, and N. Csatary
pp 1903 - 1910; DOI:
10.1021/ic00181a023
PDF
Iodine-127 Moessbauer study of some phenyl-iodine compounds and the alkane-activating manganese porphyrin complexes containing iodosylbenzene ligands
Thomas Birchall, John A. Smegal, and Craig L. Hill
pp 1910 - 1913; DOI:
10.1021/ic00181a024
PDF
Raman spectroscopy of neptunyl and plutonyl ions in aqueous solution: hydrolysis of neptunium(VI) and plutonium(VI) and disproportionation of plutonium(V)
C. Madic, G. M. Begun, D. E. Hobart, and R. L. Hahn
pp 1914 - 1921; DOI:
10.1021/ic00181a025
PDF
Solubility of magnesium hydrogen phosphate trihydrate and ion-pair formation in the system magnesium hydroxide-phosphoric acid-water at 25.degree.C
R. M. H. Verbeeck, P. A. M. De Bruyne, F. C. M. Driessens, and F. Verbeek
pp 1922 - 1926; DOI:
10.1021/ic00181a026
PDF
Electrochemical study of tungsten chloro complex chemistry in the basic aluminum chloride-1-methyl-3-ethylimidazolium chloride ionic liquid
Towner B. Scheffler and Charles L. Hussey
pp 1926 - 1932; DOI:
10.1021/ic00181a027
PDF
Stability and structure for monomeric cadmium(II) and zinc(II) complexes of the 5'-triphosphates of adenosine and cytidine in aqueous solution: isomeric equilibria in binary and ternary complexes
Helmut Sigel, Kurt H. Scheller, and Ronald M. Milburn
pp 1933 - 1938; DOI:
10.1021/ic00181a028
PDF
Preparation, characterization, and outer-sphere electron-transfer reactions of nickel complexes of 1,4,7-triazacyclononane
A. McAuley, P. R. Norman, and O. Olubuyide
pp 1938 - 1943; DOI:
10.1021/ic00181a029
PDF
Reactivity of haloruthenocene(IV) complexes
Terrance P. Smith, Keh Shin Kwan, Henry Taube, Avi Bino, and Shmuel Cohen
pp 1943 - 1945; DOI:
10.1021/ic00181a030
PDF
Oxidative addition of halogens to 1,3- and 1,5-(Ph2PN)2(SN)2: x-ray crystal structure of 1,5-(Ph2PN)2(NSBr)2 and a comparison of the crystal structures of the 12-membered ring 1,3,7,9-(Ph2PN)4(SN)2 and the corresponding dication (Ph2PN)4(SN)22+
N. Burford, T. Chivers, M. N. S. Rao, and J. F. Richardson
pp 1946 - 1952; DOI:
10.1021/ic00181a031
PDF
Dimagnesium iron(II) hydride, Mg2FeH6, containing octahedral FeH64- anions
J. J. Didisheim, P. Zolliker, K. Yvon, P. Fischer, J. Schefer, M. Gubelmann, and A. F. Williams
pp 1953 - 1957; DOI:
10.1021/ic00181a032
PDF
Spectroscopy and structure of thiolate and thioether complexes of copper(II) and the relationship of their redox chemistry to that of certain copper proteins
Anthony W. Addison, T. Nageswara Rao, and Ekkehard Sinn
pp 1957 - 1967; DOI:
10.1021/ic00181a033
PDF
Evidence for a strong similarity in conformational and phosphorus-31 NMR parameters between two series of trans-[(tert-C4H9)2PX]2M(CO)Cl complexes [M = Rh(I), Ir(I); X = H, CH3, C2H5, n-C4H9, C6H5]
C. Hackett Bushweller, Christopher D. Rithner, and David J. Butcher
pp 1967 - 1970; DOI:
10.1021/ic00181a034
PDF
Control of spin state in (porphinato)iron(III) complexes. Effect of the porphyrin ligand
David K. Geiger and W. Robert Scheidt
pp 1970 - 1972; DOI:
10.1021/ic00181a035
PDF
Molecular structure of bis[bis(trimethylsilyl)amino]zinc as determined by gas electron diffraction
Arne Haaland, Kenneth Hedberg, and Philip P. Power
pp 1972 - 1975; DOI:
10.1021/ic00181a036
PDF
A selenium-77 and tellurium-125 NMR study of the Te2Se62+ cation: magnetic inequivalence of heavy nuclei
Michael J. Collins and Ronald J. Gillespie
pp 1975 - 1978; DOI:
10.1021/ic00181a037
PDF
Proton NMR studies on six-coordinated "high-spin" iron(III) porphyrins
D. V. Behere, R. Birdy, and S. Mitra
pp 1978 - 1981; DOI:
10.1021/ic00181a038
PDF
Electronic spectrum of the planar S4N3+ cation
M. Trsic and W. G. Laidlaw
pp 1981 - 1982; DOI:
10.1021/ic00181a039
PDF
Optical absorption and ESR spectra of monomeric rhodium(II) tetraphenylporphyrin in 2-methyltetrahydrofuran solution at 77 K
Mikio Hoshino, Katsutoshi Yasufuku, Shiro Konishi, and Masashi Imamura
pp 1982 - 1984; DOI:
10.1021/ic00181a040
PDF
EPR spectroscopy of mixed-valence .mu.-oxo-bridged manganese(III)/manganese(IV) porphyrin complexes
Mark J. Camenzind, Bruce C. Schardt, and Craig L. Hill
pp 1984 - 1986; DOI:
10.1021/ic00181a041
PDF
Preparation and aquation kinetics of (acetonitrile)pentaaquachromium(III)
D. Jordan, W. C. Kupferschmidt, and R. B. Jordan
pp 1986 - 1988; DOI:
10.1021/ic00181a042
PDF
Electron transfer. 68. Mediation by N-substituted isonicotinoyl derivatives
M. S. Ram, J. R. Barber, and E. S. Gould
pp 1988 - 1990; DOI:
10.1021/ic00181a043
PDF
In Memorium: Earl Muetterties
Roald Hoffman
pp 1789 - 1789; DOI:
10.1021/ic00181a600
PDF

Issue 14


Formation of a hydrogen oxide bridging ligand in the hydrolysis of a mononuclear iron(III) complex: support by Moessbauer spectroscopy
Carl J. Carrano and K. Spartalian
pp 1993 - 1994; DOI:
10.1021/ic00182a001
PDF
Low-valent teflates: preparation and characterization of pentacarbonylmanganese teflate (Mn(CO)5(OTeF5))
Steven H. Strauss, Kent D. Abney, Kim M. Long, and Oren P. Anderson
pp 1994 - 1995; DOI:
10.1021/ic00182a002
PDF
Control of the rate of the electrochemical oxidation of the dimeric aquamolybdenum(III) cation by the rate of its deprotonation
Mark T. Paffett and Fred C. Anson
pp 1996 - 1999; DOI:
10.1021/ic00182a003
PDF
Generation of metallocarboxylic acid anions in the gas phase
Kelley R. Lane, Larry Sallans, and Robert R. Squires
pp 1999 - 2000; DOI:
10.1021/ic00182a004
PDF
Coordination of 9-methylhypoxanthine to [cis-Pt(NH3)2]2+ and [Pt(dien)]2+ as studied by proton NMR
Jeroen H. J. Den Hartog, Marianne L. Salm, and Jan Reedijk
pp 2001 - 2005; DOI:
10.1021/ic00182a005
PDF
Coordination chemistry of microbial iron transport compounds. 26. Dimeric dialkoxo-bridged iron(III) complexes of linear dihydroxamate ligands
Susan J. Barclay, Paul E. Riley, and Kenneth N. Raymond
pp 2005 - 2010; DOI:
10.1021/ic00182a006
PDF
Coordination chemistry of microbial iron transport compounds. 27. Dimeric iron(III) complexes of dihydroxamate analogs of rhodotorulic acid
Susan J. Barclay, Boi Hanh Huynh, and Kenneth N. Raymond
pp 2011 - 2018; DOI:
10.1021/ic00182a007
PDF
Paramagnetic organometallic molecules. 16. ESR studies of cobalt acetylene .pi. complexes: a new class of fluxional organocobalt radicals
Louis V. Casagrande, Taicheng Chen, Philip H. Rieger, Brian H. Robinson, Jim Simpson, and Steven J. Visco
pp 2019 - 2025; DOI:
10.1021/ic00182a008
PDF
Electronic structure of (.mu.-H)Cr2(CO)10-
Charles J. Eyermann and Alice Chung-Phillips
pp 2025 - 2029; DOI:
10.1021/ic00182a009
PDF
Gas-phase bihalide and pseudobihalide ions. An ion cyclotron resonance determination of hydrogen bond energies in XHY- species (X, Y = F, Cl, Br, CN)
J. W. Larson and T. B. McMahon
pp 2029 - 2033; DOI:
10.1021/ic00182a010
PDF
Pressure effects on the photophysical and photochemical properties of the rhodium(III) ion Rh(NH3)5Cl2+ in nonaqueous solvents
W. Weber, J. DiBenedetto, H. Offen, R. Van Eldik, and P. C. Ford
pp 2033 - 2038; DOI:
10.1021/ic00182a011
PDF
Volume profiles for the base hydrolysis of a series of pentaamminecobalt(III) complex ions in aqeuous solution
Y. Kitamura, R. Van Eldik, and H. Kelm
pp 2038 - 2043; DOI:
10.1021/ic00182a012
PDF
Luminescence lifetimes of aqueous europium chloride, nitrate, sulfate, and perchlorate solutions. Studies on the nature of the inner coordination sphere of europium(III) ion
Fujio Tanaka and Shigeru Yamashita
pp 2044 - 2046; DOI:
10.1021/ic00182a013
PDF
Modification of silicon and carbon electrodes with methacrylamide polymers containing covalently attached molybdenum dinitrogen complexes
Daniel L. DuBois
pp 2047 - 2052; DOI:
10.1021/ic00182a014
PDF
Electrochemical oxidation of tetrakis(1,8-diisocyanomenthane)dirhodium(2+) in nonaqueous solutions: a net two-electron oxidation process
Matthew R. Rhodes and Kent R. Mann
pp 2053 - 2058; DOI:
10.1021/ic00182a015
PDF
Coordinatively saturated fluoro cations. Oxidative fluorination reactions with fluorokrypton(1+) salts and platinum hexafluoride (PtF6)
Karl O. Christe, William W. Wilson, and Richard D. Wilson
pp 2058 - 2063; DOI:
10.1021/ic00182a016
PDF
Reactions of mono(disilylamino)phosphines with carbon tetrachloride
Randal R. Ford, Mary A. Goodman, Robert H. Neilson, Aroop K. Roy, Urszula G. Wettermark, and Patty Wisian-Neilson
pp 2063 - 2068; DOI:
10.1021/ic00182a017
PDF
Structural approach to the behavior of perchlorate as a ligand in transition-metal complexes using EXAFS, IR and Raman spectroscopy. 1. A perchlorate-bridged copper chain with short copper-copper distances in copper(II) perchlorate
J. L. Pascal, J. Potier, D. J. Jones, J. Roziere, and A. Michalowicz
pp 2068 - 2073; DOI:
10.1021/ic00182a018
PDF
Synthesis and structure of Co6(.mu.6-C2)(.mu.-CO)6(CO)8(.mu.4-S): first example of a peripheral dicarbide metal carbonyl cluster
G. Gervasio, R. Rossetti, and P. L. Stanghellini
pp 2073 - 2079; DOI:
10.1021/ic00182a019
PDF
Crystal and molecular structures of alkali- and alkaline-earth-metal complexes of N,N-dimethylformamide
C. Pulla Rao, A. Muralikrishna Rao, and C. N. R. Rao
pp 2080 - 2085; DOI:
10.1021/ic00182a020
PDF
Crystal structures of tetrakis (.mu.-formato)dimolybdenum(II)-potassium chloride and two new polymorphs of tetrakis(.mu.-formato)dimolybdenum(II). Single-crystal optical absorption spectra for systems with the molybdenum(II) formate dimers
Gary A. Robbins and Don S. Martin
pp 2086 - 2093; DOI:
10.1021/ic00182a021
PDF
Lithium intercalation compounds of yttrium and gadolinium monochloride: synthesis and structure
Jeff E. Ford, Gerd Meyer, and John D. Corbett
pp 2094 - 2098; DOI:
10.1021/ic00182a022
PDF
Solvent dependence of metal-to-ligand charge-transfer transitions. Evidence for initial electron localization in MLCT excited states of 2,2'-bipyridine complexes of ruthenium(II) and osmium(II)
Edward M. Kober, B. Patrick Sullivan, and Thomas J. Meyer
pp 2098 - 2104; DOI:
10.1021/ic00182a023
PDF
Synthetic routes to luminescent 2,2'-bipyridyl complexes of rhenium: preparation and spectral and redox properties of mono(bipyridyl) complexes of rhenium(III) and rhenium(I)
Jonathan V. Caspar, B. Patrick Sullivan, and Thomas J. Meyer
pp 2104 - 2109; DOI:
10.1021/ic00182a024
PDF
Preparation, spectroscopic properties, and reactivity of trans-hydridoaryl and trans-hydridomethyl complexes of platinum(II)
Dennis P. Arnold and Martin A. Bennett
pp 2110 - 2116; DOI:
10.1021/ic00182a025
PDF
Spectroscopic studies and correlation analysis of substituent effects in arylplatinum(II) complexes: cis and trans influences of aryl ligands
Dennis P. Arnold and Martin A. Bennett
pp 2117 - 2124; DOI:
10.1021/ic00182a026
PDF
Fluorosulfates of the noble metals. 5. Fluorosulfato derivatives of platinum(IV) and the fluorosulfuric acid-platinum fluorosulfate (Pt(SO3F)4) superacid system
K. C. Lee and F. Aubke
pp 2124 - 2130; DOI:
10.1021/ic00182a027
PDF
Structural and mechanistic studies of coordination compounds. 39. Successful application of the Marcus theory in predicting rate constants of some outer-sphere reductions of trans-dihalogenotetraamineruthenium(III) cations by europium(II)
Chung Kwong Poon and Tin Wu Tang
pp 2130 - 2132; DOI:
10.1021/ic00182a028
PDF
Kinetics and mechanism of oxidation of methyl ethyl ketone and cyclohexanone by potassium bis(tellurato)cuprate(III)
Ganesh Prasad Panigrahi and A. C. Pathy
pp 2133 - 2138; DOI:
10.1021/ic00182a029
PDF
Anisotropic exchange in transition-metal dinuclear complexes. 3. Bis(.mu.-(1,3-azido)bis(1,1,4,7,7-pentamethyldiethylenetriamine)dicopper(II) bis(tetraphenylborate)
L. Banci, A. Bencini, and D. Gatteschi
pp 2138 - 2141; DOI:
10.1021/ic00182a030
PDF
Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) complexes. 5. Syntheses, spectroscopic properties, and reactivity of Ru2(CO)5(alkyl-DAB), a key intermediate in the Ru3(CO)12-alkyl-DAB reaction. Crystal and molecular structure of (1,4-diisopropyl-1,4-diaza-1,3-butadiene)pentacarbonyldiruthenium, Ru2(CO)5(isopropyl-DAB)
Jan Keijsper, Louis Polm, Gerard Van Koten, and Kees Vrieze
pp 2142 - 2148; DOI:
10.1021/ic00182a031
PDF
Preparation, crystal structure, and spectroscopic characterization of [NEt4]2[Cu(SPh)3]
C. David Garner, John R. Nicholson, and William Clegg
pp 2148 - 2150; DOI:
10.1021/ic00182a032
PDF
Electronic properties of hexaaquaruthenium(III): EPR and optical spectra of Ru(H2O)63+ in alum crystals
Paul Bernhard, Anton Stebler, and Andreas Ludi
pp 2151 - 2155; DOI:
10.1021/ic00182a033
PDF
Photophysics of metal carbonyl complexes. Excited states of a series of cis-M(CO)4L2 complexes (M = Cr, Mo, or W; L = pyridine or a pyridine derivative)
Samuel Chun, Edward G. Getty, and Alistair J. Lees
pp 2155 - 2160; DOI:
10.1021/ic00182a034
PDF
Early stages of the hydrolysis of chromium(III) in aqueous solution. 2. Kinetics and mechanism of the interconversion between two tetrameric species
Hans Stunzi, Francois P. Rotzinger, and Werner Marty
pp 2160 - 2164; DOI:
10.1021/ic00182a035
PDF
Solution chemistry of lanthanide complexes. 7. Terbium(III) and europium(III) complexes of (S,S)-ethylenediamine-N,N'-disuccinic acid
Laura Spaulding and Harry G. Brittain
pp 2165 - 2170; DOI:
10.1021/ic00182a036
PDF
Iron(III) complexation by desferrioxamine B in acidic aqueous solutions. Kinetics and mechanism of the formation and hydrolysis of the binuclear complex diferrioxamine B
Mladen Birus, Zdravko Bradic, Nikola Kujundzic, and Marijan Pribanic
pp 2170 - 2175; DOI:
10.1021/ic00182a037
PDF
Electrochemical and spectrophotometric studies of iron complexes with a pentaaza macrocyclic ligand
Yih Wen D. Chen and Allen J. Bard
pp 2175 - 2181; DOI:
10.1021/ic00182a038
PDF
Electron transfer. 69. Mediation by phenylglyoxylate
W. Faye Hollaway, Vangalur S. Srinivasan, and Edwin S. Gould
pp 2181 - 2185; DOI:
10.1021/ic00182a039
PDF
Systematic design of chemical oscillators. 18. Reaction between permanganate ion and chlorine(III): kinetics and mechanism of the initial reaction and the dissociation of chlorous acid
Christine Ahlstrom, Donald W. Boyd, Irving R. Epstein, Kenneth Kustin, and John H. Romanow
pp 2185 - 2188; DOI:
10.1021/ic00182a040
PDF
Some reactions of (fluoroimido)tetrafluorosulfur
Brian A. O'Brien and Darryl D. DesMarteau
pp 2188 - 2195; DOI:
10.1021/ic00182a041
PDF
Chemistry of bipyridyl-like ligands. 3. Complexes of ruthenium(II) with 2-((4-nitrophenyl)azo)pyridine
Ronald A. Krause and Kirsten Krause
pp 2195 - 2198; DOI:
10.1021/ic00182a042
PDF
Photochemistry of the cis- and trans-dibromobis(ethylenediamine)ruthenium(III) cations
Mark E. Rerek and Peter S. Sheridan
pp 2198 - 2201; DOI:
10.1021/ic00182a043
PDF
(Trifluoromethanesulfonato)pentaammineruthenium(III): a relatively labile synthetic intermediate
Berta Anderes, Sally T. Collins, and David K. Lavallee
pp 2201 - 2203; DOI:
10.1021/ic00182a044
PDF
[(Ph2MeP)3Cu(NC)2BH2] and P3Cu(NC)2BH2 (P3 = 1,1,1-Tris((diphenylphosphino)methyl)ethane): the first metal complexes of dicyanodihydroborate
Paul G. Egan, David G. Holan, and Karen W. Morse
pp 2203 - 2204; DOI:
10.1021/ic00182a045
PDF
Studies of ion pairing for salts of [M3(.mu.-H,.mu.-CO)(CO)10]- (M = Fe, Ru)
K. P. Schick, N. L. Jones, P. Sekula, N. M. Boag, J. A. Labinger, and Herbert D. Kaesz
pp 2204 - 2207; DOI:
10.1021/ic00182a046
PDF
Iridium complexes of (diphenylphosphino)ethanethiol. Crystal and molecular structure [IrH(SCH2CH2PPh2)(HSCH2CH2PPh2)(CO)]+Cl-: a new and novel example of thiol coordination
Douglas W. Stephan
pp 2207 - 2210; DOI:
10.1021/ic00182a047
PDF
Mechanistic organometallic photochemistry: observation of metastable ruthenocenium in photolysis of ruthenocene
J. Granifo and G. Ferraudi
pp 2210 - 2212; DOI:
10.1021/ic00182a048
PDF

Issue 15


Magnetic ordering in the linear-chain antiferromagnet potassium aquapentafluoroferrate(III)
Richard L. Carlin, Ramon Burriel, J. A. Rojo, and Fernando Palacio
pp 2213 - 2215; DOI:
10.1021/ic00183a001
PDF
DNA degradation by manganese(II)-bleomycin plus peroxide
Richard M. Burger, Jonathan H. Freedman, Susan Band Horwitz, and Jack Peisach
pp 2215 - 2217; DOI:
10.1021/ic00183a002
PDF
Pentafluoroselenium isocyanate and pentafluorotellurium isocyanate, Fe5SeN:C:O and Fe5TeN:C:O
Peter Huppmann, Gerhard Kloeter, Joseph S. Thrasher, Konrad Seppelt, and Darryl D. DesMarteau
pp 2217 - 2219; DOI:
10.1021/ic00183a003
PDF
Hypochlorite chlorination of tertiary amine-boranes
Henry C. Kelly, Sritana C. Yasui, and Andrea B. Twiss-Brooks
pp 2220 - 2223; DOI:
10.1021/ic00183a004
PDF
Equilibria and kinetics of complexation of bidentate ligands with the macrocyclic complex Ni([14]aneN4)2+
E. J. Billo
pp 2223 - 2227; DOI:
10.1021/ic00183a005
PDF
Equilibrium and kinetic studies of substitution reactions of Fe(TIM)XY2+ in aqueous solution
Alison Butler and R. G. Linck
pp 2227 - 2231; DOI:
10.1021/ic00183a006
PDF
Kinetics of aqueous outer-sphere electron-transfer reactions of superoxide ion. Implications concerning the dioxygen/superoxide (O2/O2-) self-exchange rate constant
M. Steven McDowell, James H. Espenson, and Andreja Bakac
pp 2232 - 2236; DOI:
10.1021/ic00183a007
PDF
Solid-state kinetic parameters for the deaquation-anation of the tetracyanonickelate(II), tetracyanopalladate(II), and tetracyanoplatinate(II) of aquapentaaminecobalt(III). Influence of the metal-metal interactions on the platinum complex
Juan Ribas, Miquel Serra, and Albert Escuer
pp 2236 - 2242; DOI:
10.1021/ic00183a008
PDF
Hydroxamates of bis(2,2'-bipyridine)ruthenium: synthesis, protic, redox, and electroprotic equilibria, spectra, and spectroelectrochemical correlations
Phalguni Ghosh and Animesh Chakravorty
pp 2242 - 2248; DOI:
10.1021/ic00183a009
PDF
High-pressure stopped-flow studies on the metalation of N-methyl-5,10,15,20-tetraphenylporphine in N,N-dimethylformamide
Shigenobu Funahashi, Yushi Yamaguchi, and Motoharu Tanaka
pp 2249 - 2251; DOI:
10.1021/ic00183a010
PDF
Coordination chemistry of copper macrocyclic complexes: synthesis and characterization of copper complexes of TIM
Michael J. Maroney and Norman J. Rose
pp 2252 - 2261; DOI:
10.1021/ic00183a011
PDF
Electronic structure of copper complexes containing .alpha.-diimine ligands
Michael J. Maroney, Joe G. Norman, and Joseph H. Osborne
pp 2261 - 2270; DOI:
10.1021/ic00183a012
PDF
Divalent lanthanide chemistry. Preparation and crystal structures of sodium tris[bis(trimethylsilyl)amido]europate(II) and sodium tris[bis(trimethylsilyl)amido]ytterbate(II), NaM[N(SiMe3)2]3
T. Don Tilley, Richard A. Andersen, and Allan Zalkin
pp 2271 - 2276; DOI:
10.1021/ic00183a013
PDF
Synthesis and molecular structure of pentakis(triphenylphosphine)hexakis(4-chlorobenzenethiolato)hexasilver(I), derived from a new Ag5(SR)6 cage structure
Ian G. Dance, Lyn J. Fitzpatrick, and Marcia L. Scudder
pp 2276 - 2281; DOI:
10.1021/ic00183a014
PDF
Hexacarbonyl(fulvalene)ditungsten(W-W). A stretched tungsten-tungsten single bond
Harmon B. Abrahamson and Mary Jane Heeg
pp 2281 - 2286; DOI:
10.1021/ic00183a015
PDF
Synthesis, structure, and reactivity of tricarbonyl(.eta.5-cyclopentadienyl)(.eta.1-dimethylcarbamodithioato)tungsten
Harmon B. Abrahamson, Michael L. Freeman, M. Bilayet Hossain, and Dick Van der Helm
pp 2286 - 2293; DOI:
10.1021/ic00183a016
PDF
Synthesis, structure, and spectral characterization of nickel(II) (R,R)-tartrate. Crystal and molecular structure of polymeric diaquabis((R,R)-tartrato-O1,O2:O3,O4)dinickel(II) trihydrate at -162.degree.C
Lein J. Bostelaar, Rudolf A. G. De Graaff, Frans B. Hulsbergen, Jan Reedijk, and Wolfgang M. H. Sachtler
pp 2294 - 2297; DOI:
10.1021/ic00183a017
PDF
Characterization of bis(2,2'-bipyridine) and bis(1,10-phenanthroline) derivatives of molybdenum and tungsten carbonyls. Crystal and molecular structure of cis-dicarbonylbis(2,2'-bipyridine)molybdenum(0)
M. H. Chisholm, J. A. Connor, J. C. Huffman, E. M. Kober, and C. Overton
pp 2298 - 2303; DOI:
10.1021/ic00183a018
PDF
Reactions of metal-metal multiple bonds. 13. Reactions of diazoalkanes with hexaalkoxides of dimolybdenum and ditungsten (M.tplbond.M). Preparation and characterization of Mo2(O-iso-Pr)6(N2CPh2)2(py), W2(O-tert-Bu)6(N2C(p-tol)2)2, and Mo(O-tert-Bu)4(N2CPh2)
Malcolm H. Chisholm, Kirsten Folting, John C. Huffman, and A. L. Ratermann
pp 2303 - 2311; DOI:
10.1021/ic00183a019
PDF
Synthesis of tin-tellurium polyanions: structure of (Me4N)4Sn2Te6
J. C. Huffman, J. P. Haushalter, A. M. Umarji, G. K. Shenoy, and R. C. Haushalter
pp 2312 - 2315; DOI:
10.1021/ic00183a020
PDF
Zinc(2+)-catalyzed decomposition of a tris(imidazol-2-yl)phosphine. Crystal and molecular structure of [bis(4,5-diisopropylimidazol-2-yl)phosphinic acid]dichlorozinc hydrate
R. G. Ball, R. S. Brown, and J. L. Cocho
pp 2315 - 2318; DOI:
10.1021/ic00183a021
PDF
Redox-active binuclear complexes. Preparation, oxidation, and structure of Rh2(Ph2PCH2PPh2)2(1,2-O2C6Cl4)(CO)
Judith A. Ladd, Marilyn M. Olmstead, and Alan L. Balch
pp 2318 - 2323; DOI:
10.1021/ic00183a022
PDF
Preparation and characterization of some binuclear DPM-bridged complexes of iridium and the structure of one product, [Ir2Cl2(CO)2(.mu.-CO)(Ph2PCH2PPh2)2].3C4H8O
Bruce R. Sutherland and Martin Cowie
pp 2324 - 2331; DOI:
10.1021/ic00183a023
PDF
Ligand influence on the electronic properties of some bis(tertiary phosphine)-substituted chromium and molybdenum carbonyls: cyclic voltammetry and infrared spectroscopy of M(CO)4R2PCH2CH2PR2
Ron L. Cook and Joseph G. Morse
pp 2332 - 2336; DOI:
10.1021/ic00183a024
PDF
Oxidation of isopropylamine and related amines coordinated to ruthenium. Formation of monodentate imine and alkylideneamido complexes of ruthenium
Peter A. Adcock, F. Richard Keene, Robert S. Smythe, and Michael R. Snow
pp 2336 - 2343; DOI:
10.1021/ic00183a025
PDF
Electrochemical and spectroscopic study of isomerization, cross-redox and self-exchange reactions in the [Cr(CO)3P3]+/0 redox system
A. M. Bond, S. W. Carr, and R. Colton
pp 2343 - 2350; DOI:
10.1021/ic00183a026
PDF
Kinetics of the reduction of neptunium(VI) by dicarboxylic acids
L. F. Rao and G. R. Choppin
pp 2351 - 2354; DOI:
10.1021/ic00183a027
PDF
Kinetics and mechanism of silver(III) reduction
Edward T. Borish and Louis J. Kirschenbaum
pp 2355 - 2359; DOI:
10.1021/ic00183a028
PDF
Unusual EPR spectrum of [CuCl2(H2O)2][(C6H5)3PO]4: effect of magnetic dipole coupling with slow electron exchange
Michael A. Hitchman, Robbie G. McDonald, and Mark J. Riley
pp 2359 - 2361; DOI:
10.1021/ic00183a029
PDF
Ligand metal interrelationships. 2. Effect of the change from square-planar to octahedral coordination on the pKa of the ligand in unsaturated tetraaza macrocyclic nickel complexes: a pulse-radiolytic study
Haim Cohen, Mordechi Nutkovich, Dan Meyerstein, and Alan Shusterman
pp 2361 - 2363; DOI:
10.1021/ic00183a030
PDF
Crystal structure of the cis,cis,trans isomer of PtCl2(NH3)2(OH)2: corrigendum
Richard E. Marsh
pp 2363 - 2363; DOI:
10.1021/ic00183a031
PDF
Structural and magnetic characterization of the triclinic modification of bis(.mu.-hydroxo)bis[tetraamminechromium(III)] chloride tetrahydrate, [(NH3)4Cr(OH)]2Cl4.4H2O
Derek J. Hodgson and Erik Pedersen
pp 2363 - 2365; DOI:
10.1021/ic00183a032
PDF
Preparation of [Nb(.eta.5-C5Me5)Cl2]2 and Nb(.eta.5-C5Me5)(3-hexyne)Cl2
P. A. Belmonte, F. G. N. Cloke, K. H. Theopold, and R. R. Schrock
pp 2365 - 2367; DOI:
10.1021/ic00183a033
PDF
Bis(acetylacetonato)fluorovanadium(III), VF(C5H7O2)2. Synthesis of a novel neutral compound of vanadium(III) from vanadium(V)
Mihir K. Chaudhuri and Soumitra K. Ghosh
pp 2367 - 2368; DOI:
10.1021/ic00183a034
PDF

Issue 16


Photoelectron study of additivity and ligand field effects on the tungsten 5d orbitals in [W(CO)6-n(PR3)n] compounds
G. Michael Bancroft, Lisa Dignard-Bailey, and Richard J. Puddephatt
pp 2369 - 2370; DOI:
10.1021/ic00184a001
PDF
Bimetallic porphyrins: synthesis and rapid intramolecular electron transfer of (meso-tritolylpyridylporphyrin)pentaammineruthenium(III)
Cesar Franco and George McLendon
pp 2370 - 2372; DOI:
10.1021/ic00184a002
PDF
Electrochemical characterization of six-coordinate nitrosyl .sigma.-bonded iron-phenylporphyrins
K. M. Kadish, D. Lancon, and P. Cocolios
pp 2372 - 2373; DOI:
10.1021/ic00184a003
PDF
Generation of dinuclear ruthenium acetamidate complexes with variable ruthenium-ruthenium bond orders
M. Y. Chavan, F. N. Feldmann, X. Q. Lin, J. L. Bear, and K. M. Kadish
pp 2373 - 2375; DOI:
10.1021/ic00184a004
PDF
Preparation and conformational dynamics of (C5Me5)Rh(PR13)RX. Hindered rotation about rhodium-phosphorus and rhodium-carbon bonds
William D. Jones and Frank J. Feher
pp 2376 - 2388; DOI:
10.1021/ic00184a005
PDF
Nine-coordinate hexahydride complexes of molybdenum and tungsten
Robert H. Crabtree and Gregory G. Hlatky
pp 2388 - 2390; DOI:
10.1021/ic00184a006
PDF
Synthesis, properties, and structure of hydrido(cyanotrihydroborato)tris(triphenylphosphine)cobalt(II)
Richard J. Barton, David G. Holah, Hu Shengzhi, Alan N. Hughes, Saeed I. Khan, and Beverly E. Robertson
pp 2391 - 2395; DOI:
10.1021/ic00184a007
PDF
Two-dimensional short-range order in the crystal structure of (tetraphenylporphinato)iron(III) 2,3,5,6-tetrafluorobenzenethiolate. Analysis of the x-ray diffuse scattering and a simulation of crystal growth
Kathleen M. Miller and Charles E. Strouse
pp 2395 - 2400; DOI:
10.1021/ic00184a008
PDF
Multidentate ligands containing 2,2'-bipyridine and/or pyridine moieties: structural aspects of their octahedral and pentagonal-bipyramidal complexes
George R. Newkome, Vinod K. Gupta, Frank R. Fronczek, and Sebastiano Pappalardo
pp 2400 - 2408; DOI:
10.1021/ic00184a009
PDF
Structure and bonding in dirhodium(II) tetrasalicylate
Daniel P. Bancroft, F. Albert Cotton, and Scott Han
pp 2408 - 2411; DOI:
10.1021/ic00184a010
PDF
Crystal structure and molecular conformation of P1,P2-bidentate tetraammine(methylenediphosphato)cobalt(III) hydrochloride (CoPCP): CoH2P2O6CH2(NH3)4+.Cl-
Tuli P. Haromy, Wilson B. Knight, Debra Dunaway-Mariano, and M. Sundaralingam
pp 2412 - 2415; DOI:
10.1021/ic00184a011
PDF
Reduction of rhenium(VII) oxide by triethylphosphine
J. W. Johnson, J. F. Brody, G. B. Ansell, and S. Zentz
pp 2415 - 2418; DOI:
10.1021/ic00184a012
PDF
Oxygen fluorides, non-metal halides, van der Waals molecules and related species: a linking theoretical thread
Jeremy K. Burdett, Nicholas J. Lawrence, and James J. Turner
pp 2419 - 2428; DOI:
10.1021/ic00184a013
PDF
Ab initio studies on the ground state potential surface and vibrational spectra of NSF and SNF
L. J. Schaad, B. Andes Hess, P. Carsky, and R. Zahradnik
pp 2428 - 2430; DOI:
10.1021/ic00184a014
PDF
Desolvation method for assessment of crystallization energies and ion crowding in rare-earth perchlorates, chlorides, and nitrates
E. I. Onstott, Laura B. Brown, and E. J. Peterson
pp 2430 - 2435; DOI:
10.1021/ic00184a015
PDF
Electronic switching of ring orientation in cyclopentadienyl-bridged polymers
Enric Canadell, Odile Eisenstein, and Timothy Hughbanks
pp 2435 - 2440; DOI:
10.1021/ic00184a016
PDF
Examples of fast and slow electronic relaxation between 6A and 2T
Yonezo Maeda, Naoto Tsutsumi, and Yoshimasa Takashima
pp 2440 - 2447; DOI:
10.1021/ic00184a017
PDF
Oxidation-reduction reactions of complexes with macrocyclic ligands. Electron-transfer reactivity of a 1:1 cobalt(II)-dioxygen adduct
Krishan Kumar and John F. Endicott
pp 2447 - 2452; DOI:
10.1021/ic00184a018
PDF
Photochemistry of water-soluble porphyrins: comparative study of isomeric tetrapyridyl- and tetrakis(N-methylpyridiniumyl)porphyrins
K. Kalyanasundaram
pp 2453 - 2459; DOI:
10.1021/ic00184a019
PDF
Magnetic interactions in copper complexes of tetradentate binucleating phthalazine ligands. Crystal and molecular structure of binuclear .mu.-hydroxo-bridged copper(II) complexes of 1,4-bis(2-pyridylamino)phthalazine and 1,4-bis((4-methyl-2-pyridyl)amino)phthalazine
Laurence K. Thompson, A. W. Hanson, and Baratham S. Ramaswamy
pp 2459 - 2465; DOI:
10.1021/ic00184a020
PDF
Comparisons between polypyridyl nitrosyl complexes of osmium(II) and ruthenium(II)
David W. Pipes and Thomas J. Meyer
pp 2466 - 2472; DOI:
10.1021/ic00184a021
PDF
Base hydrolysis of anionopentaamminecobalt(III) complexes: the role of ion association and the question of a common coordinatively unsaturated intermediate
W. G. Jackson, C. N. Hookey, M. L. Randall, P. Comba, and A. M. Sargeson
pp 2473 - 2482; DOI:
10.1021/ic00184a022
PDF
Poly(tertiary phosphines and arsines). 21. Metal carbonyl complexes of bis(dimethylphosphino)methane
R. B. King and K. S. RaghuVeer
pp 2482 - 2491; DOI:
10.1021/ic00184a023
PDF
Synthesis, structure, and chemistry of sterically crowded metal carbonyl cluster compounds: [Fe3M(CO)14]2-, (M = Cr, Mo, W)
Colin P. Horwitz, Elizabeth M. Holt, and Duward F. Shriver
pp 2491 - 2499; DOI:
10.1021/ic00184a024
PDF
Linear-chain halogen-bridged mixed-valence complexes of palladium: infrared, electronic, Raman, and resonance Raman study
Robin J. H. Clark, Vincent B. Croud, and Mohamedally Kurmoo
pp 2499 - 2504; DOI:
10.1021/ic00184a025
PDF
An ab initio quadratic force field for methyldiborane
David D. Keeports and David F. Eggers
pp 2505 - 2509; DOI:
10.1021/ic00184a026
PDF
Preparation and hydriding behavior of magnesium metal clusters formed in low-temperature cocondensation: application of magnesium for hydrogen storage
H. Imamura, T. Nobunaga, M. Kawahigashi, and S. Tsuchiya
pp 2509 - 2511; DOI:
10.1021/ic00184a027
PDF
Electrochemical and spectroscopic studies of polypyridine complexes of iron(II/III) and ruthenium(II/III) in the aluminum chloride-N-1-butylpyridinium chloride molten salt
Saeed Sahami and Robert A. Osteryoung
pp 2511 - 2518; DOI:
10.1021/ic00184a028
PDF
Synthesis and characterization of complexes of thiomolybdates and thiotungstates with copper(I) and silver(I) cyanides, including molybdenum-95 and tungsten-183 NMR properties and the crystal and molecular structures of (n-Pr4N)2[(CN)CuS2MoS2], (n-Pr4N)2[(CN)AgS2WS2], and (Ph4As)2[(CN)CuS2MoS2Cu(CN)].H2O
Stephen F. Gheller, Trevor W. Hambley, John R. Rodgers, Robert T. C. Brownlee, Maxwell J. O'Connor, Michael R. Snow, and Anthony G. Wedd
pp 2519 - 2528; DOI:
10.1021/ic00184a029
PDF
Stoichiometry, kinetics, and mechanisms of the chromium(VI) oxidation of L-cysteine at neutral pH
Daniel W. J. Kwong and David E. Pennington
pp 2528 - 2532; DOI:
10.1021/ic00184a030
PDF
Reexamination of a cytochrome oxidase model. A noncoupled iron-copper binuclear complex
Greg A. Brewer and Ekk Sinn
pp 2532 - 2537; DOI:
10.1021/ic00184a031
PDF
Solvent, temperature, and electrolyte studies on the electron-transfer reaction between ferrocene and a cobalt clathrochelate
Dan Borchardt and Scot Wherland
pp 2537 - 2542; DOI:
10.1021/ic00184a032
PDF
Exchange interaction in multinuclear transition-metal complexes. 5. Through-bond exchange coupling in Cu2A(CH3COO)2.2CH3OH (A2- = anion of N,N'-bis(2-((o-hydroxybenzhydrylidene)amino)ethyl)piperazine)
B. Chiari, O. Piovesana, T. Tarantelli, and P. F. Zanazzi
pp 2542 - 2547; DOI:
10.1021/ic00184a033
PDF
Thermodynamic studies of the axial ligation reactions of isomeric (5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene)copper(II) complexes with anions
Shei Yeh Wu, Chung Shin Lee, and Chung Sun Chung
pp 2548 - 2550; DOI:
10.1021/ic00184a034
PDF
Syntheses and x-ray crystal structures of two new classes of macrocyclic ligands having both phosphorus and nitrogen donor atoms
Hakon Hope, Michael Viggiano, Bahman Moezzi, and Philip P. Power
pp 2550 - 2552; DOI:
10.1021/ic00184a035
PDF
(.mu.-Sulfato)bis[(meso-tetraphenylporphinato)iron(III)]
W. Robert Scheidt, Young Ja Lee, T. Bartzcak, and Keiichiro Hatano
pp 2552 - 2554; DOI:
10.1021/ic00184a036
PDF
Molybdenum-95 NMR measurements of dioxomolybdenum(VI) complexes. 3. Inverse halogen dependence of molybdenum chemical shift of [MoO2]2+ complexes
Martin Minelli, Katsumoto Yamanouchi, John H. Enemark, P. Subramanian, Bharat B. Kaul, and Jack T. Spence
pp 2554 - 2556; DOI:
10.1021/ic00184a037
PDF

Issue 17


Multinuclear magnetic resonance studies of macrocyclic complexation in room-temperature molten salts
Rick R. Rhinebarger, John W. Rovang, and Alexander I. Popov
pp 2557 - 2558; DOI:
10.1021/ic00185a001
PDF
Synthetic metals based on bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF): synthesis, structure, and ambient-pressure superconductivity in (BEDT-TTF)2I3
Jack M. Williams, T. J. Emge, H. H. Wang, M. A. Beno, P. Thomas Copps, L. N. Hall, K. Douglas Carlson, and G. W. Crabtree
pp 2558 - 2560; DOI:
10.1021/ic00185a002
PDF
Preparation, chemistry, and vanadium-51 NMR spectroscopy of (p-tolylimido)vanadium(V) complexes
Eric A. Maatta
pp 2560 - 2561; DOI:
10.1021/ic00185a003
PDF
Characterization of a true intermediate-spin (porphinato)iron(III) complex
G. E. Toney, L. W. TerHaar, J. E. Savrin, A. Gold, W. E. Hatfield, and R. Sangaiah
pp 2561 - 2563; DOI:
10.1021/ic00185a004
PDF
Comment on two papers by R. H. Magnuson concerning osmium(V) compounds. Synthesis of trichlorosulfur(II) hexachloroosmate(V)
Kurt Dehnicke, Ulrich Mueller, and Rainer Weber
pp 2563 - 2564; DOI:
10.1021/ic00185a005
PDF
Molybdenum(VI)-dioxo complexes with sterically bulky ligands
P. Subramanian, J. T. Spence, R. Ortega, and J. H. Enemark
pp 2564 - 2572; DOI:
10.1021/ic00185a006
PDF
Binuclear complexes of palladium(II) containing 1,8-diisocyano-p-menthane
Chi Ming Che, Frank H. Herbstein, William P. Schaefer, Richard E. Marsh, and Harry B. Gray
pp 2572 - 2575; DOI:
10.1021/ic00185a007
PDF
Chemistry of sterically crowded aryloxide ligands. 4. Synthesis and structure of mixed chloro aryloxides of tantalum
Linda R. Chamberlain, Ian P. Rothwell, and John C. Huffman
pp 2575 - 2578; DOI:
10.1021/ic00185a008
PDF
catena-Dichloro(diphenylethanedione dioxime)copper(II), a new one-dimensional S = 1/2 Heisenberg chain with a novel zig-zag structure
Michel Megnamisi-Belombe, Phirtu Singh, D. Eric Bolster, and William E. Hatfield
pp 2578 - 2582; DOI:
10.1021/ic00185a009
PDF
Synthesis and structures of compounds containing double bonds between the heavier Group VA elements: diphosphenes, diarsenes, phosphaarsenes, and phosphastibenes
Alan H. Cowley, Jan E. Kilduff, Jon G. Lasch, Sushil K. Mehrotra, Nichlas C. Norman, Marek Pakulski, Bruce R. Whittlesey, Jerry L. Atwood, and William E. Hunter
pp 2582 - 2593; DOI:
10.1021/ic00185a010
PDF
Kinetics and mechanism of reduction of nickel(III) complexes by titanium(III) in aqueous media
A. McAuley, O. Olubuyide, L. Spencer, and P. R. West
pp 2594 - 2599; DOI:
10.1021/ic00185a011
PDF
Reactions of rhodium trifluoroacetate with various Lewis bases. Formation of 4:1 complexes with pyridine and tert-butyl isocyanide and bond cleavage with phosphorus donors
Joshua Telser and Russell S. Drago
pp 2599 - 2606; DOI:
10.1021/ic00185a012
PDF
Redox properties and demetalation of reduced lead phthalocyanine in dimethylformamide
M. El Meray, A. Louati, J. Simon, A. Giraudeau, M. Gross, T. Malinski, and K. M. Kadish
pp 2606 - 2609; DOI:
10.1021/ic00185a013
PDF
Electrochemical and photochemical reduction of decatungstate: a reinvestigation
A. Chemseddine, C. Sanchez, J. Livage, J. P. Launay, and M. Fournier
pp 2609 - 2613; DOI:
10.1021/ic00185a014
PDF
Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II)
Michael P. Edwards, Carl Hoff, Basil Curnutte, John S. Eck, and Keith F. Purcell
pp 2613 - 2619; DOI:
10.1021/ic00185a015
PDF
Cooperativity in thermally induced intersystem crossing in solids: Fe(phen)2(NCR)2, R = BH3, BPh3, S, Se
Keith F. Purcell and Michael P. Edwards
pp 2620 - 2625; DOI:
10.1021/ic00185a016
PDF
Core photoelectron emission study of binary and ternary indium chlorides. Metal binding energy as a function of oxidation state and other parameters
John D. Corbett, Gerd Meyer, and James W. Anderegg
pp 2625 - 2632; DOI:
10.1021/ic00185a017
PDF
Effect of arene substituents and temperature on the arene replacement reactions of [(.eta.5-C5H5)Fe(.eta.6-arene)]+ and [(.eta.5-C5H5)Ru(.eta.6-arene)]+
Amy M. McNair, Janet L. Schrenk, and Kent R. Mann
pp 2633 - 2640; DOI:
10.1021/ic00185a018
PDF
Molecular orbital analysis of the bonding in gold tertiary phosphine clusters and their gold-197 Moessbauer spectra
J. W. A. Van der Velden and Z. M. Stadnik
pp 2640 - 2644; DOI:
10.1021/ic00185a019
PDF
Madelung energy calculations on the highly conducting molecular metal nickel phthalocyanine iodide
William B. Euler
pp 2645 - 2650; DOI:
10.1021/ic00185a020
PDF
Spectral and photophysical properties of ruthenium(II) 2-(phenylazo)pyridine complexes
Steven Wolfgang, Thomas C. Strekas, Harry D. Gafney, Ronald A. Krause, and Kirsten Krause
pp 2650 - 2655; DOI:
10.1021/ic00185a021
PDF
Stereochemistry and dynamic properties of square-planar and square-pyramidal cations of bivalent nickel, palladium, and platinum containing the enantiomers of (R*,R*)-(.+-.)- and (R*,S*)-(.+-.)-1-(methylphenylarsino)-2-(methylphenylphosphino)benzene
Geoffrey Salem and Stanley Bruce Wild
pp 2655 - 2663; DOI:
10.1021/ic00185a022
PDF
Resolutions involving metal complexation. Resolution of (.+-.)-1-amino-2-(methylphenylarsino)ethane and its phosphorus analog. Stereochemistry and stability of square-planar bis(bidentate) complexes of bivalent palladium and platinum
John W. L. Martin, Judith A. L. Palmer, and Stanley Bruce Wild
pp 2664 - 2668; DOI:
10.1021/ic00185a023
PDF
Synthesis and characterization of new mononuclear and dinuclear complexes of palladium(II) with glycyl chloride
Manuel Castillo, Antonio Romero, and Elias Ramirez
pp 2668 - 2671; DOI:
10.1021/ic00185a024
PDF
Different coordination modes of neutral and deprotonated ZC(S)N(H)R ligands (Z = PPh2, R = Ph, Me; Z = NMe2, R = Ph) in molybdenum and tungsten complexes. X-ray structure analysis of [Mo(CO)2[Ph2PC(S)NMe][.mu.-Ph2PC(S)NMe]]2.CH2Cl2
H. P. M. M. Ambrosius, J. Willemse, J. A. Cras, W. P. Bosman, and J. H. Noordik
pp 2672 - 2678; DOI:
10.1021/ic00185a025
PDF
Preparation, properties, and structural studies of molybdenum and tungsten complexes with [Ph2P(S)C(S)NR]- (R = Me, Ph) or Ph2PS- ligands. X-ray structure analysis of Mo(CO)2(.eta.5-C5H5)[Ph2P(S)C(S)NPh]
H. P. M. M. Ambrosius, A. W. Van Hemert, W. P. Bosman, J. H. Noordik, and G. J. A. Ariaans
pp 2678 - 2685; DOI:
10.1021/ic00185a026
PDF
Ruthenium complexes with diazabutadienes. 3. trans and cis Isomers of dichlorobis(diazabutadiene)ruthenium (RN:CR'CR':NR)2RuCl2
Heindirk Tom Dieck, Wolfgang Kollvitz, and Ingo Kleinwaechter
pp 2685 - 2691; DOI:
10.1021/ic00185a027
PDF
Reactions of aziridine, oxirane, and thiirane with carbonyl and thiocarbonyl ligands in complexes of iron, manganese, and ruthenium: syntheses of cyclic carbene compounds
Mono M. Singh and Robert J. Angelici
pp 2691 - 2698; DOI:
10.1021/ic00185a028
PDF
Reactions of aziridine and oxirane with manganese and rhenium carbonyl complexes. Syntheses of neutral 5-membered cyclic aminooxy- and dioxycarbene compounds
Mono M. Singh and Robert J. Angelici
pp 2699 - 2705; DOI:
10.1021/ic00185a029
PDF
Reactivity of cis-diamminebis(dimethyl sulfide)platinum(II) perchlorate
Giuliano Annibale, Luciano Canovese, Lucio Cattalini, Giampaolo Marangoni, Gianni Michelon, and Martin L. Tobe
pp 2705 - 2708; DOI:
10.1021/ic00185a030
PDF
Excited-state properties of binuclear Group VIB metal carbonyl complexes. Emission and photochemistry in fluid solution
Alistair J. Lees, Joanne M. Fobare, and Eileen F. Mattimore
pp 2709 - 2713; DOI:
10.1021/ic00185a031
PDF
Characterization of a stable chromium(III)-nicotinic acid complex by deuteron NMR
Charles A. Green, Robert J. Bianchini, and J. Ivan Legg
pp 2713 - 2715; DOI:
10.1021/ic00185a032
PDF
Identification of the zinc reduction product of VCl3.3THF as [V2Cl3(THF)6]2[Zn2Cl6]
Reinder J. Bouma, Jan H. Teuben, W. R. Beukema, Rick L. Bansemer, John C. Huffman, and Kenneth G. Caulton
pp 2715 - 2718; DOI:
10.1021/ic00185a033
PDF
Thionitrosyl and bridging sulfide complexes of (dicarbonyl)[hydridotris(3,5-dimethylpyrazolyl)borato]metal (metal = molybdenum and tungsten)
Dennis L. Lichtenberger and John L. Hubbard
pp 2718 - 2720; DOI:
10.1021/ic00185a034
PDF
Multinuclear NMR studies of electron distributions: nitrogen-14, carbon-13, and molybdenum-95 spectra of nitrosyl and thionitrosyl complexes of chromium, molybdenum, and tungsten
Martin Minelli, John L. Hubbard, Dennis L. Lichtenberger, and John H. Enemark
pp 2721 - 2722; DOI:
10.1021/ic00185a035
PDF
Cobalt-59 NMR of a cobalt(III) spin-crossover compound
Gil Navon and Wolfgang Klaeui
pp 2722 - 2725; DOI:
10.1021/ic00185a036
PDF
EPR of seven-coordinated high-spin cobalt(II): comparison with paramagnetic anisotropy studies and interpretation within the angular-overlap model
Irene Morgenstern-Badarau
pp 2725 - 2727; DOI:
10.1021/ic00185a037
PDF
Additions and Corrections - Steric Course of Base Hydrolysis of cis- and trans-[Co(en)2(N3)X]n+ and cis- and trans-[Co(en)2-(NCS)X]n+ (X=Br-, Cl-, OS(CH3)2, OCHN(CH3)2, N3-, O2CH-).
W. G. Jackson, and C. M. Begbie
pp 2728 - 2728; DOI:
10.1021/ic00185a600
PDF
Additions and Corrections - Base Hydrolysis of [(NH3)5COX]n+. Capture of Sulfur and Nitrogen of the Thiocyanate Ion.
W. G. Jackson, and C. N. Hookey
pp 2728 - 2728; DOI:
10.1021/ic00185a601
PDF
Additions and Corrections - Reaction Dynamics and Hydroxide Ion Quenching of Rhodium(III) Ligand Field Excited States. Photoreactions of Rh(NH3)5I2+.
Mark E. Frink, Douglas Magde, Douglas Sexton, and Peter C. Ford
pp 2728 - 2728; DOI:
10.1021/ic00185a602
PDF
Additions and Corrections - Decarbonyl-nitrosyltriosmate(3 OS-OS): Structural Analysis and Fluxional Properties.
Brian F. G. Johnson, Jack Lewis, Julian M. Mace, Paul R. Raithby, Robert E. Stevens, and Wayne L. Gladfelter
pp 2728 - 2728; DOI:
10.1021/ic00185a603
PDF

Issue 18


Proton NMR spectra of reduced spinach ferredoxin
Ivano Bertini, G. Lanini, and C. Luchinat
pp 2729 - 2730; DOI:
10.1021/ic00186a001
PDF
Metal-promoted transformation of carbon dioxide into carbon monoxide. X-ray crystal structure of the nickel-carbonate complex [O:PPh2CH2C(CH3)(CH2PPh2)2]Ni(O2CO).0.5H2O.C6H6
Claudio Bianchini, Carlo Mealli, Andrea Meli, and Michal Sabat
pp 2731 - 2732; DOI:
10.1021/ic00186a002
PDF
Bonding and conformational relationships in the open metallocenes: solid-state structures of bis(2,4-dimethylpentadienyl) compounds of vanadium and chromium
Richard D. Ernst, Charles F. Campana, David R. Wilson, and Ju Zheng Liu
pp 2732 - 2734; DOI:
10.1021/ic00186a003
PDF
NMR evidence for the delocalized .alpha.,.alpha.'-carbanion of pyridoxal and pyridoxamine Schiff bases as the intermediate in vitamin B6-catalyzed transamination
Arthur E. Martell and Patrick Taylor
pp 2734 - 2735; DOI:
10.1021/ic00186a004
PDF
Role of peroxo vs. alkylperoxo titanium porphyrin complexes in the epoxidation of olefins
Henry J. Ledon and Francois Varescon
pp 2735 - 2737; DOI:
10.1021/ic00186a005
PDF
Electrochemical studies of sulfur-nitrogen compounds. 2. The S4N- and S3N- ions, S7NH, 1,4-S6(NH)2, S4N4H4, and 1,3-S4N2
T. Chivers and M. Hojo
pp 2738 - 2742; DOI:
10.1021/ic00186a006
PDF
Extraplanar ligand-exchange dynamics in (tetraphenylporphinato)zinc(II) and the conformation of zinc(II) porphyrins in solution
Carlyle B. Storm, Anne H. Turner, and Madeline B. Swann
pp 2743 - 2746; DOI:
10.1021/ic00186a007
PDF
Molecular addition compounds. 9. Effect of structure on the reactivities of representative borane-amine complexes in typical reactions such as hydrolysis, hydroboration, and reduction
Herbert C. Brown and Leo T. Murray
pp 2746 - 2753; DOI:
10.1021/ic00186a008
PDF
Pyrazole/imidazole and pyrazolato/imidazolato complexes of pentacyanoferrate(II/III) and pentaammineruthenium(II/III). LMCT transitions of low-spin d5 complexes
Craig R. Johnson, Wayne W. Henderson, and Rex E. Shepherd
pp 2754 - 2763; DOI:
10.1021/ic00186a009
PDF
The Creutz-Taube complex revisited: a single-crystal EPR study
Anton Stebler, John H. Ammeter, Urs Fuerholz, and Andreas Ludi
pp 2764 - 2767; DOI:
10.1021/ic00186a010
PDF
Kinetic investigation of the cerium(IV) oxidation of the bis(.mu.-oxo)bis(oxomolybdenum(V)) ion
Gregory A. Chappelle, Anita MacStay, S. T. Pittenger, K. Ohashi, and K. W. Hicks
pp 2768 - 2771; DOI:
10.1021/ic00186a011
PDF
Hydrogen evolving systems. 6. Reduction of molecular nitrogen in molybdenum(III-V) hydroxide/titanium(III) hydroxide systems
Nan Hui Liu, Norman Strampach, and Gerhard N. Schrauzer
pp 2772 - 2777; DOI:
10.1021/ic00186a012
PDF
Oxidation of cysteine, cysteine methyl ester, and penicillamine by copper(II)-2,9-dimethyl-1,10-phenanthroline complexes
Gary D. Stevens and Robert A. Holwerda
pp 2777 - 2780; DOI:
10.1021/ic00186a013
PDF
Synthetic approach to the type 1 active site of copper proteins. Copper(I), copper(II), and zinc(II) complexes with N2SS* ligand donor sets
Luigi Casella
pp 2781 - 2787; DOI:
10.1021/ic00186a014
PDF
Lower valence fluorides of chromium. 1. The hexagonal bronze type phase rubidium chromium fluoride (RbxCrF3)
Y. S. Hong, K. N. Baker, R. F. Williamson, and William O.J. Boo
pp 2787 - 2793; DOI:
10.1021/ic00186a015
PDF
Unusual redox and chemical properties of a sterically constrained N3CuII center. Preparation, structure, and solution studies of (nitrato)(1,4,7-triazacyclododecane)copper(II) nitrate
Harald Gampp, Michael M. Roberts, and Stephen J. Lippard
pp 2793 - 2798; DOI:
10.1021/ic00186a016
PDF
Low-temperature crystal structure of a five-coordinate iron(II) complex exhibiting singlet-triplet spin equilibrium
Mauro Bacci, Carlo A. Ghilardi, and Annabella Orlandini
pp 2798 - 2802; DOI:
10.1021/ic00186a017
PDF
Distortion isomerism in a thiocyanate-bridged copper(II) dimer. X-ray structure of .beta.-bis(.mu.-thiocyanato-N,S)-bis[bis(5,7-dimethyl[1,2,4]triazolo[1,5-a]pyrimidine)(thiocyanato-N)copper(II)] and comparison of its spectral and structural properties with those of other copper(II) 5,7-dimethyl[1,2,4]triazolo[1,5-a]pyrimidine thiocyanates
Jaap G. Haasnoot, Willem L. Driessen, and Jan Reedijk
pp 2803 - 2807; DOI:
10.1021/ic00186a018
PDF
Formation, crystal structure, and EPR spectroscopic properties of a heteronuclear (Pt2,Cu) mixed-nucleobase (1-methylcytosine, 1-methyluracil) complex: bis[(.mu.-1-methyluracilato-N3,O4)(.mu.-1-methylcytosine-N3,O2)-cis-diammineplatinum(II)]copper(II) tetranitrate-6-water
Bernhard Lippert, Ulf Thewalt, Helmut Schoellhorn, David M. L. Goodgame, and Robert W. Rollins
pp 2807 - 2813; DOI:
10.1021/ic00186a019
PDF
Copper(I) complexes with unsaturated small molecules. Preparation and structural characterization of copper(I)-di-2-pyridylamine complexes with olefins, acetylene, and carbon monoxide
Jeffery S. Thompson and John F. Whitney
pp 2813 - 2819; DOI:
10.1021/ic00186a020
PDF
Gas-phase structure of (CF3)2S(O)F2
Heinz Oberhammer, Jean'ne M. Shreeve, and Gary L. Gard
pp 2820 - 2822; DOI:
10.1021/ic00186a021
PDF
X-ray and neutron diffraction studies of the polyhydrido complex FeH6Mg4Br3.5Cl0.5(C4H8O)8: discussion of binary transition-metal hydride anions of the type [MHx]n-
Robert Bau, Michael Y. Chiang, Douglas M. Ho, Sidney G. Gibbins, Thomas J. Emge, and Thomas F. Koetzle
pp 2823 - 2829; DOI:
10.1021/ic00186a022
PDF
Displacement of ammonia from cis-diamminebis(dimethyl sulfide)platinum(II) perchlorate in basic aqueous solution. First- and second-order dependences of rate on hydroxide concentration
Giuliano Annibale, Massimiliano Bonivento, Lucio Cattalini, and Gianni Michelon
pp 2829 - 2833; DOI:
10.1021/ic00186a023
PDF
Bridged or nonbridged structures for dinuclear metal complexes. The case of tetrakis(methyl isocyanide)dipalladium(I) iodide: an unbridged compound
Nicole M. Rutherford, Marilyn M. Olmstead, and Alan L. Balch
pp 2833 - 2837; DOI:
10.1021/ic00186a024
PDF
Structural comparison of cobalt and nickel complexes with carbon disulfide and isothiocyanatobenzene molecules stabilized by tripodal polyphosphine ligands. Implications for the nature of the chemical bonding in compounds containing carbon-sulfur linkages .eta.2 coordinated to L3M fragments
C. Bianchini, D. Masi, Carlo C. Mealli, and A. Meli
pp 2838 - 2844; DOI:
10.1021/ic00186a025
PDF
Octahedral-tetrahedral geometry changes for zinc(II) in the presence of chloride ions
Herbert B. Silber, Dexter Simon, and Ferenc Gaizer
pp 2844 - 2848; DOI:
10.1021/ic00186a026
PDF
Synthesis, crystal structure and fluxional behavior of Re3H2(CO)10(.eta.5-C7H9)
Tiziana Beringhelli, Gianfranco Ciani, Giuseppe D'Alfonso, Pierfrancesco Romiti, Angelo Sironi, and Maria Freni
pp 2849 - 2852; DOI:
10.1021/ic00186a027
PDF
Silver complexes with succinimide as models for the interaction of silver(I) with the uracil residue
Johanne Perron and Andre L. Beauchamp
pp 2853 - 2859; DOI:
10.1021/ic00186a028
PDF
An INDO study of [1.1]ferrocenophane as a catalyst for hydrogen liberation from aqueous acidic media
A. Waleh, G. H. Loew, and U. T. Mueller-Westerhoff
pp 2859 - 2863; DOI:
10.1021/ic00186a029
PDF
Structure and properties of a cobalt(III) complex with a branched cyclic tetraamine ligand, (6-methyl-6-(4-amino-2-azabutyl)-1,4-diazacycloheptane)(ethylenediamine)cobalt(III) perchlorate
Kanji Tomioka, Ushio Sakaguchi, and Hayami Yoneda
pp 2863 - 2867; DOI:
10.1021/ic00186a030
PDF
Trinuclear complexes of 1,3,5,7-tetraketonates. Synthesis, molecular structure, absorption spectra, and electrochemistry of several bis[1,7-diphenyl-1,3,5,7-heptanetetronato(3-)]bis[dioxouranium(VI)]metal(II)-4-pyridine complexes
R. L. Lintvedt, B. A. Schoenfelner, C. Ceccarelli, and M. D. Glick
pp 2867 - 2874; DOI:
10.1021/ic00186a031
PDF
Multiple luminescence from borohydridobis(triphenylphosphine)copper(I)
Donald P. Segers, M. Keith DeArmond, Paul A. Grutsch, and Charles Kutal
pp 2874 - 2878; DOI:
10.1021/ic00186a032
PDF
Reactions involving the hydrazinium free radical; oxidation of hydrazine by hexachloroiridate
David M. Stanbury
pp 2879 - 2882; DOI:
10.1021/ic00186a033
PDF
Investigation of exchange and redox reactions of mercury dithiocarbamate complexes by electrochemical techniques at mercury electrodes, mercury-199 nuclear magnetic resonance spectrometry and mass spectrometry
A. M. Bond, R. Colton, M. L. Dillon, J. E. Moir, and D. R. Page
pp 2883 - 2891; DOI:
10.1021/ic00186a034
PDF
Ground- and excited-state electron-transfer reactions: photoinduced redox reactions of poly(pyridine)ruthenium(II) complexes and cobalt(III) cage compounds
Chup Yew Mok, Andrew W. Zanella, Carol Creutz, and Norman Sutin
pp 2891 - 2897; DOI:
10.1021/ic00186a035
PDF
An isothiocyanato complex of technetium(II). Spectroelectrochemical and single-crystal x-ray structural studies on trans-[Tc(DPPE)2(NCS)2]0, where DPPE = 1,2-bis(diphenylphosphino)ethane
Giuliano Bandoli, Ulderico Mazzi, Akio Ichimura, Karen Libson, William R. Heineman, and Edward Deutsch
pp 2898 - 2901; DOI:
10.1021/ic00186a036
PDF
Complexes of dimolybdenum(II) with DL-amino acids
Francoise Apfelbaum-Tibika and Avi Bino
pp 2902 - 2905; DOI:
10.1021/ic00186a037
PDF
Crystal structure at 300 and 105 K, magnetic properties and Moessbauer spectra of bis(triaquatris(4-ethyltriazole-N1)iron(II)-N2,N2',N2")iron(II) hexakis(trifluoromethanesulfonate). A linear, trinuclear iron(II) compound, showing a unique high-spin-low-spin transition of the central iron atom
Ger Vos, Rudolf A. G. De Graaff, Jaap G. Haasnoot, Adri M. Van der Kraan, Peter De Vaal, and Jan Reedijk
pp 2905 - 2910; DOI:
10.1021/ic00186a038
PDF
X.alpha.-SW calculations for naked actinide dimers: existence of .vphi. bonds between metal atoms
Bruce E. Bursten and Geoffrey A. Ozin
pp 2910 - 2911; DOI:
10.1021/ic00186a039
PDF
Preparation and chemistry of Mo(CO)3(S2PPh2)2
C. Y. Chou and Eric A. Maatta
pp 2912 - 2914; DOI:
10.1021/ic00186a040
PDF
Franck-Condon barriers to outer-sphere reductive cleavage
David M. Stanbury
pp 2914 - 2916; DOI:
10.1021/ic00186a041
PDF

Issue 19


Experimental probes of the electronic matrix element contributions to bimolecular reactions: metal-to-ligand charge-transfer perturbations of electronic transfer rates
T. Ramasami and John F. Endicott
pp 2917 - 2918; DOI:
10.1021/ic00187a001
PDF
X-ray structure and physical properties of the mixed-valence compound 1,12-dimethyl[1.1]ferrocenophanium triiodide
Michael F. Moore, Scott R. Wilson, David N. Hendrickson, and Ulrich T. Mueller-Westerhoff
pp 2918 - 2920; DOI:
10.1021/ic00187a002
PDF
The framework chemistry of zeolites: aluminum-27 MASNMR of extralattice tetrahedral aluminum species
D. R. Corbin, R. D. Farlee, and G. D. Stucky
pp 2920 - 2922; DOI:
10.1021/ic00187a003
PDF
An improved synthesis of tellurium fluoride hypofluorite (TeF5OF)
Carl J. Schack and Karl O. Christe
pp 2922 - 2922; DOI:
10.1021/ic00187a004
PDF
Preparation of O2XeF2-x(OTeF5)x, OXeF4-y(OTeF5)y and XeF4-y(OTeF5)y (x = 0-2, y = 0-4) and study by xenon-129 and fluorine-19 NMR and Raman spectroscopy: the oxygen primary isotopic effect in the xenon-129 NMR spectra of xenon(VI) oxyfluorides (XeO2F2 and XeOF4)
Gerhard A. Schumacher and Gary J. Schrobilgen
pp 2923 - 2929; DOI:
10.1021/ic00187a005
PDF
Addition compounds of alkali-metal hydrides. 24. A general method for preparation of potassium trialkoxyborohydrides. A new class of reducing agents
Herbert C. Brown, Jin Soon Cha, and Behrooz Nazer
pp 2929 - 2931; DOI:
10.1021/ic00187a006
PDF
Ferric isoporphyrins from hydroperoxide oxidation of (tetraphenylporphinato)iron(III) complexes
Avram Gold, W. Ivey, G. E. Toney, and R. Sangaiah
pp 2932 - 2935; DOI:
10.1021/ic00187a007
PDF
Mechanism of carbon monoxide insertion in the [Fe(CO)2(PMe3)2(Me)X] complexes
G. Cardaci, G. Reichenbach, and G. Bellachioma
pp 2936 - 2940; DOI:
10.1021/ic00187a008
PDF
Synthetically versatile (trifluoromethanesulfonato)metal amine complexes
Nicholas E. Dixon, Geoffrey A. Lawrance, Peter A. Lay, and Alan M. Sargeson
pp 2940 - 2947; DOI:
10.1021/ic00187a009
PDF
Mixed platinum-rhodium carbonyl clusters. 1. Synthesis, reactivity, and solution structures of [PtRh5(CO)15]-, [PtRh4(CO)14]2- and [PtRh4(CO)12]2-
Alessandro Fumagalli, Secondo Martinengo, Paolo Chini, Daniele Galli, Brian T. Heaton, and Roberto Della Pergola
pp 2947 - 2954; DOI:
10.1021/ic00187a010
PDF
Synthesis of M2Pt(CO)12 (M = Re, Mn). Crystal structure of rhenium platinum dodecacarbonyl (Re2Pt(CO)12)
Michael A. Urbancic, Scott R. Wilson, and John R. Shapley
pp 2954 - 2958; DOI:
10.1021/ic00187a011
PDF
Synthesis and structure of a cobalt(I) meso-tetraphenylporphyrin complex, [CoI(TPP)][K.cntnd.222]4Cl3.H2O
P. Doppelt, J. Fischer, and R. Weiss
pp 2958 - 2962; DOI:
10.1021/ic00187a012
PDF
Synthesis and characterization of technetium(V) 8-quinolinolates. X-ray crystal structure of cis-chlorobis(2-methyl-8-quinolinolato)oxotechnetium(V)
Bruce E. Wilcox, Mary Jane Heeg, and Edward Deutsch
pp 2962 - 2967; DOI:
10.1021/ic00187a013
PDF
Photochemistry of cyclopentadienylcobalt 1,4-diaryltetraazadienes. Examples of CH, CF, and CC bond breaking
Michal E. Gross, Curtis E. Johnson, Michael J. Maroney, and William C. Trogler
pp 2968 - 2973; DOI:
10.1021/ic00187a014
PDF
Structural characterization of a hexameric cobalt-carbonyl-sulfur complex, [Co3(CO)9C](.mu.3-SCS)[Co3(CO)7S], consisting of two tricobalt carbonyl clusters dissymmetrically linked by a bridging SCS group
Chin Hsuan Wei
pp 2973 - 2977; DOI:
10.1021/ic00187a015
PDF
Complex chemistry of reactive organic compounds. 46. Conformation of metal carbene complexes: synthesis and structure of carbonyl(.eta.5-cyclopentadienyl)(diphenylcarbene)nitrosylchromium and its relationship to the isoelectronic compound dicarbonyl(.eta.5-cyclopentadienyl)(diphenylcarbene)manganese
Wolfgang A. Herrmann, John L. Hubbard, Ivan Bernal, Jim D. Korp, Barry L. Haymore, and Gregory L. Hillhouse
pp 2978 - 2983; DOI:
10.1021/ic00187a016
PDF
Analogs of the [Fe4S4]+ sites of reduced ferredoxins: single-step synthesis of the clusters [Fe4S4(SR)4]3- and examples of compressed tetragonal core structures
Karl S. Hagen, Alan D. Watson, and R. H. Holm
pp 2984 - 2990; DOI:
10.1021/ic00187a017
PDF
Enhanced reactivity of nickel(II) complexes involving multidentate ligands in their complexation
Shinkichi Yamada, Takatoshi Kido, and Motoharu Tanaka
pp 2990 - 2993; DOI:
10.1021/ic00187a018
PDF
Stereochemical nonrigidity in six-coordinate Group VIB metal carbonyl derivatives via a nondissociative pathway
Donald J. Darensbourg and Robert L. Gray
pp 2993 - 2996; DOI:
10.1021/ic00187a019
PDF
Enthalpies of reaction of pentaammineruthenium(II) complexes
James F. Wishart, Henry Taube, Kenneth J. Breslauer, and Stephan S. Isied
pp 2997 - 3001; DOI:
10.1021/ic00187a020
PDF
Intervalence transfer in mixed-metal dimers of ruthenium and osmium: relationship between redox asymmetry and the intervalence-transfer absorption band
Kenneth A. Goldsby and Thomas J. Meyer
pp 3002 - 3010; DOI:
10.1021/ic00187a021
PDF
Unique redox and spectroscopic properties of dipyridylamine complexes of d6 transition metals: electrochemical behavior
David E. Morris, Yasuhiko Ohsawa, Donald P. Segers, M. Keith DeArmond, and Kenneth W. Hanck
pp 3010 - 3017; DOI:
10.1021/ic00187a022
PDF
Electron-transfer quenching of the luminescence of ruthenium and osmium polypyridine complexes by cobalt(III) complexes
Diana Sandrini, Maria Teresa Gandolfi, Mauro Maestri, Fabrizio Bolletta, and Vincenzo Balzani
pp 3017 - 3023; DOI:
10.1021/ic00187a023
PDF
The boric acid/lactic acid system. Equilibria and reaction mechanism
Richard Pizer and Russell Selzer
pp 3023 - 3026; DOI:
10.1021/ic00187a024
PDF
Statistical factors and the ratio of successive stability constants
Richard Pizer
pp 3027 - 3028; DOI:
10.1021/ic00187a025
PDF
Electron-transfer reactions of ion pairs: reduction of various (carboxylato)pentaamminecobalt(III) complexes by hexacyanoferrate(II)
Eduardo Kremer, Gisela Chai, Marta Morkevicius, Madeleine Seaman, and Albert Haim
pp 3028 - 3030; DOI:
10.1021/ic00187a026
PDF
Comparison between carbonyl derivatives of palladium and those of nickel and platinum
Daniela Belli Dell'Amico, Fausto Calderazzo, Carlo Alberto Veracini, and Nicola Zandona
pp 3030 - 3033; DOI:
10.1021/ic00187a027
PDF
Kinetics of the acid dissociation of the copper(II) and nickel(II) complexes of 5,7-dioxo-1,4,8,11-tetraazacyclotetradecane
Robert W. Hay, Mahesh P. Pujari, and Fiona McLaren
pp 3033 - 3035; DOI:
10.1021/ic00187a028
PDF
Synthesis of new chiral bicyclic aminophosphoranes and of rhodium(I) chelates derived from their open-form tautomers. Isolation and characterization of an optically pure rhodium(I) nitrogen/phosphorus chelate
F. Jeanneaux, J. G. Riess, and J. Wachter
pp 3036 - 3038; DOI:
10.1021/ic00187a029
PDF

Issue 20


Pressure tuning of excited-state equilibria as probed by photoemission properties of iridium complexes
John DiBenedetto, Richard J. Watts, and Peter C. Ford
pp 3039 - 3040; DOI:
10.1021/ic00188a001
PDF
Thermolysis of adenosylcobalamin: a product, kinetic, and cobalt-carbon (C5') bond dissociation energy study
Richard G. Finke and Benjamin P. Hay
pp 3041 - 3043; DOI:
10.1021/ic00188a002
PDF
The most simple type of a manganese dihalide phosphine adduct: MnI2(PEt3)2
Nikolaus Hebendanz, Frank H. Koehler, and Gerhard Mueller
pp 3043 - 3044; DOI:
10.1021/ic00188a003
PDF
"Photoinduced" complex formation
Ginya Adachi, Koji Sakai, Kenji Kawata, and Jiro Shiokawa
pp 3044 - 3045; DOI:
10.1021/ic00188a004
PDF
Lanthanide complexes of ionophores. 2. Spectroscopic characterization of lanthanide(III) ion binding to lasalocid A and A23187 in methanol
Michael Albin, Beth M. Cader, and William DeW. Horrocks
pp 3045 - 3050; DOI:
10.1021/ic00188a005
PDF
Formation of trans-M(O)2(CO)4 (M = Mo and W): intermediates in the photooxidation of matrix-isolated M(CO)6
Joseph A. Crayston, Matthew J. Almond, Anthony J. Downs, Martyn Poliakoff, and James J. Turner
pp 3051 - 3056; DOI:
10.1021/ic00188a006
PDF
Kinetics of oxygen atom transfer reactions involving oxomolybdenum complexes. General treatment for reactions with intermediate oxo-bridged molybdenum(V) dimer formation
Martha S. Reynolds, Jeremy M. Berg, and Richard H. Holm
pp 3057 - 3062; DOI:
10.1021/ic00188a007
PDF
Synthesis and characterization of the cyano- and carboxyborane adducts of quinuclidine
B. Kemp, S. Kalbag, and R. A. Geanangel
pp 3063 - 3065; DOI:
10.1021/ic00188a008
PDF
Kinetic and equilibrium studies on the diaquachromium(III) complex containing a saturated tetradentate tetraaza 15-membered macrocycle ligand
David T. Richens, I. Kofi Adzamli, Peter Leupin, and A. Geoffrey Sykes
pp 3065 - 3069; DOI:
10.1021/ic00188a009
PDF
Kinetic studies on reactions of iron-sulfur proteins. 8. Inner-sphere reductions of parsley [2Fe-2S] and Clostridium pasteurianum 2[4Fe-4S] ferredoxins with a chromium(II)-macrocycle complex
I. Kofi Adzamli, Richard A. Henderson, John D. Sinclair-Day, and A. Geoffrey Sykes
pp 3069 - 3073; DOI:
10.1021/ic00188a010
PDF
Magnetic coupling and EPR spectra of catena-bis(.mu.-perchlorato)[bis(.mu.-imidazolato)bis(perchlorato)octakis(imidazole)tricopper(II)]
C. Benelli, R. K. Bunting, D. Gatteschi, and C. Zanchini
pp 3074 - 3076; DOI:
10.1021/ic00188a011
PDF
Substitution chemistry of the doubly bonded ditungsten(IV) ethoxide complex W2Cl4(.mu.-OEt)2(OEt)2(HOEt)2 toward heterocyclic tertiary amines
William S. Harwood, David DeMarco, and Richard A. Walton
pp 3077 - 3080; DOI:
10.1021/ic00188a012
PDF
New bromo complexes of osmium(IV) and osmium(III): [Os2Br10]2- and OsBr3(PPh3)2(CH3CN)
F. Albert Cotton, Stan A. Duraj, Conrad C. Hinckley, Marek Matusz, and Wieslaw J. Roth
pp 3080 - 3083; DOI:
10.1021/ic00188a013
PDF
Irida-, rhoda-, nickela-, and cuprapentaboranes derived from the arachno-[B4H9]- ion. Crystal structure of [Ir(.eta.4-B4H9)(CO){P(CH3)2C6H5}2], an analog of arachno-B5H11 and [Ir(.eta.4-C4H6)(CO){P(CH3)2C6H5}2]+
Simon K. Boocock, Mark A. Toft, Kenneth E. Inkrott, Leh Yeh Hsu, John C. Huffman, Kirsten Folting, and Sheldon G. Shore
pp 3084 - 3091; DOI:
10.1021/ic00188a014
PDF
Studies on nickel(II) complexes of cyclam ligands containing functionalized nitrogen substituents: synthesis, isomerization, and N-dealkylation
Gary M. Freeman, E. Kent Barefield, and Donald G. Van Derveer
pp 3092 - 3103; DOI:
10.1021/ic00188a015
PDF
Preparation of a new ligand containing disulfide and imidazole donor groups. Structure of dibromo[5-(1,2,5-dithiazepan-5-ylmethylene)-4-methyl-2-ethylimidazole]cadmium(II). Cadmium-113 and carbon-13 NMR studies of complex formation
Gwendalyn C. Baumann, Michael F. Summers, John P. Hutchinson, Jon Zubieta, and Luigi G. Marzilli
pp 3104 - 3108; DOI:
10.1021/ic00188a016
PDF
Regiospecific addition of trifluoroamine oxide to trifluorovinyl olefins
Scott A. Kinkead and Jeanne M. Shreeve
pp 3109 - 3112; DOI:
10.1021/ic00188a017
PDF
Reactions of bis(2,2,2-trifluoroethyl) sulfite, bis(hexafluoroisopropyl) sulfite, and diethyl sulfite with chlorine fluoride: evidence of an Arbuzov rearrangement
Ramesh C. Kumar, Scott A. Kinkead, and Jeanne M. Shreeve
pp 3112 - 3114; DOI:
10.1021/ic00188a018
PDF
Reinvestigation of the electronic and magnetic properties of ruthenium butyrate chloride
Joshua Telser and Russell S. Drago
pp 3114 - 3120; DOI:
10.1021/ic00188a019
PDF
EPR spectra and bonding in the 2:1 base adducts of Rh2(carboxylate)4+
Russell S. Drago, Richard Cosmano, and Joshua Telser
pp 3120 - 3124; DOI:
10.1021/ic00188a020
PDF
Cu2(o-Ph2PC6H4C(O)CHC(O)C(CH3)3)2: synthesis, structure and oxidation to a mixed-valent copper(I)-copper(II) complex
Debra A. Wrobleski, Thomas B. Rauchfuss, Arnold L. Rheingold, and Keith A. Lewis
pp 3124 - 3129; DOI:
10.1021/ic00188a021
PDF
Peracid oxidation of inorganic chalcogen ligands in transition-metal complexes
John E. Hoots, David A. Lesch, and Thomas B. Rauchfuss
pp 3130 - 3136; DOI:
10.1021/ic00188a022
PDF
Polarized neutron diffraction and Moessbauer effect study of the magnetic ordering in wustite, FeyO
Clive Wilkinson, Anthony K. Cheetham, Gary J. Long, Peter D. Battle, and David A. O. Hope
pp 3136 - 3141; DOI:
10.1021/ic00188a023
PDF
Neutron diffraction and Moessbauer-effect study of manganese iron monoxide ((MnxFe1-x)yO) solid solutions
Gary J. Long, D. A. O. Hope, and A. K. Cheetham
pp 3141 - 3146; DOI:
10.1021/ic00188a024
PDF
Pentacoordinated molecules. 54. Pentacoordinated structures of triphenyltin esters of anthranilic acid, o-(dimethylamino)benzoic acid, and p-aminobenzoic acid formed by intramolecular carboxylate group coordination
Robert G. Swisher, Jean F. Vollano, V. Chandrasekhar, Roberta O. Day, and Robert R. Holmes
pp 3147 - 3152; DOI:
10.1021/ic00188a025
PDF
Pentacoordinated molecules. 55. Intramolecularly formed pentacoordinated structures of triphenyltin esters of salicylic acid, o-anisic acid, and p-methylthiobenzoic acid
Jean F. Vollano, Roberta O. Day, Denise N. Rau, V. Chandrasekhar, and Robert R. Holmes
pp 3153 - 3160; DOI:
10.1021/ic00188a026
PDF
Structural studies of salts of cis and trans .mu.-fluoro-bridged polymers of pentafluorogermanate(1-) and of the pentafluorogermanate(1-) monomer
Thomas E. Mallouk, Bernard Desbat, and Neil Bartlett
pp 3160 - 3166; DOI:
10.1021/ic00188a027
PDF
Fluoride ion affinities of germanium tetrafluoride and boron trifluoride from thermodynamic and structural data for (SF3)2GeF6, ClO2GeF5, and ClO2BF4
Thomas E. Mallouk, Guy L. Rosenthal, Gerhard Mueller, Raymond Brusasco, and Neil Bartlett
pp 3167 - 3173; DOI:
10.1021/ic00188a028
PDF
Synthesis and characterization of the chromium(III) dimer bis(.mu.-hydroxo)bis[[N,N'-bis(2-pyridylmethyl)-1,2-ethanediamine]chromium(III)] perchlorate, [(bispicen)Cr(OH)]2(ClO4)4.H2O
Miriam A. Heinrichs, Derek J. Hodgson, Kirsten Michelsen, and Erik Pedersen
pp 3174 - 3180; DOI:
10.1021/ic00188a029
PDF
Reduction of sulfur dioxide by Cp2MH2 (M = Mo, W) to Cp2M(S2O3) and water. Molecular structure and reaction with acids of an organometallic molybdenum-thiosulfate complex
G. J. Kubas and R. R. Ryan
pp 3181 - 3183; DOI:
10.1021/ic00188a030
PDF
Synthesis and characterization of cationic technetium complexes of 1,2-bis(dimethylphosphino)ethane (DMPE). Structure determinations of trans-[TcV(DMPE)2(OH)(O)](F3CSO3)2, trans-[TcIII(DMPE)2Cl2]F3CSO3, and [TcI(DMPE)3]+ using x-ray diffraction, EXAFS, and technetium-99 NMR
Jean Luc Vanderheyden, Alan R. Ketring, Karen Libson, Mary Jane Heeg, Lee Roecker, Philip Motz, Robert Whittle, R. C. Elder, and Edward Deutsch
pp 3184 - 3191; DOI:
10.1021/ic00188a031
PDF
Nature of iron(I) and iron(0) tetraphenylporphyrin complexes. Synthesis and molecular structure of (dibenzo-18-crown-6)bis(tetrahydrofuran)sodium (meso-tetraphenylporphinato)ferrate and bis[tris(tetrahydrofuran)sodium] (meso-tetraphenylporphinato)ferrate
Toshio Mashiko, Christopher A. Reed, Kenneth J. Haller, and W. Robert Scheidt
pp 3192 - 3196; DOI:
10.1021/ic00188a032
PDF
Nuclear magnetic resonance study of the kinetics of ligand-exchange reactions in uranyl complexes. 5. Exchange reaction of acetylacetonate in bis(acetylacetonato)(dimethyl sulfoxide)dioxouranium(VI)
Yasuhisa Ikeda, Hiroshi Tomiyasu, and Hiroshi Fukutomi
pp 3197 - 3202; DOI:
10.1021/ic00188a033
PDF
Ligand control of cis-dioxomolybdenum(VI) redox chemistry: kinetic and activation parameter data for oxygen atom transfer
Joseph Topich and James T. Lyon
pp 3202 - 3206; DOI:
10.1021/ic00188a034
PDF
Photochemical reactions of hexafluoroacetone with pentaborane(9) and 2,4-dicarbaheptaborane(7)
Robert J. Astheimer and Larry G. Sneddon
pp 3207 - 3212; DOI:
10.1021/ic00188a035
PDF
Kinetics of the stepwise oxidation of manganese(II) by peroxodiphosphate (PDP) in aqueous perchloric acid. Catalysis by silver(I)
K. Jagan Mohana Rao, A. S. P. Vittal, and P. V. Krishna Rao
pp 3212 - 3216; DOI:
10.1021/ic00188a036
PDF
Mono- and binuclear iridium carbonyl hydrides containing bis(tertiary phosphine) ligands
Barbara J. Fisher and Richard Eisenberg
pp 3216 - 3222; DOI:
10.1021/ic00188a037
PDF
Trichlorostannate complexes of platinum. Synthesis, multinuclear NMR spectroscopy and x-ray crystallography of trans-[Pt(SnCl3)2(P(OPh)3)2] and related complexes
A. Albinati, P. S. Pregosin, and H. Ruegger
pp 3223 - 3229; DOI:
10.1021/ic00188a038
PDF
Electrochemical study of aquapentaamineruthenium(II) using activated glassy-carbon electrodes
Alex A. Diamantis, W. Rorer Murphy, and Thomas J. Meyer
pp 3230 - 3234; DOI:
10.1021/ic00188a039
PDF
Novel five-coordinate iron(III) complexes produced by oxidation of square-planar (S = 1) iron(II) complexes
D. P. Riley and D. H. Busch
pp 3235 - 3241; DOI:
10.1021/ic00188a040
PDF
Reactions of metal atoms with alkynes. 2. Cocondensation reactions of germanium and tin atoms with acetylene and formation of integral metal-acetylene polymers
Robert W. Zoellner and Kenneth J. Klabunde
pp 3241 - 3246; DOI:
10.1021/ic00188a041
PDF
Synthesis and characterization studies on new ethylenediamine-N,N-diacetate complexes of cobalt(III)
Gary A. Sigel and John A. Weyh
pp 3246 - 3249; DOI:
10.1021/ic00188a042
PDF
Solvatochromism of the LMCT transition of pentacyanoferrate(III) complexes
Rex E. Shepherd, M. Fazlul Hoq, Nancy Hoblack, and Craig R. Johnson
pp 3249 - 3252; DOI:
10.1021/ic00188a043
PDF
Solvent effects on the boron-11 and proton NMR spectra of decaborane(14), B10H14
Donald F. Gaines, Caterina K. Nelson, Joan C. Kunz, John H. Morris, and David Reed
pp 3252 - 3254; DOI:
10.1021/ic00188a044
PDF
Observation of both bridging and chelating modes of the 2-(2-pyridyl)-1,8-naphthyridine ligand (pynp) in a single dirhodium(II) complex: x-ray structure of [Rh2(pynp)3Cl2][PF6]2.CH3CN
A. T. Baker, Wayne R. Tikkanen, William C. Kaska, and Peter C. Ford
pp 3254 - 3256; DOI:
10.1021/ic00188a045
PDF
Mechanism of palladium(II)-catalyzed carbon-carbon double bond isomerization in olefins
Ayusman Sen and Ta Wang Lai
pp 3257 - 3258; DOI:
10.1021/ic00188a046
PDF
Reaction of carbon disulfide with trinuclear palladium and platinum clusters. Crystal structure of Pt2(.mu.-CS2)2(P(tert-Bu)2Ph)2
David H. Farrar, Ravi R. Gukathasan, and Stephen A. Morris
pp 3258 - 3261; DOI:
10.1021/ic00188a047
PDF
Synthesis and characterization of bis[difluorooxychlorine(V)] hexafluoronickelate(IV), (ClF2O)2NiF6
William W. Wilson and Karl O. Christe
pp 3261 - 3262; DOI:
10.1021/ic00188a048
PDF
Dynamic Jahn-Teller effects in high-spin trigonal-bipyramidal nickel(II) complexes
Lucia Banci, Cristiano Benelli, and Dante Gatteschi
pp 3262 - 3263; DOI:
10.1021/ic00188a049
PDF
Synthesis of sodium and tetra-n-butylammonium dicyanodihydroborate
Bernard F. Spielvogel, Fahim U. Ahmed, Mrinal K. Das, and Andrew T. McPhail
pp 3263 - 3265; DOI:
10.1021/ic00188a050
PDF
First observation of resolvable coupling between manganese-55 and carbon-13
Roger M. Nielson and Scot Wherland
pp 3265 - 3266; DOI:
10.1021/ic00188a051
PDF
Copper(I) and copper(II) complexes of 3-methoxy-1,5-dithiacyclooctane. Evidence of a long-range electrostatic interaction in the copper(I) complex giving an "apparent" five-coordinated complex
W. K. Musker, M. M. Olmstead, and R. M. Kessler
pp 3266 - 3269; DOI:
10.1021/ic00188a052
PDF
Synthesis and characterization of ligand-bridged dimers. 2. Homobinuclear derivatives of (methylcyclopentadienyl)manganese dicarbonyl
P. L. Gaus, Nancy Marchant, Mary Anne Marsinek, and M. O. Funk
pp 3269 - 3271; DOI:
10.1021/ic00188a053
PDF
Electronic structure of octachloroditungstate(II)
Ramiro Arratia-Perez and David A. Case
pp 3271 - 3273; DOI:
10.1021/ic00188a054
PDF
Use of the bireciprocal length-energy relationship to predict the structures of boron hydrides and the structural analogy between boron hydrides and other atom clusters
D. J. Fuller and D. L. Kepert
pp 3273 - 3274; DOI:
10.1021/ic00188a055
PDF

Issue 21


Pyridinium molybdates. Synthesis and structure of an octamolybdate containing coordinately bound pyridine: [(C5H5N)2Mo8O26]4-
E. M. McCarron, J. F. Whitney, and D. B. Chase
pp 3275 - 3280; DOI:
10.1021/ic00189a001
PDF
Hydrothermal synthesis of a new molybdenum hollandite containing tetranuclear metal-atom clusters. X-ray crystal structure of K2Mo8O16
Charlie C. Torardi and Joseph C. Calabrese
pp 3281 - 3284; DOI:
10.1021/ic00189a002
PDF
Chemistry and structure of hexakis(thiourea-S)technetium(III) trichloride tetrahydrate, [Tc(SC(NH2)2)6]Cl3.4H2O
M. J. Abrams, A. Davison, R. Faggiani, A. G. Jones, and C. J. L. Lock
pp 3284 - 3288; DOI:
10.1021/ic00189a003
PDF
Halide abstraction from titanium(III) chloride by zinc chloride
Kirsten Folting, John C. Huffman, Rick L. Bansemer, and Kenneth G. Caulton
pp 3289 - 3292; DOI:
10.1021/ic00189a004
PDF
Polyoxotungstate anions containing high-valent rhenium. 1. Keggin anion derivatives
Fernando Ortega and Michael T. Pope
pp 3292 - 3297; DOI:
10.1021/ic00189a005
PDF
Reaction entropies of redox reactions of transition-metal complexes with sulfur donor ligands
J. E. J. Schmitz and J. G. M. Van der Linden
pp 3298 - 3303; DOI:
10.1021/ic00189a006
PDF
Reactions of coordinated ligands. 13. Template syntheses of 14- to 16-membered tetraphosphacycloalkanes using bis(tertiary phosphines) with protected carbonyl groups in the alkyl side chains
Rainer Bartsch, Sibbele Hietkamp, Helmut Peters, and Othmar Stelzer
pp 3304 - 3309; DOI:
10.1021/ic00189a007
PDF
Spontaneous solvolysis reactions of some palladium(II)-diethylenetriamine complexes in aqueous solution: equilibrium and kinetic data
M. Kotowski and Rudi Van Eldik
pp 3310 - 3312; DOI:
10.1021/ic00189a008
PDF
Synthesis and properties of rotaxane complexes. 2. Rotaxanes consisting of .alpha.-or .beta.-cyclodextrin threaded by (.mu.-.alpha.,.omega.-diaminoalkane)bis[chlorobis(ethylenediamine)cobalt(III)] complexes
Horoshi Ogino and Kazuya Ohata
pp 3312 - 3316; DOI:
10.1021/ic00189a009
PDF
A Menschutkin type amine alkylation involving methyl transfer to benzylamine from palladium(II) chelate complexes of o-(diphenylphosphino)thioanisole
Annamarie Benefiel, D. Max Roundhill, William C Fultz, and Arnold L. Rheingold
pp 3316 - 3324; DOI:
10.1021/ic00189a010
PDF
Nonadiabatic effects in outer-sphere electron-transfer reactions of cobalt(III) complexes: experimental probes of charge-transfer perturbations of the rates of several cross-reactions
T. Ramasami and John F. Endicott
pp 3324 - 3333; DOI:
10.1021/ic00189a011
PDF
Single-crystal carbon-13 ENDOR and TRIPLE studies on tetra-n-butylammonium bis(cis-1,2-cyanoethenedithiolato)cuprate(II), (n-Bu4N)2[Cu(mnt)2]
R. Kirmse, J. Stach, U. Abram, W. Dietzsch, R. Boettcher, M. C. M. Gribnau, and C. P. Keijzers
pp 3333 - 3338; DOI:
10.1021/ic00189a012
PDF
Electronic spectra of tris(.mu.-halo)bis(triammineruthenium)(2+) ions: evidence for delocalized mixed-valence D3h ruthenium(II, III) ground states
Noel S. Hush, James K. Beattie, and Vivienne M. Ellis
pp 3339 - 3342; DOI:
10.1021/ic00189a013
PDF
Reactivity of palladium dithiozonate with Lewis acids and bases
Enxin Ma and H. Freiser
pp 3342 - 3344; DOI:
10.1021/ic00189a014
PDF
Solvent extraction equilibria and kinetics in the palladium(II)-hydrochloric acid-7-(1-vinyl-3,3,5,5-tetramethylhexyl)-8-quinolinol system
Enxin Ma and Henry Freiser
pp 3344 - 3347; DOI:
10.1021/ic00189a015
PDF
Formation and dissociation kinetics of alkaline-earth ions with benzo-substituted cryptands
Jean M. Bemtgen, Mary E. Springer, Vincent M. Loyola, Ralph G. Wilkins, and Richard W. Taylor
pp 3348 - 3353; DOI:
10.1021/ic00189a016
PDF
Gas-solid interactions of zinc tetraphenylporphine with various volatile ligands
Jack E. Leonard, Junichi Itoh, Russell Seguin, and C. S. Giam
pp 3353 - 3357; DOI:
10.1021/ic00189a017
PDF
Electrochemical studies of ferrocene and ferrocenium ion in aluminum chloride-N-(1-butyl)pyridinium chloride ionic liquid
Zenon J. Karpinski, Chenniah Nanjundiah, and Robert A. Osteryoung
pp 3358 - 3364; DOI:
10.1021/ic00189a018
PDF
Mono- and binuclear tri- and tetracarbonyl complexes of chromium(0), molybdenum(0), and tungsten(0) with the 2,2'-bipyrimidine radical anion
Wolfgang Kaim
pp 3365 - 3368; DOI:
10.1021/ic00189a019
PDF
Substituent effects on bonding properties in diphosphenes, disilenes and diimines
Wolfgang W. Schoeller and Volker Staemmler
pp 3369 - 3373; DOI:
10.1021/ic00189a020
PDF
Stereoelectronic effect of cyclization in aminophosphine systems: structural PES and NMR study of Me2NP(OCH2)2CMe2 and CH2(CH2CH2)2NP(OCH2)2CMe2
D. E. Schiff, J. W. Richardson, R. A. Jacobson, A. H. Cowley, J. Lasch, and J. G. Verkade
pp 3373 - 3377; DOI:
10.1021/ic00189a021
PDF
Molecular photoelectron spectroscopic investigation of some polycyclic Group VA compounds and related acyclic species. 2. Free and coordinated phosphite, thiophosphite, and arsenite esters
A. H. Cowley, M. Lattman, R. A. Montag, and J. G. Verkade
pp 3378 - 3383; DOI:
10.1021/ic00189a022
PDF
Preparation of the crystalline .beta.(bridged) isomer of Mo2Cl4(dppe)2 and determination of its crystal structure
Pradyot Agaskar and F. Albert Cotton
pp 3383 - 3387; DOI:
10.1021/ic00189a023
PDF
X-ray, ESR and optical absorption studies of tetrakis(cyclohexylamine)copper(II) nitrate: an example of a flattened-tetrahedral copper(II) complex
J. Gouteron, S. Jeannin, Yves Jeannin, J. Livage, and C. Sanchez
pp 3387 - 3393; DOI:
10.1021/ic00189a024
PDF
Synthesis and x-ray structure of the first mercury(I)-containing polytungstate, [(Hg2)2WO(H2O)(AsW9O33)2]10-, with an odd open-shell structure
J. Martin-Frere and Y. Jeannin
pp 3394 - 3398; DOI:
10.1021/ic00189a025
PDF
Exchange interaction in multinuclear transition-metal complexes. 6. Nature of metal-metal coupling in dinuclear iron(III) systems containing FeOFeO bridging units
B. Chiari, O. Piovesana, T. Tarantelli, and P. F. Zanazzi
pp 3398 - 3404; DOI:
10.1021/ic00189a026
PDF
Substituted cysteamine ligands and their complexes with molybdenum(VI)
James L. Corbin, Kenneth F. Miller, Narayanakutty Pariyadath, Jay Heinecke, Alice E. Bruce, Scot Wherland, and Edward I. Stiefel
pp 3404 - 3412; DOI:
10.1021/ic00189a027
PDF
Six-coordinate dioxomolybdenum(VI) complexes containing a nonoctahedral structure with a short sulfur-sulfur contact
Jeremy M. Berg, Darlene J. Spira, Keith O. Hodgson, Alice E. Bruce, Kenneth F. Miller, James L. Corbin, and Edward I. Stiefel
pp 3412 - 3418; DOI:
10.1021/ic00189a028
PDF
Reduction of perchlorate ion by (N-(hydroxyethyl)ethylenediaminetriacetato) aquatitanium(III)
Bo Ying Liu, Paul A. Wagner, and Joseph E. Earley
pp 3418 - 3420; DOI:
10.1021/ic00189a029
PDF
Reactions at the metal vertex of a ruthenacarborane cluster. Activation of carbon monoxide by closo-3,3,3-(CO)3-3,1,2-RuC2B9H11
Paul E. Behnken and M. Frederick Hawthorne
pp 3420 - 3423; DOI:
10.1021/ic00189a030
PDF
Spectroelectrochemical studies on tris(bipyridyl)iridium complexes: ultraviolet, visible and near-infrared spectra of the series [Ir(bipyridyl)3]3+/2+/+/0
Vyvyan T. Coombe, Graham A. Heath, Alan J. MacKenzie, and Lesley J. Yellowlees
pp 3423 - 3425; DOI:
10.1021/ic00189a031
PDF
Solution structure and properties of the [(2,2'-bipyridinyl-C3,N')bis(2,2'-bipyridine-N,N')iridium(III)](2+) hydrate ion, "pseudo-[Ir(bpy)3(OH)]2+"
Paul S. Braterman, Graham A. Heath, Alan J. MacKenzie, Brian C. Noble, Robert D. Peacock, and Lesley J. Yellowlees
pp 3425 - 3426; DOI:
10.1021/ic00189a032
PDF
Molecular orbital study of the substituent effect on the redox properties of disubstituted bipyridines and their ruthenium(II) complexes
Yasuhiko Ohsawa, Myung Hwan Whangbo, Kenneth W. Hanck, and M. Keith DeArmond
pp 3426 - 3428; DOI:
10.1021/ic00189a033
PDF
Mechanisms of alkylation of mercuric ions by alkylcobalamins
Yueh Tai Fanchiang
pp 3428 - 3430; DOI:
10.1021/ic00189a034
PDF

Issue 22


Reactions of phosphorus electrophiles with [(.eta.5-C5Me5)Fe(CO)2]-; spectroscopic evidence for a phosphinidene complex
Hiroshi Nakazawa, William E. Buhro, Guy Bertrand, and J. A. Gladysz
pp 3431 - 3433; DOI:
10.1021/ic00190a001
PDF
Photochemical isomerization of [Cp*MoS(.mu.-S)]2 (Cp* = .eta.5-(Me)5C5) to Cp*Mo4(.mu.-S2)(.mu.-S)2 and [Cp*MoS]2(.mu.-S2)
Alice E. Bruce and David R. Tyler
pp 3433 - 3434; DOI:
10.1021/ic00190a002
PDF
Adiabatic intramolecular electron transfer in pyrazine-2,6-dicarboxylato-bridged complexes of cobalt(III)-ruthenium(II) and of cobalt(III)-iron(II): comparison of inner-sphere vs. outer-sphere activated complexes
Ademir Neves, Willy Herrmann, and Karl Wieghardt
pp 3435 - 3443; DOI:
10.1021/ic00190a003
PDF
Reactions of the nickel(II) and copper(II) complexes of the dihydrazone ligand 4,4,9,9-tetramethyl-5,8-diazadodecane-2,11-dione dihydrazone with pentane-2,4-dione. Crystal structures of two resultant nickel(II) complexes
Neil F. Curtis, Frederick W. B. Einstein, and Anthony C. Willis
pp 3444 - 3449; DOI:
10.1021/ic00190a004
PDF
Two quadruply bonded amino acid complexes of dichromium(II): structures of tetrakis(glycine)tetrabromodichromium(II) tetrahydrate and tetrakis(glycine)tetrachlorodichromium(II) trihydrate
Michael Ardon, Avi Bino, Shmuel Cohen, and Timothy R. Felthouse
pp 3450 - 3455; DOI:
10.1021/ic00190a005
PDF
3,3',4,4'-Tetramethyl-1,1'-diphosphaferrocene (DPF): template ligand for the formation of polymetallic complexes
Bernard Deschamps, Francois Mathey, Jean Fischer, and John H. Nelson
pp 3455 - 3462; DOI:
10.1021/ic00190a006
PDF
4,5-Dimethyl-2-(2-pyridyl)phosphorin as a chelating ligand. Synthesis and x-ray crystal structure analysis of (4,5-dimethyl-2-(2-pyridyl)phosphorin)tetracarbonylchromium
Anne Breque, Catherine C. Santini, Francois Mathey, Jean Fischer, and Andre Mitschler
pp 3463 - 3467; DOI:
10.1021/ic00190a007
PDF
Monomeric and anion-bridged dimeric and polymeric oxamide oxime complexes of copper(II): preparation, crystal and molecular structures, and magnetic properties
Helmut Endres, Dietrich Noethe, Elisabeth Rossato, and William E. Hatfield
pp 3467 - 3473; DOI:
10.1021/ic00190a008
PDF
Electron-transfer barriers and metal-ligand bonding as a function of metal oxidation state. 3. Crystal and molecular structures of tris(2,2'-bipyridine)nickel(III) triperchlorate-2-acetonitrile-0.5-dichloromethane
David J. Szalda, Donal H. Macartney, and Norman Sutin
pp 3473 - 3479; DOI:
10.1021/ic00190a009
PDF
Transfer of electronic excitation energy in the antiferromagnets rubidium trichloromanganate(II), cesium trichloromanganate(II), cesium tribromomanganate(II), and rubidium tetrachloromanganate(II)
Ursula Kambli and Hans U. Guedel
pp 3479 - 3486; DOI:
10.1021/ic00190a010
PDF
Ligation of phosphorus ligands to silver(I). 2. Electronic and steric effects in the coordination of one to four P(OR)3 and PR3 ligands
S. M. Socol and J. G. Verkade
pp 3487 - 3493; DOI:
10.1021/ic00190a011
PDF
Direct observation of the ground-state splitting in d5 and d7 metallocenes by inelastic neutron scattering
Anton Stebler, Albert Furrer, and John H. Ammeter
pp 3493 - 3500; DOI:
10.1021/ic00190a012
PDF
Forbidden vibrational modes in iron(II), ruthenium(II), and osmium(II) hexacyanides: a tunneling, IR, and Raman spectroscopy study
K. W. Hipps, Stephen D. Williams, and Ursula Mazur
pp 3500 - 3505; DOI:
10.1021/ic00190a013
PDF
Infrared spectroscopic investigation of the reaction between thionyl chloride and nitrogen dioxide
T. C. DeVore and T. N. Gallaher
pp 3506 - 3509; DOI:
10.1021/ic00190a014
PDF
An EPR study of [CoIIL2]2+, [CoIILL']2+ and [CoIIILL'O2-]2+ (L = 2,2',2"-terpyridine; L' = 2,2'-bipyridine) complexes in zeolite Y
Koichi Mizuno, Seiichiro Imamura, and Jack H. Lunsford
pp 3510 - 3514; DOI:
10.1021/ic00190a015
PDF
Reactions of platinum(II) aqua complexes. 1. Multinuclear (platinum-195, nitrogen-15, and phosphorus-31) NMR study of reactions between the cis-diamminediaquaplatinum(II) cation and the oxygen-donor ligands hydroxide, perchlorate, nitrate, sulfate, phosphate, and acetate
Trevor G. Appleton, Ron D. Berry, Carol A. Davis, John R. Hall, and Heather A. Kimlin
pp 3514 - 3521; DOI:
10.1021/ic00190a016
PDF
Reactions of platinum(II) aqua complexes. 2. Platinum-195 NMR study of reactions between the tetraaquaplatinum(II) cation and chloride, hydroxide, perchlorate, nitrate, sulfate, phosphate, and acetate
Trevor G. Appleton, John R. Hall, Stephen F. Ralph, and Craig S. M. Thompson
pp 3521 - 3525; DOI:
10.1021/ic00190a017
PDF
Kinetic study of the reaction of aquochromium(II) ions with benzyl radicals in aqueous solutions; thermodynamics of the chromium-carbon bond
Reed J. Blau, James H. Espenson, and Andreja Bakac
pp 3526 - 3528; DOI:
10.1021/ic00190a018
PDF
Kinetics and mechanism of the complexation reaction of gallium(III) with tropolone as studied by a high-pressure stopped-flow technique. Evidence for a dissociative-interchange mechanism
Shinkichi Yamada, Akiko Iwanaga, Shigenobu Funahashi, and Motoharu Tanaka
pp 3528 - 3532; DOI:
10.1021/ic00190a019
PDF
Reactivity of decamethylvanadocene with phenyl isothiocyanate and carbonyl sulfide: reactions related to the desulfurization of the thiocarbonyl group
S. Gambarotta, M. L. Fiallo, Carlo Floriani, A. Chiesi-Villa, and C. Guastini
pp 3532 - 3537; DOI:
10.1021/ic00190a020
PDF
Oxidation of the carbonylbis(1,2-bis(diphenylphosphino)ethane)iridium(I) cation. Preparation and characterization of a series of iridium(III) carbonyl dications
Michael A. Lilga and James A. Ibers
pp 3538 - 3543; DOI:
10.1021/ic00190a021
PDF
Immobile- and mobile-phase ESR spectroscopy of copper complexes: studies on biologically interesting bis(thiosemicarbazonato)copper(II) chelates
William E. Antholine, Riccardo Basosit, James S. Hyde, Suzanne Lyman, and David H. Petering
pp 3543 - 3548; DOI:
10.1021/ic00190a022
PDF
Reactivity of the peroxo ligand in metalloporphyrin complexes. Reaction of sulfur dioxide with iron and titanium porphyrin peroxo complexes to give sulfato complexes of sulfate
Andrew R. Miksztal and Joan Selverstone Valentine
pp 3548 - 3552; DOI:
10.1021/ic00190a023
PDF
Crystal and molecular structure of the (.mu.-oxo)bis[aquobis(phenanthroline)iron(III)] complex, a Raman spectroscopic model for the binuclear iron site in hemerythrin and ribonucleotide reductase
Jeffrey E. Plowman, Thomas M. Loehr, Cynthia K. Schauer, and Oren P. Anderson
pp 3553 - 3559; DOI:
10.1021/ic00190a024
PDF
Iron porphyrin models of peroxidase enzyme intermediates: oxidation of deuteroferriheme by iodosobenzene and iodobenzene diacetate
Henry C. Kelly and Sritana C. Yasui
pp 3559 - 3563; DOI:
10.1021/ic00190a025
PDF
Oxidative electrochemistry of iron thiocarbonyl porphyrins
Lawrence A. Bottomley, Mark R. Deakin, and Jean Noel Gorce
pp 3563 - 3571; DOI:
10.1021/ic00190a026
PDF
Quenching of the triplet states of organic compounds by iron(III) complexes of .beta.-diketones due to reversible electron transfer
F. Wilkinson and C. Tsiamis
pp 3571 - 3577; DOI:
10.1021/ic00190a027
PDF
The nature of the sulfur-carbon triple bond
James E. Boggs
pp 3577 - 3580; DOI:
10.1021/ic00190a028
PDF
Carbon-13 CP/MAS NMR and crystallographic investigations of the structure and solid-state transformations of lead(II) acetate trihydrate
Robert G. Bryant, V. P. Chacko, and Margaret C. Etter
pp 3580 - 3584; DOI:
10.1021/ic00190a029
PDF
Synthesis, spectroscopic properties, and x-ray structure of [1,7-bis(5-methylimidazol-4-yl)-2,6-dithiaheptane]dichlorocopper(II): a compound with unusually long copper(II)-thioether bonds
Jacobus Van Rijn, Willem L. Driessen, Jan Reedijk, and Jean Marie Lehn
pp 3584 - 3588; DOI:
10.1021/ic00190a030
PDF
Synthesis and spectroscopic characterization of transition-metal chelates containing a new hexadentate ligand. Crystal and molecular structure of the heptacoordinated compound (perchlorato-O) [N,N,N',N'-tetrakis(pyrazol-1-ylmethyl)-1,2-diaminoethane]manganese(II) perchlorate
Frans B. Hulsbergen, Willem L. Driessen, Jan Reedijk, and Gerrit C. Verschoor
pp 3588 - 3592; DOI:
10.1021/ic00190a031
PDF
Further studies of the phosphine complexes of niobium(IV) chloride
F. Albert Cotton, Stan A. Duraj, and Wieslaw J. Roth
pp 3592 - 3596; DOI:
10.1021/ic00190a032
PDF
Chemistry of metals in ionomers: reactions of rhodium-PSSA with carbon monoxide, molecular hydrogen, and water
Vincent D. Mattera, Philip J. Squattrito, and William M. Risen
pp 3597 - 3601; DOI:
10.1021/ic00190a033
PDF
Metal cluster vs. atom reactivities: magnesium cluster Grignard reagents
Yuzo Imizu and Kenneth J. Klabunde
pp 3602 - 3605; DOI:
10.1021/ic00190a034
PDF
Reactions of tetrasulfur tetranitride with chlorodiphenylphosphine, dichlorophenylphosphine, and phosphorus trichloride: preparation of the six-membered rings (Ph2PN)2(NSX) (X = Cl, Br, I, Ph, NR2) and the related cation [(Ph2PN)2NS]+
T. Chivers and M. N. S. Rao
pp 3605 - 3609; DOI:
10.1021/ic00190a035
PDF
Photochemical reduction of the uranyl ion with dialkyl sulfides
S. S. Sandhu, K. B. Kohli, and A. S. Brar
pp 3609 - 3612; DOI:
10.1021/ic00190a036
PDF
Synthetic, structural, and catalytic studies on ethylene and carbonyl complexes of rhodium(I) containing 2-alkoxy-1,3-dioxa-6,9-diaza-2-phosphacycloundecane ligands
Claude Vaccher, Andre Mortreux, Francis Petit, Jean Paul Picavet, Henri Sliwa, Nicholas W. Murrall, and Alan J. Welch
pp 3613 - 3617; DOI:
10.1021/ic00190a037
PDF
X.alpha. method as a tool for structure elucidation of short-lived transients generated by pulse radiolysis or flash photolysis. 1. Reductive reactions of hexachloroplatinate(2-)
A. Goursot, H. Chermette, E. Penigault, M. Chanon, and W. L. Waltz
pp 3618 - 3625; DOI:
10.1021/ic00190a038
PDF
Carbon-13, phosphorus-31 and proton NMR studies of the interactions of the carbonylbis(triphenylphosphine)rhodium(I) cation with base pairs of 6-mercaptoguanosine and 8-mercaptoguanosine with cytidine
David W. Abbott and Clifton Woods
pp 3626 - 3629; DOI:
10.1021/ic00190a039
PDF
Nitrogen-15 and cobalt-59 NMR study of the bent nitrosyl ligand in cobalt complexes
John Bultitude, Leslie F. Larkworthy, Joan Mason, David C. Povey, and Barry Sandell
pp 3629 - 3633; DOI:
10.1021/ic00190a040
PDF
Synthesis, characterization, and x-ray molecular structures of mono- and dinuclear copper complexes with 2,7-bis(2-pyridyl)-1,8-naphthyridine
Wayne R. Tikkanen, Carl Krueger, Kenneth D. Bomben, William L. Jolly, William Kaska, and Peter C. Ford
pp 3633 - 3638; DOI:
10.1021/ic00190a041
PDF
Solvent, ligand, and ionic charge effects on reaction entropies for simple transition-metal redox couples
Joseph T. Hupp and Michael J. Weaver
pp 3639 - 3644; DOI:
10.1021/ic00190a042
PDF
Investigation of solution kinetics of transition-metal complexes by EPR spectroscopy
Harald Gampp
pp 3645 - 3649; DOI:
10.1021/ic00190a043
PDF
The effect of anions on redox reactions. The chromium(II) reduction of bis(pentane-2,4-dionato)ethylenediaminecobalt(III) in the presence of chloride ions
Nita A. Lewis and Ananda M. Ray
pp 3649 - 3653; DOI:
10.1021/ic00190a044
PDF
Syntheses of heptafluoronitrosocyclobutane and nonafluoronitrosocyclopentane and their reactions with tetrafluoroethene, 1,3-hexafluorobutadiene and tetrafluorohydrazine
Helen M. Marsden and Jeanne M. Shreeve
pp 3654 - 3659; DOI:
10.1021/ic00190a045
PDF
Molecular structure of diaminotrifluorophosphorane, PF3(NH2)2, in the gas phase
Colin J. Marsden, Kenneth Hedberg, Jeanne M. Shreeve, and Krishna D. Gupta
pp 3659 - 3662; DOI:
10.1021/ic00190a046
PDF
Flash photolysis investigation of photoactive ruthenium complex mixtures
Jeffrey K. Nagle and Thomas J. Meyer
pp 3663 - 3665; DOI:
10.1021/ic00190a047
PDF
Substitution and addition reactions of a methylenephosphine with alkyllithium reagents
Bei Li Li and Robert H. Neilson
pp 3665 - 3666; DOI:
10.1021/ic00190a048
PDF
Synthesis and properties of silver trifluoride AgF3
Roland Bougon, Bui Huy Tue, M. Lance, and H. Abazli
pp 3667 - 3668; DOI:
10.1021/ic00190a049
PDF
Kinetics and mechanism of the formation of alkyl radicals and alkyl(pentaaquo)chromium(2+) complexes by the reaction of free radicals derived from (2-hydroxy-2-propyl)(pentaaquo)chromium(2+) ions with alkyl iodides
James H. Espenson, Suzanne L. Bruhn, and Andreja Bakac
pp 3668 - 3670; DOI:
10.1021/ic00190a050
PDF
Hydrolytic reactions of radon fluorides
Lawrence Stein
pp 3670 - 3671; DOI:
10.1021/ic00190a051
PDF
New routes to the preparation of the aquamolybdenum(IV) ion by comproportionation reactions
F. Albert Cotton, David O. Marler, and Willi Schwotzer
pp 3671 - 3673; DOI:
10.1021/ic00190a052
PDF
Reexamination of the .pi. bonding in dichloro(cycloocta-1,5-diene)platinum
Ashfaquzzaman Syed, Edwin D. Stevens, and Sandra G. Cruz
pp 3673 - 3674; DOI:
10.1021/ic00190a053
PDF
Micelle-trapped tris(benzhydroxamato)iron(III) as a siderophore model compound
Ingolfur Kristjansson, Finn H. Nielsen, and Jens Ulstrup
pp 3674 - 3677; DOI:
10.1021/ic00190a054
PDF
Synthesis and characterization of an oxygen-bridged vanadium(III) dimer
P. Chandrasekhar and P. H. Bird
pp 3677 - 3679; DOI:
10.1021/ic00190a055
PDF
Metal vapor routes to metal-isocyanide complexes. Synthesis and molecular structure of tris(.mu.-cyclohexyl isocyanide)tris(cyclohexyl isocyanide)-triangulo-tripalladium
Colin G. Francis, Saeed I. Khan, and Peter R. Morton
pp 3680 - 3681; DOI:
10.1021/ic00190a056
PDF
Crystal structure of Au7(PPh3)7+: corrigendum
Richard E. Marsh
pp 3682 - 3682; DOI:
10.1021/ic00190a057
PDF

Issue 23


A new structure type for a 6-electron triangulo tungsten cluster: W3(.mu.3-CMe)(.mu.-O-iso-Pr)3(O-iso-Pr)6
Malcolm H. Chisholm, David M. Hoffman, and John C. Huffman
pp 3683 - 3684; DOI:
10.1021/ic00191a001
PDF
Olefin coordination with rhodium(II) trifluoroacetate
Michael P. Doyle, Mark R. Colsman, and Mitchell S. Chinn
pp 3684 - 3685; DOI:
10.1021/ic00191a002
PDF
Electron-transfer chemistry of electronically excited octachlorodirhenate(III)
Daniel G. Nocera and Harry B. Gray
pp 3686 - 3688; DOI:
10.1021/ic00191a003
PDF
Electron transfer. 70. Reductions of oxyhalogens by vitamin B12r (Cob(II)alamin)
P. N. Balasubramanian and E. S. Gould
pp 3689 - 3693; DOI:
10.1021/ic00191a004
PDF
Oxidation-reduction reactions of complexes with macrocyclic ligands. Role of kinetic factors in distinguishing mechanistic pathways in reactions of copper(I) complexes with coordinated dioxygen
Megumu Munakata and John F. Endicott
pp 3693 - 3698; DOI:
10.1021/ic00191a005
PDF
Solvent effects on redox reactions. 1. Chromium(II) reduction of tris(pentane-2,4-dionato)cobalt(III) in water/dimethylformamide solvent mixtures
Nita A. Lewis and Ananda M. Ray
pp 3698 - 3704; DOI:
10.1021/ic00191a006
PDF
Tetraborane(8) adducts of strongly basic phosphines
Mitsuaki Kameda, Mamoru Shimoi, and Goji Kodama
pp 3705 - 3709; DOI:
10.1021/ic00191a007
PDF
Reactions of hexahydrobis(trimethylphosphine)triboron(1+) octahydrotriborate(1-) with Lewis bases. Novel formation of tetraborane(8) adducts
Mitsuaki Kameda and Goji Kodama
pp 3710 - 3712; DOI:
10.1021/ic00191a008
PDF
Boron-nitrogen compounds. 99. Studies on B-(pyrazol-1-yl)pyrazaboles
Kurt Niedenzu and Philipp M. Niedenzu
pp 3713 - 3716; DOI:
10.1021/ic00191a009
PDF
Synthesis of isotopic forms of dilithiomethane [(CH26Li2)n and (CD2Li2)n] and preliminary structural information obtained by x-ray powder and solid-phase carbon-13 NMR techniques
John A. Gurak, John W. Chinn, Richard J. Lagow, Hugo Steinfink, and Constantino S. Yannoni
pp 3717 - 3720; DOI:
10.1021/ic00191a010
PDF
Synthesis, properties, and reactions of bis((trifluoromethyl)sulfonyl) imide, (CF3SO2)2NH
Jerry Foropoulos and Darryl D. DesMarteau
pp 3720 - 3723; DOI:
10.1021/ic00191a011
PDF
Copper(II) complexes with linear pentadentate chelators
Harald Gampp, Doris Haspra, Marcel Maeder, and Andreas D. Zuberbuehler
pp 3724 - 3730; DOI:
10.1021/ic00191a012
PDF
Solution studies of systems with polynuclear complex formation. 5. Copper(II) and cadmium(II) D-(+)-tartrate systems
Kjell Blomqvist and Ebbe R. Still
pp 3730 - 3734; DOI:
10.1021/ic00191a013
PDF
Dihalo- and aquahalobis(1,3-propanediamine)rhodium(III): aqueous solution photochemistry and photophysics. Steric effects on ligand field excited-state reactivities
L. H. Skibsted, M. P. Hancock, D. Magde, and D. A. Sexton
pp 3735 - 3740; DOI:
10.1021/ic00191a014
PDF
Electrochemistry and photochemistry of silver(II) complexes of macrocyclic amines
I. J. Clark and Mac B. Harrowfield
pp 3740 - 3745; DOI:
10.1021/ic00191a015
PDF
Effect of high pressure on the emission spectrum of tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate single crystals
Hartmut Yersin and Erich Gallhuber
pp 3745 - 3748; DOI:
10.1021/ic00191a016
PDF
Flash photolysis studies of dinuclear manganese carbonyl compounds
Howard W. Walker, Richard S. Herrick, Robert J. Olsen, and Theodore L. Brown
pp 3748 - 3752; DOI:
10.1021/ic00191a017
PDF
Optical and ESR studies for the reaction of molybdenum tetraphenylporphyrns in .gamma.-ray irradiated 2-methyltetrahydrofuran
Taira Imamura, Masayuki Takahashi, Tetsuya Tanaka, Takashi Jin, Masatoshi Fujimoto, Sadashi Sawamura, and Meiseki Katayama
pp 3752 - 3755; DOI:
10.1021/ic00191a018
PDF
Structure and vibrational spectra of oxonium hexafluoroarsenates(V) and -antimonates(V)
K. O. Christe, P. Charpin, E. Soulie, R. Bougon, J. Fawcett, and D. R. Russell
pp 3756 - 3766; DOI:
10.1021/ic00191a019
PDF
Lewis base adducts of Group IB metal compounds. 8. High-resolution solid-state phosphorus-31 nuclear magnetic resonance spectra of tetrameric ((triphenylphosphine)copper(I) halide) complexes and crystal structure determination of "cubane" [PPh3CuBr]4
Peter F. Barron, Jeffrey C. Dyason, Lutz M. Engelhardt, Peter C. Healy, and Allan H. White
pp 3766 - 3769; DOI:
10.1021/ic00191a020
PDF
Lewis base adducts of Group IB metal(I) compounds. 9. Synthesis and crystal structures of adducts of copper(I) thiocyanate with substituted pyridine bases
Peter C. Healy, Chaveng Pakawatchai, Rocco I. Papasergio, Vincent A. Patrick, and Allan H. White
pp 3769 - 3776; DOI:
10.1021/ic00191a021
PDF
Molecular and crystal structure of an open cyclamphosphorane adduct: cyclamphosphane-bis(borane)
Jean Marc Dupart, Andre Grand, Simonne Pace, and Jean G. Riess
pp 3776 - 3779; DOI:
10.1021/ic00191a022
PDF
Raman spectra of Co(NH3)6X3 (X = Cl, Br, I) complexes
Lucjan Dubicki and Bryce Williamson
pp 3779 - 3784; DOI:
10.1021/ic00191a023
PDF
Ternary complexes in solution. 44. Dependence of an intramolecular aromatic-ring stacking interaction in mixed-ligand copper(II) complexes in aqueous solution on the distance of the stacking moiety from the coordinating group and the solid-state structure of the ternary copper(II)-1,10-phenanthroline-phenylpropionate complex
Erich Dubler, Ulrich K. Haering, Kurt H. Scheller, Philippe Baltzer, and Helmut Sigel
pp 3785 - 3792; DOI:
10.1021/ic00191a024
PDF
Synthesis and characterization of a series of isomeric oxotechnetium(V) diamido dithiolates
David Brenner, Alan Davison, John Lister-James, and Alun G. Jones
pp 3793 - 3797; DOI:
10.1021/ic00191a025
PDF
Solution structure of the chromium(III) complex with EDTA by deuteron NMR spectroscopy
W. D. Wheeler and J. I. Legg
pp 3798 - 3802; DOI:
10.1021/ic00191a026
PDF
Ab initio direct calculation of the singlet-triplet splitting in a .mu.-oxalato copper(II) binuclear complex
M. F. Charlot, M. Verdaguer, Y. Journaux, P. De Loth, and J. P. Daudey
pp 3802 - 3808; DOI:
10.1021/ic00191a027
PDF
Design of .mu.-oxalato copper(II) binuclear complexes exhibiting expected magnetic properties
Miguel Julve, Michel Verdaguer, Alain Gleizes, Michele Philoche-Levisalles, and Olivier Kahn
pp 3808 - 3818; DOI:
10.1021/ic00191a028
PDF
Structure of the transition state for water exchange on hexaaquo divalent metal ions
Kenneth E. Newman and Kim M. Adamson-Sharpe
pp 3818 - 3822; DOI:
10.1021/ic00191a029
PDF
Preparation and properties of new pentacoordinate nitrosyliron complexes
Gabriele Albertin and Emilio Bordignon
pp 3822 - 3825; DOI:
10.1021/ic00191a030
PDF
Crystallographic characterization of the novel (Ag5Br8)n3n- polyanion
John D. Kildea and Allan H. White
pp 3825 - 3827; DOI:
10.1021/ic00191a031
PDF
Coordination chemistry of methylmercury(II) with flexible tripod ligands containing pyridyl and N-methylimidazolyl groups, including the crystal structure of [bis(N-methylimidazol-2-yl)(pyridin-2-yl)methanol-N,N',N'']methylmercury(II) nitrate, [MeHg(py(N-MeIm)2COH)]NO3
Allan J. Canty, Jennifer M. Patrick, and Allan H. White
pp 3827 - 3830; DOI:
10.1021/ic00191a032
PDF
Fast infrared detection of pentacarbonyldinitrogenchromium (Cr(CO)5N2) in room-temperature solution
Stephen P. Church, Friedrich Wilhelm Grevels, Horst Hermann, and Kurt Schaffner
pp 3830 - 3833; DOI:
10.1021/ic00191a033
PDF
Hyperfine parameters in an exchange-coupled copper(II)-nickel(II) pair. Relation to the local hyperfine splitting
S. R. Desjardins, I. Morgenstern-Badarau, and O. Kahn
pp 3833 - 3835; DOI:
10.1021/ic00191a034
PDF
Germanium-73 chemical shifts and spin-lattice relaxation times of some tetrasubstituted germanes
Yoshito Takeuchi, Toshie Harazono, and Norihiro Kakimoto
pp 3835 - 3836; DOI:
10.1021/ic00191a035
PDF
Piezochromism of nickel(II) complexes with tetraaza macrocyclic ligands in water
Yoichi Kitamura, Tasuku Ito, and Masako Kato
pp 3836 - 3838; DOI:
10.1021/ic00191a036
PDF

Issue 24


Ambient-pressure superconductivity at 2.7 K and higher temperatures in derivatives of (BEDT-TTF)2IBr2: synthesis, structure, and detection of superconductivity
Jack M. Williams, Hau H. Wang, Mark A. Beno, Thomas J. Emge, L. M. Sowa, P. T. Copps, F. Behroozi, L. N. Hall, K. Douglas Carlson, and G. W. Crabtree
pp 3839 - 3841; DOI:
10.1021/ic00192a001
PDF
Temperature dependence of the quantum yields for the photoanation of Ru(bpy)2L22+ complexes
David V. Pinnick and Bill Durham
pp 3841 - 3842; DOI:
10.1021/ic00192a002
PDF
Layered compounds with alternating organic and inorganic layers: vanadyl organophosphonates
Jack W. Johnson, A. J. Jacobson, J. F. Brody, and J. T. Lewandowski
pp 3842 - 3844; DOI:
10.1021/ic00192a003
PDF
Models of oxidized heme proteins. Preparation and characterization of a trans-dioxoruthenium(VI) porphyrin complex
John T. Groves and Robert Quinn
pp 3844 - 3846; DOI:
10.1021/ic00192a004
PDF
Redirected ligand-field analysis. 1. Ligand fields of coordination voids and "semicoordination" in copper(II) complexes
Robert J. Deeth and Malcolm Gerloch
pp 3846 - 3853; DOI:
10.1021/ic00192a005
PDF
Redirected ligand-field analysis. 2. Asymmetric chelation in trigonal-bipyramidal copper(II) complexes
Robert J. Deeth and Malcolm Gerloch
pp 3853 - 3861; DOI:
10.1021/ic00192a006
PDF
Dynamics of spin-state interconversion and cooperativity for ferric spin-crossover complexes in the solid state. 1. The unperturbed fast spin-flipping N4O2 complex [Fe(SalAPA)2]ClO4
Wayne D. Federer and David N. Hendrickson
pp 3861 - 3870; DOI:
10.1021/ic00192a007
PDF
Dynamics of spin-state interconversion and cooperativity for ferric spin-crossover complexes in the solid state. 2. Perturbations of the fast spin-flipping N4O2 complex [Fe(SalAPA)2]ClO4
Wayne D. Federer and David N. Hendrickson
pp 3870 - 3877; DOI:
10.1021/ic00192a008
PDF
An electronic structural model for the emitting MLCT excited states of Ru(bpy)32+ and Os(bpy)32+
Edward M. Kober and Thomas J. Meyer
pp 3877 - 3886; DOI:
10.1021/ic00192a009
PDF
EPR, magnetic and structural investigations on the weak-exchange Heisenberg linear chain bis(N-methylphenazinium) bis(dicyanoethenedithiolato)cuprate(II), [(NMP)2][Cu(mnt)2]
P. Kuppusamy, B. L. Ramakrishna, and P. T. Manoharan
pp 3886 - 3892; DOI:
10.1021/ic00192a010
PDF
Infrared matrix isolation study of intermediate molecular complexes: complexes of tetrafluorogermane with oxygen-containing bases
Angela M. Walther and Bruce S. Ault
pp 3892 - 3897; DOI:
10.1021/ic00192a011
PDF
Resonance Raman spectra of high oxidation state iron porphyrin dimers
M. A. Crisanti, T. G. Spiro, Daniel R. English, David N. Hendrickson, and Kenneth S. Suslick
pp 3897 - 3901; DOI:
10.1021/ic00192a012
PDF
Solvent effects in the complexation of dibenzo-14-crown-4 and its analogs with lithium ion
Chi S. Chen, Shieh J. Wang, and Shaw C. Wu
pp 3901 - 3903; DOI:
10.1021/ic00192a013
PDF
Ruthenium(II) complexes of modified 1,10-phenanthrolines. 1. Synthesis and properties of complexes containing dipyridophenazines and a dicyanomethylene-substituted 1,10-phenanthroline
Martin N. Ackermann and Leonard V. Interrante
pp 3904 - 3911; DOI:
10.1021/ic00192a014
PDF
Interaction of complexes of composition MnLX2 (L = tertiary phosphine) with dioxygen
V. F. Newberry, H. D. Burkett, S. D. Worley, and W. E. Hill
pp 3911 - 3917; DOI:
10.1021/ic00192a015
PDF
Ring-size effects on the formation of dicopper(II) and dicopper(III) complexes with bimacrocycles, 13- and 14-membered tetraaza subunits
Armando Buttafava, Luigi Fabbrizzi, Angelo Perotti, Antonio Poggi, and Barbara Seghi
pp 3917 - 3922; DOI:
10.1021/ic00192a016
PDF
Aquation of chloropentaammine and chloropentakis(methylamine) complexes of cobalt(III) and chromium(III): comparative activation volumes and mechanistic implications
Geoffrey A. Lawrance, Karen Schneider, and Rudi Van Eldik
pp 3922 - 3925; DOI:
10.1021/ic00192a017
PDF
Carbonate complexation of dioxoneptunium(VI) at 25.degree.C: its effect on the neptunium(V)/neptunium(VI) potential
Leon Maya
pp 3926 - 3930; DOI:
10.1021/ic00192a018
PDF
Ascending water electrode studies of metal extractants. Role of kinetic factors in the Faradaic ion transfer of metal-phenanthroline complex ions across an aqueous-organic solvent interface
Z. Yoshida and Henry Freiser
pp 3931 - 3935; DOI:
10.1021/ic00192a019
PDF
Electrochemical behavior of Ru(trpy)(bpy)(OH2)3+ in aqueous solution and when incorporated in Nafion coatings
Ron C. McHatton and Fred C. Anson
pp 3935 - 3942; DOI:
10.1021/ic00192a020
PDF
Electrochemistry of the .mu.-carbido iron tetraphenylporphyrin dimer, ((TPP)Fe)2C, in nonaqueous media. Evidence for axial ligation by pyridine
D. Lancon and K. M. Kadish
pp 3942 - 3947; DOI:
10.1021/ic00192a021
PDF
Electrochemistry of oxo- and peroxotitanium(IV) porphyrins. Mechanism of the two-electron reduction of a .eta.2-coordinated peroxo ligand.
Tadeusz Malinski, Dane Chang, Jean Marc Latour, Jean Claude Marchon, Maurice Gross, Alain Giraudeau, and Karl M. Kadish
pp 3947 - 3955; DOI:
10.1021/ic00192a022
PDF
Redox and spectral properties of nickel(II) macrocycles containing dianionic, tetraazaannulene ligands
Cynthia L. Bailey, Robert D. Bereman, D. Paul Rillema, and Robert Nowak
pp 3956 - 3960; DOI:
10.1021/ic00192a023
PDF
Mechanism of electrochemical reduction of the (5,10,15,20-tetraphenylporphinato)dihydroxophosphorus(V)cation
Carl A. Marrese and Carl J. Carrano
pp 3961 - 3968; DOI:
10.1021/ic00192a024
PDF
Synthesis, spectra and structure of af-dibromo-b-ethoxo-d-oxo-ce-bis(4-nitropyridine)technetium(V) and related complexes
P. H. Fackler, M. E. Kastner, and M. J. Clarke
pp 3968 - 3972; DOI:
10.1021/ic00192a025
PDF
Kinetic and mechanistic study of the succinic anhydride reductive elimination reaction from the six-coordinate hydridoalkyliridium(III) complex
M. Basato, B. Longato, F. Morandini, and S. Bresadola
pp 3972 - 3976; DOI:
10.1021/ic00192a026
PDF
Kinetics and mechanism of the oxidation of bis(.mu.-hydroxo)bis[aqua(1,4,7-triazacyclononane)molybdenum(III)](4+) by perchlorate. Acid-base-catalyzed trans .fwdarw. cis isomerization of bis(.mu.-oxo)-trans-dioxobis[(1,4,7-triazacyclononane)molybdenum(V)](2+)
Manfred Hahn and Karl Wieghardt
pp 3977 - 3982; DOI:
10.1021/ic00192a027
PDF
Kinetics and mechanism of the chloride-assisted oxidative dealkylation of alkylcobalamins by iron(III) ions
Yueh Tai Fanchiang
pp 3983 - 3986; DOI:
10.1021/ic00192a028
PDF
Kinetics of dealkylation reactions of N-alkylporphyrin complexes. 4. Effect of N-alkyl and N-aryl substituents on the dealkylation process
David K. Lavallee and Debasish Kuila
pp 3987 - 3992; DOI:
10.1021/ic00192a029
PDF
Metal atom synthesis of metalla boron clusters. 5. Synthesis of the first (.eta.6-arene)metallaborane and (.eta.6-arene)metallaoxaborane clusters. Structural characterizations of 5-[.eta.6-C6(CH3)3H3]FeB9H13 and 2-[.eta.6-C6(CH3)3H3]Fe-6-OB8H10
Robert P. Micciche, James J. Briguglio, and Larry G. Sneddon
pp 3992 - 3999; DOI:
10.1021/ic00192a030
PDF
Random-exchange-coupled chain in the amorphous complex (ethylenediaminetetraacetato)dicobalt hexahydrate (Co2(EDTA).6H2O): comparison with the crystallized complex
E. Coronado, M. Drillon, D. Beltran, and J. C. Bernier
pp 4000 - 4004; DOI:
10.1021/ic00192a031
PDF
Studies on copper(II) complexes of o-quinone monooximes. Adducts of bis(4-chloro-1-benzoquinone 2-oximato)copper(II) with some heterocyclic bases. Structure of the 2,2'-bipyridine adduct
Carla Bisi Castellani, Giuseppina Gatti, and Roberto Millini
pp 4004 - 4008; DOI:
10.1021/ic00192a032
PDF
Molecular stereochemistry of low-spin five-coordinate phenyl(meso-tetraphenylporphyrinato)iron(III)
Pascal Doppelt
pp 4009 - 4011; DOI:
10.1021/ic00192a033
PDF
Pentahydridorhenium: crystal and molecular structure of ReH5(PMePh2)3
Thomas J. Emge, Thomas F. Koetzle, Joseph W. Bruno, and Kenneth G. Caulton
pp 4012 - 4017; DOI:
10.1021/ic00192a034
PDF
Equilibrium constants for dimerization of several paramagnetic iron thiolate complexes with the formula [Fe(SPh)(L)(L')(.eta.-C5H5)]+
Paul M. Treichel and Laurence D. Rosenhein
pp 4018 - 4022; DOI:
10.1021/ic00192a035
PDF
Cleavage of the rhenium-methyl bond of (.eta.-C5H5)Re(NO)(PPh3)(CH3) by protic and halogen electrophiles: stereochemistry at rhenium
James H. Merrifield, Jesus M. Fernandez, William E. Buhro, and J. A. Gladysz
pp 4022 - 4029; DOI:
10.1021/ic00192a036
PDF
Synthesis and molecular structure of Ru2(C5NH4NH)6(PMe2Ph)2, a ruthenium-ruthenium-bonded molecule with 2-pyridinylamide ligands in three coordination modes and other novel features
Akhil R. Chakravarty, F. Albert Cotton, and Derek A. Tocher
pp 4030 - 4033; DOI:
10.1021/ic00192a037
PDF
New preparative methods, structure, and nitration of bi-oxo-capped trimolybdenum(IV) and tritungsten(IV) cluster cations
F. Albert Cotton, Zvi Dori, David O. Marler, and Willi Schwotzer
pp 4033 - 4038; DOI:
10.1021/ic00192a038
PDF
Comparative study of structures, including Jahn-Teller effects, in the saccharinate complexes, [M(C7H4NO3S)2(H2O)4].2H2O, of chromium and zinc, as well as other divalent metal ions
F. Albert Cotton, Gregg E. Lewis, Carlos A. Murillo, Willi Schwotzer, and Grettel Valle
pp 4038 - 4041; DOI:
10.1021/ic00192a039
PDF
An octanuclear basic benzoate containing four vanadium(III) and four zinc(II) atoms: [VZnO(O2CC6H5)3(THF)]4.2THF
F. Albert Cotton, Stan A. Duraj, and Wieslaw J. Roth
pp 4042 - 4045; DOI:
10.1021/ic00192a040
PDF
Preparation, structure, and properties of the polar dirhodium(II) tetrakis(6-fluoro-2-oxypyridinate) molecule
F. Albert Cotton, Scott Han, and Wenning Wang
pp 4046 - 4050; DOI:
10.1021/ic00192a041
PDF
Pyrazolyl-bridged iridium dimers. 4. Two-fragment, two-center oxidative addition of halogens and methyl halides to trans-bis(triphenylphosphine)dicarbonylbis(.mu.-pyrazolyl)diiridium(I)
Jerry L. Atwood, Kathy A. Beveridge, Gordon W. Bushnell, Keith R. Dixon, Donald T. Eadie, Stephen R. Stobart, and Michael J. Zaworotko
pp 4050 - 4057; DOI:
10.1021/ic00192a042
PDF
Synthesis and spectroscopic studies of metal-metal-bonded linear heterotrimetallic gold(I) complexes. Crystal structure of [n-Bu4N][Au[Cr(CO)3-.eta.-C5H5]2]
Pierre Braunstein, Ulrich Schubert, and Michel Burgard
pp 4057 - 4064; DOI:
10.1021/ic00192a043
PDF
Platinum(II) complexes of unsymmetrical, potentially bidentate ligands
Gordon K. Anderson and Ravi Kumar
pp 4064 - 4068; DOI:
10.1021/ic00192a044
PDF
Ligand substitution reactions of a dinuclear platinum(I) complex
Makoto Shimura and James H. Espenson
pp 4069 - 4071; DOI:
10.1021/ic00192a045
PDF
Equilibria, spectra, and photochemistry of copper(I)-ammonia complexes in aqueous solution
T. F. Braish, R. E. Duncan, J. J. Harber, R. L. Steffen, and K. L. Stevenson
pp 4072 - 4075; DOI:
10.1021/ic00192a046
PDF
Geometries and energies of complexes between formaldehyde and first-and second-row cations. A theoretical study
Douglas J. Raber, Nancy K. Raber, Jayaraman Chandrasekhar, and Paul von Rague Schleyer
pp 4076 - 4080; DOI:
10.1021/ic00192a047
PDF
X-ray photoelectron spectroscopic study of sulfur-nitrogen-fluorine compounds
David B. Beach, William L. Jolly, Ruediger Mews, and Alfred Waterfeld
pp 4080 - 4084; DOI:
10.1021/ic00192a048
PDF
Metal-nitroxyl interactions. 41. Comparison of electron-electron spin-spin interactions in spin-labeled silver porphyrins in fluid solution, in frozen solution, and on imbiber beads
Kundalika M. More, Gareth R. Eaton, and Sandra S. Eaton
pp 4084 - 4087; DOI:
10.1021/ic00192a049
PDF
Electrochemical studies of sulfur-nitrogen compounds. 3. S3N3O-, S3N3O2-, and S4N5O- ions and S4N4O2, S3N2O, Ph2CNSNSO, and S(NSO)2
T. Chivers and M. Hojo
pp 4088 - 4093; DOI:
10.1021/ic00192a050
PDF
Mass spectrometric investigation of silver ion promoted carbon-carbon bond scission
K. L. Busch, R. G. Cooks, R. A. Walton, and K. V. Wood
pp 4093 - 4097; DOI:
10.1021/ic00192a051
PDF
The molybdenum-molybdenum triple bond. 15. Compounds with chains of metal atoms having M-M single and triple bonds: M2(M'(M'Me3)3)2(NMe2)4 (M.tplbond.M) where M = Mo and W and M' = Si and Sn
Malcolm H. Chisholm, Hsin Tien Chiu, Kirsten Folting, and John C. Huffman
pp 4097 - 4102; DOI:
10.1021/ic00192a052
PDF
X-ray and neutron diffraction single-crystal studies of tris(phenyldiisopropylphosphine)tungsten hexahydride [WH6(PPh-i-Pr2)3]
David Gregson, Sax A. Mason, Judith A. K. Howard, John L. Spencer, and David G. Turner
pp 4103 - 4107; DOI:
10.1021/ic00192a053
PDF
Reactions of matrix-isolated iron atoms with dinitrogen
Marca M. Doeff, Stewart F. Parker, Paul H. Barrett, and Ralph G. Pearson
pp 4108 - 4110; DOI:
10.1021/ic00192a054
PDF
Chiral metal complexes. 17. Cocrystallization of four diastereoisomers: a second example
Paul Jones, Robert S. Vagg, and Peter A. Williams
pp 4110 - 4111; DOI:
10.1021/ic00192a055
PDF
Preparation and characterization of trans-diiodotetra-tert-butoxytungsten(VI): the first structurally well-characterized WVI-I bonds
F. Albert Cotton, Willi Schwotzer, and Edwar S. Shamshoum
pp 4111 - 4113; DOI:
10.1021/ic00192a056
PDF
A novel dinuclear vanadium(II) compound with bridging chlorine atoms, bridging diphosphinomethane ligands, and bidentate tetrahydroborate ligands
F. Albert Cotton, Stan A. Duraj, and Wieslaw J. Roth
pp 4113 - 4115; DOI:
10.1021/ic00192a057
PDF
Steric factors controlling the formation of allenyl- vs. propargyl cobaloxime complexes
Daniel J. Pasto and Debra A. Timmers
pp 4115 - 4116; DOI:
10.1021/ic00192a058
PDF
Sodium borohydride reduction of cobaloxime complexes. An electron-transfer, free-radical process
Daniel J. Pasto, Debra A. Timmers, and Nai Zhong Huang
pp 4117 - 4119; DOI:
10.1021/ic00192a059
PDF
Mechanism of oxidation of mandelic acid by Fenton's reagent
Surendra N. Mahapatro, Akhil K. Panigrahi, Radhasyam Panda, and Damburu M. Patro
pp 4119 - 4120; DOI:
10.1021/ic00192a060
PDF

Issue 25


Oxygenation of organic substrates by iodosylbenzene catalyzed by soluble manganese, iron, cobalt, or copper salts in acetonitrile
Reuel B. VanAtta, Catherine C. Franklin, and Joan Selverstone Valentine
pp 4121 - 4123; DOI:
10.1021/ic00193a001
PDF
Proton transfer in the excited state of carboxylic acid derivatives of tris(2,2'-bipyridine-N,N')ruthenium(II)
Peter A. Lay and Wolfgang H. F. Sasse
pp 4123 - 4125; DOI:
10.1021/ic00193a002
PDF
Factors affecting the metal-promoted head-to-head dimerization of carbon disulfide, CS2 to C2S4. Synthesis, chemistry, structure, and MO analysis of [(triphos)Rh(.mu.-C2S4)Rh(triphos)](BPh4)2.CH2Cl2
Claudio Bianchini, Carlo Mealli, Andrea Meli, and Michal Sabat
pp 4125 - 4127; DOI:
10.1021/ic00193a003
PDF
A novel isomer of s-cis-[Co(edda-type)(L)] (edda = ethylenediamine-N,N'-diacetate; and L = one bidentate or two unidentate ligands) containing equatorially-oriented N-CH2 bonds of the acetate arms. Crystal structure of [s-cis-(N,N'-dimethyl-(1R,2R)-1,2-cyclohexanediamine-N,N'-diacetato](ethylenediamine)cobalt(III) perchlorate, s-cis-[Co(N,N'-Me2-R,R-chxnda)(en)]ClO4
Shigenobu Yano, Takashi Murata, Masatsugu Asami, Michiro Inoue, Morio Yashiro, Masao Kosaka, and Sadao Yoshikawa
pp 4127 - 4128; DOI:
10.1021/ic00193a004
PDF
Cofacial binuclear copper complexes of a bis(.beta.-diketone) ligand
Andrew W. Maverick and Floyd E. Klavetter
pp 4129 - 4130; DOI:
10.1021/ic00193a005
PDF
Synthesis of novel organo(silyl)phosphine synthons and their conversion to new organophosphines
David M. Schubert and Arlan D. Norman
pp 4130 - 4131; DOI:
10.1021/ic00193a006
PDF
Structural nomenclature for polyboron hydrides and related compounds. 3. Linear conjuncto structures
James B. Casey, William J. Evans, and Warren H. Powell
pp 4132 - 4143; DOI:
10.1021/ic00193a007
PDF
Preparation of tertiary phosphine complexes of tetravalent and trivalent uranium methyltrihydroborates. Crystal structures of tetrakis(methyltrihydroborato)(1,2-bis(dimethylphosphino)ethane)uranium(IV) and tris(methyltrihydroborato)bis(1,2-bis(dimethylphosphino)ethane)uranium(III)
John Brennan, Ron Shinomoto, Allan Zalkin, and Norman Edelstein
pp 4143 - 4146; DOI:
10.1021/ic00193a008
PDF
Preparation and characterization of salts containing cations of tricoordinate boron
Chaitanya K. Narula and Heinrich Noeth
pp 4147 - 4152; DOI:
10.1021/ic00193a009
PDF
Synthesis and characterization of copper(II), nickel(II) and cobalt(III) complexes with 1,4,8,11-tetraazacyclohexadecane and 1,4,8,11-tetraazacyclopheptadecane
Ramesh Bembi, Virendra K. Bhardwarj, Randhir Singh, Kapil Taneja, and Shabana Aftab
pp 4153 - 4157; DOI:
10.1021/ic00193a010
PDF
Transition-metal eight-coordination. 17. Synthesis and characterization of homo- and heteroligand tetrakis molybdenum(IV) chelates
Ronald D. Archer and Carl J. Weber
pp 4158 - 4162; DOI:
10.1021/ic00193a011
PDF
Substitution reactions of five-coordinate complexes. 1. Formation and aquation kinetics of the (acido)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) (blue) cation
Chung Shin Lee and Chung Sun Chung
pp 4162 - 4166; DOI:
10.1021/ic00193a012
PDF
Electron-transfer reactions of tris(picolinato)vanadate(II), a LOMI reagent
A. Martin Lannon, A. Graham Lappin, and Michael G. Segal
pp 4167 - 4170; DOI:
10.1021/ic00193a013
PDF
Oligo(phosphine) ligands. 7. Free-radical-catalyzed synthesis of some completely alkylated oligo(tertiary phosphines) containing trimethylene linkages
Martin Antberg, Constanze Prengel, and Lutz Dahlenburg
pp 4170 - 4174; DOI:
10.1021/ic00193a014
PDF
Free-radical decomposition of trifluoramine oxide with nitric oxide: a facile in situ source of nitrosyl fluoride
Scott A. Kinkead and Jeanne M. Shreeve
pp 4174 - 4177; DOI:
10.1021/ic00193a015
PDF
The effect of X- = Cl-, Br-, I- on the kinetics of the Arbuzov rearrangement involving [CpCo(dppe)X]+ and P(OR)3(R = Me, Et)
Shayne J. Landon and Thomas B. Brill
pp 4177 - 4181; DOI:
10.1021/ic00193a016
PDF
Effects of imide anions and axial donors on the stability and oxidation behavior of square-planar 13-15-membered macrocyclic tetraamine complexes of nickel(II) and copper(II)
Eiichi Kimura, Tohru Koike, Ryosuke Machida, Rieko Nagai, and Mutsuo Kodama
pp 4181 - 4188; DOI:
10.1021/ic00193a017
PDF
Zinc ion in Escherichia coli DNA polymerase: a reinvestigation
Daniel R. Graham and David S. Sigman
pp 4188 - 4191; DOI:
10.1021/ic00193a018
PDF
Effects of phenoxide ligation on iron-sulfur clusters. 2. Preparation and properties of [Fe2S2(OAr)4]2- ions
W. E. Cleland and Bruce A. Averill
pp 4192 - 4197; DOI:
10.1021/ic00193a019
PDF
On the trail of dichlorodinitrosyltungsten: a tale of two reactions
Allen D. Hunter and Peter Legzdins
pp 4198 - 4204; DOI:
10.1021/ic00193a020
PDF
Stereochemical studies in the development of technetium radiopharmaceuticals. 1. Fluxional racemization of technetium and rhenium penicillamine complexes
Dennis Lee Johnson, Alan R. Fritzberg, Bruce L. Hawkins, Sudhakar Kasina, and Dennis Eshima
pp 4204 - 4207; DOI:
10.1021/ic00193a021
PDF
Molecular A-frames. Identification and characterization of the rhodium A-frame precursor complex bis(.mu.-hydrido)dicarbonylbis(bis(diphenylphosphino)methane)dirhodium, Rh2(.mu.-H)2(CO)2(dppm)2
Carrie Woodcock and Richard Eisenberg
pp 4207 - 4211; DOI:
10.1021/ic00193a022
PDF
Dinuclear uranium alkoxides. Preparation and structures of KU2(OCMe3)9, U2(OCMe3)9, and U2(OCHMe2)10, containing [uranium(IV), uranium(IV)], [uranium(IV), uranium(V)], and [uranium(V), uranium(V)], respectively
F. Albert Cotton, David O. Marler, and Willi Schwotzer
pp 4211 - 4215; DOI:
10.1021/ic00193a023
PDF
2-Anilinopyridine complexes of dimolybdenum(II) and ditungsten(II)
Akhil R. Chakravarty, F. Albert Cotton, and Edwar S. Shamshoum
pp 4216 - 4221; DOI:
10.1021/ic00193a024
PDF
Correlation of molybdenum-molybdenum quadruple bond length with angle of internal rotation, using data for 10 compounds
Fred L. Campbell, F. Albert Cotton, and Gregory L. Powell
pp 4222 - 4226; DOI:
10.1021/ic00193a025
PDF
Synthesis and characterization of an iron carbonyl cluster containing bismuth: crystal and molecular structure of tetraethylammonium (.mu.3-bismuthido)nonacarbonyl(.mu.3-carbonyl)-triangulo-triferrate(1-), [Et4N][(.mu.3-Bi)Fe3(CO)9(.mu.3-CO)], a closo cluster of the first transition series with a large heteroatom
Kenton H. Whitmire, Craig B. Lagrone, Melvyn Rowen Churchill, James C. Fettinger, and Linda Vollaro Biondi
pp 4227 - 4232; DOI:
10.1021/ic00193a026
PDF
Discrete trigonal-pyramidal lead(II) complexes: syntheses and x-ray structure analyses of [(C6H5)4As][Pb(EC6H5)3] (E = S, Se)
Philip A. W. Dean, Jagadese J. Vittal, and Nicholas C. Payne
pp 4232 - 4236; DOI:
10.1021/ic00193a027
PDF
Optically active cis-dianiono(tetraamine)chromium(III) complexes. 5. The absolute configuration of (-)-cis-(RRRR)-[CrCl2(cyclam)]ClO4
Donald A. House and Vickie McKee
pp 4237 - 4242; DOI:
10.1021/ic00193a028
PDF
X-ray crystal and molecular structures of related octahedral magnesium tetraphenylporphyrin complexes
V. McKee, Ong Chin Choon, and G. A. Rodley
pp 4242 - 4248; DOI:
10.1021/ic00193a029
PDF
cis-Bis(2-phenylpyridine)platinum(II) (CBPPP): a simple molecular platinum compound
Laurent Chassot, Edgar Mueller, and Alexander Von Zelewsky
pp 4249 - 4253; DOI:
10.1021/ic00193a030
PDF
New cationic rhodium(I)-iridium(III) complexes with bridging hydride and chloride ligands. Synthesis and x-ray crystal structure of [(diphos)Rh(.mu.-H)(.mu.-Cl)IrCl(PEt3)3]BF4 and [(diphos)Rh(.mu.-H)(.mu.-Cl)IrH(PEt3)3]BF4
Hans Lehner, Dominique Matt, Antonio Togni, Rene Thouvenot, Luigi M. Venanzi, and Alberto Albinati
pp 4254 - 4261; DOI:
10.1021/ic00193a031
PDF
Preparation and structure of a new kind of an extended partially oxidized linear-chain compound: catena-(.mu.-bromo)bis((1R,2R)-cyclohexanediamine)nickel(2.77) bromide
Hans Toftlund and Ole Simonsen
pp 4261 - 4265; DOI:
10.1021/ic00193a032
PDF
Reactions of tetrathiometalates, MS42-(M = Mo, W). Syntheses and properties of M2S42+-containing compounds. Structure of bis(tetraphenylphosphonium) bis(.mu.-sulfido)bis[sulfido(1,2-ethanedithiolato)tungstate(V)], [P(C6H5)4]2[W2S4(S2C2H4)2]
Wie Hin Pan, Travis Chandler, John H. Enemark, and Edward I. Stiefel
pp 4265 - 4269; DOI:
10.1021/ic00193a033
PDF
Proton and INEPT nitrogen-15 and silver-109 NMR studies of the structural and dynamic features in solution of some silver(I) and copper(I) complexes with polydentate N4-donor ligands, (RS)-1,2-(6-R-py-2-CH:N)2Cy and 1,2-(6-R-py-2-CH:N)2ethane (Cy = cyclohexane, R = H or Me)
Gerard C. Van Stein, Gerard Van Koten, Kees Vrieze, and Christian Brevard
pp 4269 - 4278; DOI:
10.1021/ic00193a034
PDF
Structural characterization of a terbium(III) complex with 1,4,8,11-tetraazacyclotetradecane-1,4,8,11-tetraacetic acid. Lanthanide ions and the conformation of the 14-membered macrocycles
Marie Rose Spirlet, Jean Rebizant, Marie France Loncin, and Jean F. Desreux
pp 4278 - 4283; DOI:
10.1021/ic00193a035
PDF
Gas-phase structure of azidotrifluoromethane. Electron diffraction, microwave spectroscopy, and normal-coordinate analysis
Karl O. Christe, Dines Christen, Heinz Oberhammer, and Carl J. Schack
pp 4283 - 4288; DOI:
10.1021/ic00193a036
PDF
Rhodium(I) carbonyl complexes of (diphenylphosphino)acetic acid
A. Jegorov, B. Kratochvil, V. Langer, and J. Podlahova
pp 4288 - 4291; DOI:
10.1021/ic00193a037
PDF
Crystal structures and magnetic properties of (.mu.-terephthalato)bis[(N,N,N',N",N"-pentamethyldiethylenetriamine)aquocopper(II)] perchlorate and (.mu.-terephthalato)bis[(N,N,N',N",N"-pentaethyldiethylenetriamine)copper(II)] perchlorate
Michel Verdaguer, Jacqueline Gouteron, Suzanne Jeannin, Yves Jeannin, and Olivier Kahn
pp 4291 - 4296; DOI:
10.1021/ic00193a038
PDF
Crystal and molecular structure of sodium pentacyanonitrosylruthenate(II) dihydrate and its spectroscopic properties and reactivity
Jose A. Olabe, Luis A. Gentil, Graciela Rigotti, and Alda Navaza
pp 4297 - 4302; DOI:
10.1021/ic00193a039
PDF
Syntheses and molecular structures of related six- and eight-coordinate complexes: tetrachloro(2,2'-bi-2-thiazine)zirconium(IV), tetrachlorobis(2,2'-bi-2-thiazoline)zirconium(IV), and bis(2,2'-bi-2-thiazoline)tetrakis(isothiocyanato)zirconium(IV)
R. A. Johnson, R. B. Von Dreele, and T. M. Brown
pp 4302 - 4309; DOI:
10.1021/ic00193a040
PDF
2,6-Bis(diphenylphosphino)pyridine as a bridging ligand in planar complexes of platinum(II) and palladium(II)
Fred E. Wood, Jan Hvoslef, Haakon Hope, and Alan L. Balch
pp 4309 - 4315; DOI:
10.1021/ic00193a041
PDF
Ligand substitution in molybdenum(0) carbonyl complexes Mo(CO)5(amine) and cis-Mo(CO)4(amine)2: kinetics and high-pressure effects
Hans Tobias Macholdt and Horst Elias
pp 4315 - 4321; DOI:
10.1021/ic00193a042
PDF
Boron analogs of amino acids. 4. Synthesis of glycine and N-methylated glycine ester analogs
Bernard F. Spielvogel, Fahim U. Ahmed, Gary L. Silvey, Patty Wisian-Neilson, and Andrew T. McPhail
pp 4322 - 4324; DOI:
10.1021/ic00193a043
PDF
Cofacial assembly of partially oxidized metallomacrocycles as an approach to controlling lattice architecture in low-dimensional molecular solids. Synthesis and properties of cofacially joined silicon and germanium hemiporphyrazine polymers
Carl W. Dirk and Tobin J. Marks
pp 4325 - 4332; DOI:
10.1021/ic00193a044
PDF
Kinetics of reduction of ferrichrome and ferrichrome A by chromium(II), europium(II), vanadium(II), and dithionite
S. Arif Kazmi, A. Lee Shorter, and James V. McArdle
pp 4332 - 4341; DOI:
10.1021/ic00193a045
PDF
High-pressure stopped-flow study of complex formation on nickel(II) ion in dimethylformamide. Possible existence of a 5-coordinate intermediate
Peter J. Nichols, Yolande Fresard, Yves Ducommun, and Andre E. Merbach
pp 4341 - 4345; DOI:
10.1021/ic00193a046
PDF
Solvent and structure effects on the spin-crossover and electron-transfer properties of [FeIII(X-Salmeen)2](PF6) and [FeIII(X-Sal)2trien](PF6)
Tianpei Zhu, Chih Ho Su, Dwight Schaeper, B. Kaye Lemke, Lon J. Wilson, and Karl M. Kadish
pp 4345 - 4349; DOI:
10.1021/ic00193a047
PDF
Proton and carbon-13 NMR study of the effects of meso substituents on the S = 3/2, 5/2 spin state admixture of (perchlorato)(tetraarylporphinato)iron(III) complexes
Glen E. Toney, Avram Gold, Johanthan Savrin, Leonard W. Ter Haar, R. Sangaiah, and William E. Hatfield
pp 4350 - 4352; DOI:
10.1021/ic00193a048
PDF
Infrared study of ambient-temperature chloroaluminates as a function of melt acidity
Stephen Tait and R. A. Osteryoung
pp 4352 - 4360; DOI:
10.1021/ic00193a049
PDF
Ligand additivity in the valence photoelectron spectroscopy of phosphine-substituted molybdenum carbonyls
Bruce E. Bursten, Donald J. Darensbourg, Glen E. Kellogg, and Dennis L. Lichtenberger
pp 4361 - 4365; DOI:
10.1021/ic00193a050
PDF
Gas-phase reactions. 44. The phosphorus P4 .dblarw. 2P2 equilibrium visualized
H. Bock and H. Mueller
pp 4365 - 4368; DOI:
10.1021/ic00193a051
PDF
Electrochemistry of macrobicyclic mixed nitrogen-sulfur donor complexes of cobalt(III)
Lawrence R. Gahan, Geoffrey A. Lawrance, and Alan M. Sargeson
pp 4369 - 4376; DOI:
10.1021/ic00193a052
PDF
On the nonobservability of cubic phosphorus P8
E. Amitai Halevi, Hans Bock, and Bernhard Roth
pp 4376 - 4378; DOI:
10.1021/ic00193a053
PDF
EPR of copper(II) complexes with tripodal ligands: dynamical properties
G. Kokoszka, K. D. Karlin, F. Padula, J. Baranowski, and C. Goldstein
pp 4378 - 4380; DOI:
10.1021/ic00193a054
PDF
Mixed-ligand iron(II) complexes containing 2,2'-bipyrimidine. Spectroscopic, electrochemical, and coulombic modification of highly absorbing metal complexes by ligand substitution
Ronald R. Ruminski, Kurt D. Van Tassel, and John D. Petersen
pp 4380 - 4382; DOI:
10.1021/ic00193a055
PDF
Ligand substitution processes in tetranuclear carbonyl clusters. 8. Reactions of dodecacarbonyltetracobalt (Co4(12CO)12/Co4(13CO)12) with phosphorus donor ligands. Further evidence for cluster integrity during ligand substitution processes
Donald J. Darensbourg and David J. Zalewski
pp 4382 - 4384; DOI:
10.1021/ic00193a056
PDF
Direct identification of copper-molybdenum-sulfur clusters by molybdenum-95 NMR spectroscopy
Martin Minelli, John H. Enemark, John R. Nicholson, and C. David Garner
pp 4384 - 4386; DOI:
10.1021/ic00193a057
PDF
A dimeric platinum(III) system containing a long metal-metal bond. Crystal structure of K4[Pt2(P2O5H2)4CH3I].2H2O
Chi Ming Che, Thomas C. W. Mak, and Harry B. Gray
pp 4386 - 4388; DOI:
10.1021/ic00193a058
PDF
Copper-63 NMR studies of copper(I) complexes. Relationship between copper-63 chemical shift and metal-ligand binding
Susumu Kitagawa and Megumu Munakata
pp 4388 - 4390; DOI:
10.1021/ic00193a059
PDF
Detailed correlations between the ligand-to-metal charge-transfer (LMCT) spectra of copper(II) and ruthenium(III) imidazoles and imidazolates. Electronic structures of carbon-bound ruthenium(III) imidazoles and imidazolates
Karsten Krogh-Jespersen and Harvey J. Schugar
pp 4390 - 4393; DOI:
10.1021/ic00193a060
PDF
The acid decomposition of tris(dimethylglyoximato)nickelate(IV) in the presence of nucleophiles. Evidence for substitution inertness of the nickel(IV) complex
S. Acharya and R. K. Panda
pp 4393 - 4394; DOI:
10.1021/ic00193a061
PDF
Formation and structure of an unusual complex from the reaction of formaldehyde with alkali halide salt molecules in argon matrixes
Stephen B. H. Bach and Bruce S. Ault
pp 4394 - 4396; DOI:
10.1021/ic00193a062
PDF
Infrared study of sulfur-containing iron oxide. Behavior of sulfur during reduction and oxidation
Tuo Jin, Motoi Machida, Tsutomu Yamaguchi, and Kozo Tanabe
pp 4396 - 4398; DOI:
10.1021/ic00193a063
PDF
N-Acyl isocyanide complexes of iron(II) porphyrins. Access to mixed-ligand species using a substitute for carbon monoxide
M. Le Plouzennec, A. Bondon, and G. Simonneaux
pp 4398 - 4399; DOI:
10.1021/ic00193a064
PDF
Kinetics and mechanism of the reactions of sulfito complexes in aqueous solution. 6. Formation, aquation, and intramolecular electron transfer of the cis-aquo(sulfito-O)bis(ethylenediamine)cobalt(III) ion
T. P. Dasgupta and G. M. Harris
pp 4399 - 4402; DOI:
10.1021/ic00193a065
PDF

Issue 26


A pentafluorosulfur .beta.-sultone and some derivatives
JoAnn M. Canich, Maria M. Ludvig, Gary L. Gard, and Jeanne M. Shreeve
pp 4403 - 4407; DOI:
10.1021/ic00194a001
PDF
Synthesis, structure, and electronic features of (.mu.-sulfido)bis[(N,N'-ethylenebis(salicylaldiminato))iron(III)], [Fe(salen)]2S, containing the only authenticated example of the iron(III)-sulfur-iron(III) single bridge
J. R. Dorfman, J. J. Girerd, E. D. Simhon, T. D. P. Stack, and Richard H. Holm
pp 4407 - 4412; DOI:
10.1021/ic00194a002
PDF
Linear polysiloxanes from dichlorosilane
Dietmar Seyferth and Christian C. Prud'homme
pp 4412 - 4417; DOI:
10.1021/ic00194a003
PDF
An electroactive polymer film on a mercury electrode based on a thallium macrocyclic polyether complex
J. Massaux, P. Burgmayer, E. Takeuchi, and Royce W. Murray
pp 4417 - 4423; DOI:
10.1021/ic00194a004
PDF
Insertion reactions of hexaalkoxydimolybdenum and -ditungsten compounds with organic isocyanates. Syntheses and structures of W2(OCMe3)4[N(C6H5)C(O)OCMe3]2 and Mo2(O-i-Pr)4[N(C6H5)C(O)O-i-Pr]
Malcolm H. Chisholm, F. Albert Cotton, Kirsten Folting, John C. Huffman, A. L. Ratermann, and Edwar S. Shamshoum
pp 4423 - 4427; DOI:
10.1021/ic00194a005
PDF
Dissociative substitution in four-coordinate planar platinum(II) complexes. Kinetics of sulfoxide exchange and displacement by bidentate ligands in the reactions of cis-diarylbis(dimethyl sulfoxide)platinum(II) in chloroform and benzene
Santo Lanza, Domenico Minniti, Peter Moore, John Sachinidis, Raffaello Romeo, and Martin L. Tobe
pp 4428 - 4433; DOI:
10.1021/ic00194a006
PDF
Chemistry of molybdenum. 3. Synthesis, characterization, and electrochemical studies of monomeric oxodihalogenomolybdenum(VI), -molybdenum(V), and -molybdenum(IV) complexes of 2-aminocyclopent-1-ene-1-dithiocarboxylic acid
Muktimoy Chaudhury
pp 4434 - 4439; DOI:
10.1021/ic00194a007
PDF
Hydrazinium, alkali-metal, and ammonium trifluorooxovanadates(IV). Synthesis and spectroscopic studies of a new oxofluorovanadate(IV) complex, VOF3-
Mihir K. Chaudhuri, Soumitra K. Ghosh, and Japyesan Subramanian
pp 4439 - 4442; DOI:
10.1021/ic00194a008
PDF
Thermodynamic equilibria in the system zinc(II)-pyridoxal 5'-phosphate-2-amino-3-phosphonopropionic acid in aqueous solution
Bruno Szpoganicz and Arthur E. Martell
pp 4442 - 4447; DOI:
10.1021/ic00194a009
PDF
Amino acid amides of dithiooxalic acid: spectroscopic, electrochemical, and magnetic properties of copper(II) binuclear complexes and crystal structure of [N,N'-(1,2-dithioxoethane-1,2-diyl)bis(methyl methioninato)]bis(bromocopper(II))
Richard Veit, Jean Jacques Girerd, Olivier Kahn, Francis Robert, Yves Jeannin, and Nabil El Murr
pp 4448 - 4454; DOI:
10.1021/ic00194a010
PDF
Crystal structure and magnetic properties of [Cu2(tmen)2(N3)3](PF6) (tmen = N,N,N',N'-tetramethylethylenediamine): a copper(II) chain compound with both single symmetrical and double dissymmetrical end-to-end azido bridges
Itka Bkouche-Waksman, Marie Laure Boillot, Olivier Kahn, and Sonia Sikorav
pp 4454 - 4459; DOI:
10.1021/ic00194a011
PDF
Luminescence and NMR studies of the conformational isomers of lanthanide complexes with an optically active polyaza polycarboxylic macrocycle
Harry G. Brittain and Jean F. Desreux
pp 4459 - 4466; DOI:
10.1021/ic00194a012
PDF
Structural study of copper(II) sulfate solution in highly concentrated aqueous ammonia by x-ray absorption spectra
Mitsuru Sano, Tetsuya Maruo, Yuichi Masuda, and Hideo Yamatera
pp 4466 - 4469; DOI:
10.1021/ic00194a013
PDF
Two-mode .nu.(CO) vibrational frequency changes as indicators of geometry changes in mixed crystals of dodecacarbonyltriruthenium and dodecacarbonyltriosmium
Sidney F. A. Kettle and Pier Luigi Stanghellini
pp 4469 - 4471; DOI:
10.1021/ic00194a014
PDF
High oxidation state dinitrogen complexes. Synthesis and crystal structure of [W(C6H5C.tplbond.CC6H5)(CH3OCH2CH2OCH3)Cl2]2(.mu.-N2).0.5CH3OCH2CH2OCH3
Melvyn Rowen Churchill, Yong Ji Li, Klaus H. Theopold, and Richard R. Schrock
pp 4472 - 4476; DOI:
10.1021/ic00194a015
PDF
Structural studies on polynuclear osmium carbonyl hydrides. 29. Degenerate framework rearrangement in a capped-square-pyramidal metal-carbon cluster and its conversion to a capped-trigonal-bipyramidal cluster. Crystal structures of (.eta.5-C5H5)WOs3(CO)10(.mu.3-CC6H4CH3)2H and (.eta.5-C5H5)WOs3(CO)9(.mu.3-CC6H4CH3)2H
Joon T. Park, John R. Shapley, Melvyn Rowen Churchill, and Clifford Bueno
pp 4476 - 4486; DOI:
10.1021/ic00194a016
PDF
Structural investigations on solid tetraphosphorus hexaoxide
M. Jansen and M. Moebs
pp 4486 - 4488; DOI:
10.1021/ic00194a017
PDF
Organometallic complexes with metal-metal bonds. 19. Comparison of two strategies towards the syntheses of platinum mixed-metal clusters. Reactivity of linear M-Pt-M and Mn-Pt-Mn complexes. X-ray crystal structures of Pt2M2(.eta.5-C5H5)2(.mu.3-CO)2(.mu.-CO)4(PEt3)2 with M = Cr, Mo, and W
Robert Bender, Pierre Braunstein, Jean Marc Jud, and Yves Dusausoy
pp 4489 - 4502; DOI:
10.1021/ic00194a018
PDF
Facile and reversible conversion of an ammonium tetraphenylborate salt, Fe(NO)2[PhP(OCH2CH2)2NH2+]2[BPh4-]2, into an amine-triphenylborane adduct, Fe(NO)2[PhP(OCH2CH2)2N(H).BPh3]2
Laurence Mordenti, Jean Louis Roustan, and Jean G. Riess
pp 4503 - 4506; DOI:
10.1021/ic00194a019
PDF
Preparation and crystal structure of mercury hexafluoroniobate (Hg3NbF6) and mercury hexafluorotantalate (Hg3TaF6): mercury layer compounds
I. David Brown, Ronald J. Gillespie, Keith R. Morgan, Zin Tun, and P. K. Ummat
pp 4506 - 4508; DOI:
10.1021/ic00194a020
PDF
Reactivity of the monodent dithiocarbamate ligand in CpFe(CO)2(.eta.1-S2CNR2)
Daniel Catheline, Enrique Roman, and Didier Astruc
pp 4508 - 4514; DOI:
10.1021/ic00194a021
PDF
Quantitative studies on the coordination chemistry of tetrakis(n-butyrato)diruthenium chloride
Russell S. Drago, Richard Cosmano, and Joshua Telser
pp 4514 - 4518; DOI:
10.1021/ic00194a022
PDF
Low-spin manganese(III) porphyrin imidazolate and cyanide complexes. Modulation of magnetic anisotropy by axial ligation
Andrew P. Hansen and Harold M. Goff
pp 4519 - 4525; DOI:
10.1021/ic00194a023
PDF
Reaction pathways from structural data: dynamic stereochemistry of nickel compounds
Thomas P. E. Auf der Heyde and Luigi R. Nassimbeni
pp 4525 - 4532; DOI:
10.1021/ic00194a024
PDF
Ligand effects on the excited-state dynamics of rhodium(III) complexes, photoluminescence properties of the tetraammine complexes Rh(NH3)4XYn+, and their relationship to photoreactivity
D. A. Sexton, L. H. Skibsted, D. Magde, and Peter C. Ford
pp 4533 - 4538; DOI:
10.1021/ic00194a025
PDF
Axial-ligand-dependent electrochemical and spectral properties of a series of acetate- and acetamidate-bridged dirhodium complexes
Madhav Y. Chavan, T. P. Zhu, X. Q. Lin, M. Q. Ahsan, J. L. Bear, and K. M. Kadish
pp 4538 - 4545; DOI:
10.1021/ic00194a026
PDF
Flash photolysis of Fe(TIM)CO(X)2+ complexes
Alison Butler and R. G. Linck
pp 4545 - 4549; DOI:
10.1021/ic00194a027
PDF
Flash photolytic investigation of photoinduced carbon monoxide dissociation from dinuclear manganese carbonyl compounds
Richard S. Herrick and Theodore L. Brown
pp 4550 - 4553; DOI:
10.1021/ic00194a028
PDF
Study of trans-dichlorobis(ethylenediamine)nickel(III) in zeolite Y
Hanfan Liu, Wenxia Shen, William H. Quayle, and Jack H. Lunsford
pp 4553 - 4556; DOI:
10.1021/ic00194a029
PDF
Resonance Raman spectra of iron(II) cytochrome P450 model complexes: influence of the thiolate ligand
G. Chottard, M. Schappacher, L. Ricard, and R. Weiss
pp 4557 - 4561; DOI:
10.1021/ic00194a030
PDF
Spectrophotometric studies of iodine complexes in an aluminum chloride-butylpyridinium chloride ionic liquid
Zenon J. Karpinski and Robert A. Osteryoung
pp 4561 - 4565; DOI:
10.1021/ic00194a031
PDF
Proton exchange of hexaamminecobalt(3+) ion with cosolvent water in Me2SO solutions: a cobalt-59 NMR study
John G. Russell, R. G. Bryant, and M. M. Kreevoy
pp 4565 - 4567; DOI:
10.1021/ic00194a032
PDF
Redox chemistry of multiply bonded diosmium complexes: preparation and characterization of complexes containing osmium-osmium bonds of order 2.5
Stephen M. Tetrick, Vyvyan T. Coombe, Graham A. Heath, T. Anthony Stephenson, and Richard A. Walton
pp 4567 - 4570; DOI:
10.1021/ic00194a033
PDF
Electronic structure and spectroscopic properties of chromium(V), molybdenum(VI) and niobium(V) tetraperoxides
M. Roch, J. Weber, and A. F. Williams
pp 4571 - 4580; DOI:
10.1021/ic00194a034
PDF
Resonance Raman studies of phenolate-bridged binuclear copper complexes. Relevance to hemocyanin and tyrosinase
J. W. Pyrz, K. D. Karlin, T. N. Sorrell, G. C. Vogel, and L. Que
pp 4581 - 4584; DOI:
10.1021/ic00194a035
PDF
Three-coordinate metal amides of manganese(II) and cobalt(II): synthesis and x-ray structure of the first tris(silylamide) of manganese and the x-ray crystal structures of [M2(N(SiMe3)2)4] (M = Mn, Co)
Brendan D. Murray and Philip P. Power
pp 4584 - 4588; DOI:
10.1021/ic00194a036
PDF
Halide abstraction from vanadium trichloride by zinc chloride. Crystal structure of vanadium trichloride.zinc chloride.4 tetrahydrofuran.2 water
Kirsten Folting, John C. Huffman, Rick L. Bansemer, Kenneth G. Caulton, Joel L. Martin, and Paul D. Smith
pp 4589 - 4592; DOI:
10.1021/ic00194a037
PDF
Interactions of cobalt carbonyls with oxide surfaces. 2. Dicobalt octacarbonyl and tetracobalt dodecacarbonyl on silicas and aluminas
Roger L. Schneider, Russell F. Howe, and Kenneth L. Watters
pp 4593 - 4599; DOI:
10.1021/ic00194a038
PDF
Interactions of cobalt carbonyls with oxide surfaces. 3. Dicobalt octacarbonyl and tetracobalt dodecacarbonyl in zeolites
Roger L. Schneider, Russell F. Howe, and Kenneth L. Watters
pp 4600 - 4607; DOI:
10.1021/ic00194a039
PDF
Empirical intensity parameters for the 4f .fwdarw. 4f absorption spectra of nine-coordinate neodymium(III) and holmium(III) complexes in aqueous solution
Eileen M. Stephens, Scott Davis, Michael F. Reid, and F. S. Richardson
pp 4607 - 4611; DOI:
10.1021/ic00194a040
PDF
Model calculations for the intensity parameters of nine-coordinate neodymium(III) and holmium(III) complexes of trigonal symmetry
Eileen M. Stephens, Michael F. Reid, and F. S. Richardson
pp 4611 - 4618; DOI:
10.1021/ic00194a041
PDF
Molecular orbital calculations on dinitrogen-bridged transition-metal dimers
Cynthia B. Powell and Michael B. Hall
pp 4619 - 4627; DOI:
10.1021/ic00194a042
PDF
Generalized molecular orbital calculations on transition-metal dioxygen complexes. Models for iron and cobalt porphyrins
James E. Newton and Michael B. Hall
pp 4627 - 4632; DOI:
10.1021/ic00194a043
PDF
Structure of blue-violet OsX2L2 and its reactions with bidentate ligands (Dz-): spectra and electrochemistry of OsDL2(2-z)+[X = Cl, Br; L = 2-(m-tolylazo)pyridine; z = 0-2]
Barindra Kumar Ghosh, Anuradha Mukhopadhyay, Sreebrata Goswami, Siddhartha Ray, and Animesh Chakravorty
pp 4633 - 4639; DOI:
10.1021/ic00194a044
PDF
Substitution by trialkyl phosphites on [C(NMe2)3][Ru3{.mu.-O:C(NMe2)}(CO)10]: crystal and molecular structure of Ru3{.mu.-H,.mu.-O:C(NMe2)}(CO)9P(OPh)3
Andreas Mayr, Ying Chih Lin, Neil M. Boag, Carsten E. Kampe, Carolyn B. Knobler, and Herbert D. Kaesz
pp 4640 - 4645; DOI:
10.1021/ic00194a045
PDF
Substitution by phosphorus ligands on edge-double-bridged triruthenium carbonyl complexes and on Ru2[.mu.-O:C(Et)]2(CO)6: carbon-13 NMR characterization
Carsten E. Kampe and Herbert D. Kaesz
pp 4646 - 4653; DOI:
10.1021/ic00194a046
PDF
Fast atom bombardment mass spectrometry of phthalocyanines
Royal B. Freas and Joseph E. Campana
pp 4654 - 4658; DOI:
10.1021/ic00194a047
PDF
Crystal and molecular structure of chloro(phthalocyaninato)gallium(III), Ga(Pc)Cl, and chloro(phthalocyaninato)aluminum(III), Al(Pc)Cl
Kenneth J. Wynne
pp 4658 - 4663; DOI:
10.1021/ic00194a048
PDF
Synthesis and structural characterization of rhodium(I) and iridium(I) complexes of the asymmetric tetradentate PPNN ligand 2,2'-bis[[o-(diphenylphosphino)benzylidene]amino]-6,6'-dimethylbiphenyl
Tricia L. Marxen, Brian J. Johnson, Per V. Nilsson, and Louis H. Pignolet
pp 4663 - 4670; DOI:
10.1021/ic00194a049
PDF
Photophysical and photochemical properties of cobalt(III) phosphite complexes
Virginia H. Houlding and Vincent M. Miskowski
pp 4671 - 4675; DOI:
10.1021/ic00194a050
PDF
The transition metal-carbon monoxide bond
Ralph G. Pearson
pp 4675 - 4679; DOI:
10.1021/ic00194a051
PDF
Crystal structures from powder data. 1. Crystal structure of zirconium potassium hydrogen phosphate (ZrKH(PO4)2)
A. Clearfield, L. B. McCusker, and P. R. Rudolf
pp 4679 - 4682; DOI:
10.1021/ic00194a052
PDF
Synthesis and structure of trans-[O2(TBP)4Tc]+ (TBP = 4-tert-butylpyridine) and related complexes
M. E. Kastner, P. H. Fackler, M. J. Clarke, and E. Deutsch
pp 4683 - 4688; DOI:
10.1021/ic00194a053
PDF
Molecular and electronic structures of two 16-electron complexes of tungsten(II): WBr2(CO)2(C7H8) (C7H8 = norbornadiene) and WBr2(CO)2(PPh3)2
F. A. Cotton and J. H. Meadows
pp 4688 - 4693; DOI:
10.1021/ic00194a054
PDF
Synthesis and characterization of an unusual asymmetric diosmium complex, Os2Cl3(PhNpy)3
Akhil R. Chakravarty, F. Albert Cotton, and Derek A. Tocher
pp 4693 - 4697; DOI:
10.1021/ic00194a055
PDF
An ortho-metallation reaction of Os2(O2CCH3)4Cl2: syntheses and crystal structure characterizations of Os2(O2CR)2[(C6H5)2P(C6H4)]2Cl2 (R = CH3 (1), C2H5 (2))
Akhil R. Chakravarty, F. Albert Cotton, and Derek A. Tocher
pp 4697 - 4700; DOI:
10.1021/ic00194a056
PDF
Alkali metal cation effects in a Prussian blue surface modified electrode
Alvin L. Crumbliss, Paul S. Lugg, and Nicholas Morosoff
pp 4701 - 4708; DOI:
10.1021/ic00194a057
PDF
Kinetics, mechanism, and thermodynamics of aqueous iron(III) chelation and dissociation: influence of carbon and nitrogen substituents in hydroxamic acid ligands
Christina Poth Brink and Alvin L. Crumbliss
pp 4708 - 4718; DOI:
10.1021/ic00194a058
PDF
Selenido osmium carbonyl cluster compounds. Structure, bonding, and reactivity of the electron-rich cluster Os4(CO)12(.mu.3-Se)2
Richard D. Adams and Istvan T. Horvath
pp 4718 - 4722; DOI:
10.1021/ic00194a059
PDF
Cluster synthesis. 7. Role of bridging sulfido ligands in the synthesis of platinum osmium carbonyl cluster compounds
Richard D. Adams and T. S. Andy Hor
pp 4723 - 4732; DOI:
10.1021/ic00194a060
PDF
Cluster synthesis. 8. Synthesis and crystal and molecular structures of the sulfido-bridged platinum osmium carbonyl cluster compounds PtOs3(CO)9L(PPh3)(.mu.3-S)2 (L = CO, PPh3)
Richard D. Adams, T. S. Andy Hor, and Istvan T. Horvath
pp 4733 - 4738; DOI:
10.1021/ic00194a061
PDF
Synthesis and structure of new trinuclear cluster compounds [M3(.mu.3-O)2(O2CC3H7)6(H2O)3]2+ (M = Mo, W). Comparison of molybdenum and tungsten bond radii as a function of M-M bond order
F. Albert Cotton, Zvi Dori, David O. Marler, and Willi Schwotzer
pp 4738 - 4742; DOI:
10.1021/ic00194a062
PDF
Synthesis, characterization, and electrochemical properties of technetium complexes containing both tetradentate Schiff base and monodentate tertiary phosphine ligands: single-crystal structure of trans-(N,N'-ethylenebis(acetylacetone iminato))bis-(triphenylphosphine) technetium(III) hexafluorophosphate
Silvia S. Jurisson, Keith Dancey, Mary McPartlin, Peter A. Tasker, and Edward Deutsch
pp 4743 - 4749; DOI:
10.1021/ic00194a063
PDF
Mass spectrometric behavior of bis(cyanoimino-.beta.-carbonylenolato)nickel(II) complexes
S. Daolio, P. Traldi, B. Pelli, M. Basato, B. Corain, and F. Kreissl
pp 4750 - 4752; DOI:
10.1021/ic00194a064
PDF
Ligand redistribution in triazene 1-oxide complexes: a voltammetric study
Rabindranath Mukherjee and Animesh Chakravorty
pp 4753 - 4755; DOI:
10.1021/ic00194a065
PDF
Synthesis and characterization of the alkoxo-bridged chromium(III) dimer bis(.mu.-methoxo)bis[bis(2,2,6,6-tetramethyl-3,5-heptanedionato)chromium(III)]
Helen R. Fischer, Derek J. Hodgson, and Erik Pedersen
pp 4755 - 4758; DOI:
10.1021/ic00194a066
PDF
X-ray and neutron diffraction study of [P(CH2C6H5)(C6H5)3]+[HIr4(CO)11]-
Robert Bau, Michael Y. Chiang, Chiau Yu Wei, Luigi Garlaschelli, Secondo Martinengo, and Thomas F. Koetzle
pp 4758 - 4762; DOI:
10.1021/ic00194a067
PDF
Esters of phosphotungstic acid. Anhydrous phosphotungstic acid
Walter H. Knoth and R. D. Farlee
pp 4765 - 4766; DOI:
10.1021/ic00194a068
PDF
Unsymmetrical chelating ligands. Synthesis of 1-mercapto-2-phosphinobenzenes with a variety of substituents on the ligating sites
Evan P. Kyba and Clyde N. Clubb
pp 4766 - 4768; DOI:
10.1021/ic00194a069
PDF
Synthesis, characterization, and structure of chlorodimethyl(N,N'-dimethyldithiocarbamato)germane
Raj K. Chadha, John E. Drake, and Anil B. Sarkar
pp 4769 - 4770; DOI:
10.1021/ic00194a070
PDF
Interligand frontier orbital contacts in phenanthroline chelates
Keith F. Purcell
pp 4770 - 4772; DOI:
10.1021/ic00194a071
PDF
Comment on the measurement and interpretation of susceptibility data
Philippe Baltzer and Juerg Hulliger
pp 4772 - 4773; DOI:
10.1021/ic00194a072
PDF
.pi. Bonding in trisilylamine and related compounds
David B. Beach and William L. Jolly
pp 4774 - 4775; DOI:
10.1021/ic00194a073
PDF
Does coordination activate heterocycles toward nucleophilic attack? The importance of .pi. interactions between metal ion and ligand
Peter A. Lay
pp 4775 - 4777; DOI:
10.1021/ic00194a074
PDF
Equilibrium constants and electrophilic exchange-reaction kinetics of lead(II) porphyrins
Shirleyanne E. Haye and Peter Hambright
pp 4777 - 4779; DOI:
10.1021/ic00194a075
PDF
Single-crystal EPR spectra of tetra-n-butylammonium bis(isotrithione-3,4-dithiolato)cuprate(II) (copper-63)
Joachim Stach, Reinhard Kirmse, Wolfgang Dietzsch, Ruth Maria Olk, and Eberhard Hoyer
pp 4779 - 4780; DOI:
10.1021/ic00194a076
PDF
Preparation, Structure, and Properties of the Polar Dirhodium(II) Tetrakis(6-fluoro-2-oxypyridinate) Molecule
F. Albert Cotton, Scott Han, and Wenning Wang
pp 4762 - 4765; DOI:
10.1021/ic00194a600
PDF